Provided are a molded article that contains a polyarylene sulfide (PAS) resin and a glass fiber and allows a decrease in mechanical strength to be suppressed even in a hot water environment and under acidic conditions, a PAS resin composition capable of providing such a molded article, and methods for producing the same. More specifically, provided are a PAS resin composition including, per 100 parts by mass of a PAS resin, 10 to 100 parts by mass of a glass fiber having, in the glass fiber, a ZrO.sub.2 content of 16 mass % or more, a TiO.sub.2 content of 5 to 10 mass % or less, and a CaO content of 0.1 to 5 mass %, and 0.01 to 10 parts by mass of a silane coupling agent (C) blended as essential components; a molded article; and methods for producing the same.

The present invention concerns Method for producing a unidirectional tape, the method comprising the steps of a) providing an impregnation slurry comprising primary particles and secondary particles, water, optionally an organic carrying medium, optionally an organic compound and optionally a surface active compound, and providing a unidirectional fiber layer having an average interstitial filament distance, wherein the primary particles comprise a first polymer and the primary particles have a particle size equal to or smaller than the average interstitial filament distance, and the secondary particles comprise a second polymer and the secondary particles have a particle size larger than the average interstitial filament distance, b) impregnating the unidirectional fiber layer with the impregnation slurry to form an impregnated unidirectional fiber web comprising an impregnated unidirectional fiber layer and a surface polymer layer, wherein the impregnated unidirectional fiber layer comprises, preferably consists of, the unidirectional fibers and the primary particles, and the surface polymer layer comprises the secondary particles, c) drying the impregnated unidirectional fiber web to obtain a unidirectional tape.

A method for producing and recycling a crosslinked photopolymer is disclosed. The method includes mixing reactive thiols, multifunctional alkenes, and a photoinitiator to create a homogeneous mixture that is crosslinked through exposure to light. The method also includes decrosslinking the crosslinked photopolymer through base-catalyzed thiol-disulfide exchange reactions by mixing the crosslinked photopolymer with a reactive thiol, a base catalyst, and a solvent to create a decrosslinked material including recycled thiol oligomers which are reactive. The method further includes removing the base catalyst and the solvent and recrosslinking the recycled thiol oligomers by mixing stoichiometric amounts of the recycled thiol oligomers and a reactive alkene such that a molar ratio between thiol end groups and ene end groups is maintained at 1:1. The method includes adding a photoinitiator and mixing to create a homogeneous mixture, and recrosslinking the homogeneous mixture through exposure to light. The recrosslinked photopolymer includes dynamic disulfide bonds.

The purpose of the present invention is to provide a thermoplastic resin composition having exceptional thermal stability and mechanical characteristics, a fiber-reinforced resin substrate, and a molded article obtained therefrom. In order to achieve the abovementioned purpose, an embodiment of the present invention has the structure described below. Specifically, a thermoplastic resin composition including a thermoplastic resin (A) having an electron-donating group, and a transition metal compound (B), wherein the transition metal compound (B) includes a nickel compound (B1) and a copper compound (B2), the complete decomposition temperature of the copper compound (B2) is 400° C. or higher, and the copper compound (B2) has a nickel content of 0.001-4 parts by mass (inclusive) and a copper content of 0.001-4 parts by mass (inclusive) with respect to 100 parts by mass of the thermoplastic resin (A) having an electron-donating group.

The present invention relates to a polyarylene sulfide which has more improved compatibility with other polymer materials or fillers, and a method for preparing the same. The polyarylene sulfide is characterized in that at least part of end groups of the main chain of the polyarylene sulfide is hydroxyl group (—OH), the polyarylene sulfide contains iodine bonded to its main chain and free iodine, and the content of iodine bonded to the main chain and free iodine is 10 to 10,000 ppmw.

The present invention relates to a poly(arylene sulfide) (PAS), comprising recurring units p, q and r according of formula (I) wherein n.sub.p, n.sub.q and n.sub.r are respectively the mole % of each recurring units p, q and r; recurring units p, q and r are arranged in blocks, in alternation or randomly; 2≤(n.sub.q+n.sub.r)/(n.sub.p+n.sub.q+n.sub.r)≤9; n.sub.q is ≥0% and n.sub.r is ≥0%; j is zero or an integer varying between 1 and 4; R.sup.1 is selected from the group consisting of halogen atoms, C.sub.1-C.sub.12 alkyl groups, C.sub.7-C.sub.24 alkylaryl groups, C.sub.7-C.sub.24 aralkyl groups, C.sub.6-C.sub.24 arylene groups, C.sub.1-C.sub.12 alkoxy groups, and C.sub.6-C.sub.18 aryloxy groups.

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The present invention relates to a thermoplastic composite composition and a molded product manufactured therefrom, and more specifically, to a high-rigidity and high-heat resistance thermoplastic composite composition and a molded product manufactured therefrom.

The thermoplastic composite composition includes: (a) a first polymer resin including a polyphenylene sulfide polymer having a melt index (ASTM D-1238, 235° C.) of 100 to 150 g/10 min; (b) a second polymer resin including a polyphenylene sulfide polymer having a melt index (ASTM D-1238, 235° C.) of 250 to 850 g/10 min, and an amorphous monomer having an aliphatic cyclobutanediol; (c) a carbon fiber surface-treated with a polyimide; (d) a fatty acid compound; and (e) a heat-resistant additive.

Since the thermoplastic composite composition according to the present invention uses the polymer resin including the amorphous monomer having the aliphatic cyclobutanediol, compatibility of the carbon fiber and the thermoplastic resin may increase, leading to an improvement in impregnation properties, so that high-rigidity and high-heat resistance aeronautical interior and a structural molded product.

The present disclosure provides a polymeric composition including a thermoplastic polymer and an ionic liquid compound, wherein the ionic liquid compound improves the melt flow rate of the polymeric composition. The present disclosure also provides a method of preparing a polymeric composition with improved melt flow rate by mixing an ionic liquid compound with a thermoplastic polymer to obtain the polymeric composition. In some aspects, the polymeric composition includes a recycled polymer.

Disclosed are particles that have an exterior surface coated with a thin polymeric coating, such as a coating that includes a sulfur-containing polymer. Also disclosed are compositions, such as fuel-resistant sealant and coating compositions, which include such particles. Aerospace vehicles having an aperture at least partially sealed with a sealant deposited from such a sealant composition are also disclosed.

The invention relates to a foam material (FP) comprising a polymer composition (C) comprising at least a polyphenylene sulfide polymer (PPS) and at least one functionalized elastomer (E). The present invention also relates to a process for the manufacture of said foam material and to an article (A) including said foam material (FP), for example a composite material.