Provided is a molding material comprising a composite of 1 to 50 wt % of a continuous reinforcing fiber bundle (A) and 0.1 to 20 wt % of a poly (phenylene ether ether ketone) oligomer (B); and 30 to 98.9 wt % of a thermoplastic resin (C) adhering to the composite, wherein the component (B) has a melting point of not higher than 270 C. Also provided are a method for molding the molding material, a method for producing the molding material, and a method for producing a fiber-reinforced composite material. A molded article having high heat resistance and dynamic properties can be easily produced without impairing the economic efficiency and productivity during the process for producing a molding material. In addition, a fiber-reinforced composite material can be produced with more ease and high productivity.

A carbon fiber-reinforced polyarylene sulfide has both dynamic characteristics and molding cycle characteristics and can be produced with high productivity by preparing a polycarbodiimide-modified polyarylene sulfide using a polyarylene sulfide and a polycarbodiimide as raw materials, then melting the resulting polycarbodiimide-modified polyarylene sulfide, and combining the polycarbodiimide-modified polyarylene sulfide with carbon fibers at a specific ratio to produce a composite.

A molding material is provided including a composite having 1 to 50 wt % of (A) a bundle of continuous reinforcing fibers and 0.1 to 40 wt % of (B) a polyarylene sulfide prepolymer or (B) a polyarylene sulfide; and 10 to 98.9 wt % of (C) a thermoplastic resin adhered to the composite; wherein the composite further has (D) a zero-valent transition metal compound or (E) a low-valent iron compound in an amount of 0.001 to 20 mol % based on the amount of sulfur atoms contained in the component (B) or (B). A prepreg and a method of producing a fiber-reinforced molding base material is also provided. By using the molding material according to the present invention which exhibits excellent economic efficiency and productivity, a molded article having excellent mechanical characteristics can be easily produced.

The present invention relates to a composite film comprising a graphene oxide coating layer, a porous polymer support comprising the same, and a method for preparing the same. More particularly, the present invention relates to a composite film comprising a graphene oxide coating layer with improved permeability and stability, a porous polymer support for a composite film comprising a graphene oxide coating layer with improved permeability, and a method for preparing the same.

The present invention provides a laminated body including a support (A) that includes a polyphenylene sulfide resin composition containing a polyphenylene sulfide (a1) and an elastomer (a2), and a metal layer (B) and a metal-plating layer (C) that are laminated on the support (A) in this order, wherein the elastomer (a2) is contained in the polyphenylene sulfide resin composition in an amount in the range of 0.3 to 90 parts by mass relative to 100 parts by mass of the polyphenylene sulfide (a1). The laminated body is excellent in adhesiveness between the polyphenylene sulfide as the support and the metal-plating layer, and also has a thermal resistance so as to maintain the excellent adhesiveness even when exposed to a high-temperature environment.

Sulfur copolymers having high sulfur content for use as raw materials in 3D printing. The sulfur copolymers are prepared by melting and copolymerizing one or more comonomers with cyclic selenium sulfide, elemental sulfur, elemental selenium, or a combination thereof. Optical substrates, such as films and lenses, are constructed from the sulfur copolymer via 3D printing and are substantially transparent in the visible and infrared spectrum. The optical substrates can have refractive indices of about 1.75-2.6 at a wavelength in a range of about 500 nm to about 8 m.

Methods of forming a polyarylene sulfide and systems as may be utilized in carrying out the methods are described. Included in the formation method is a filtration process for treatment of a mixture, the mixture including a polyarylene sulfide, a salt byproduct of the polyarylene sulfide formation reaction, and a solvent. The filtration process includes maintaining the downstream side of the filter medium at an increased pressure. The downstream pressure can such that the boiling temperature of the mixture at the downstream pressure can be higher than the temperature at which the polyarylene sulfide is insoluble in the solvent.

A composite thermal barrier material (100) has a sandwich structure, and comprises an inner layer (110) consisting of an aerogel material which has ultra-low thermal conductivity; and two flame retardant layers (120) which comprising a flame retardant resin matrix (130), wherein the inner layer (110) is sandwiched by the two flame retardant layers (120), and the flame retardant layer (120) also contains an expandable graphite (140), a high temperature decomposable material (150) and a phase change material (160) as functional fillers dispersed in the flame retardant resin matrix (130). The composite thermal barrier material (100) has excellent thermal insulation property, and may stop the thermal propagation when one cell has thermal runaway.

A resin composition for molding includes a polyarylene thioether resin having a constant ? of 0.8 or greater determined by the Mark-Houwink equation represented by Equation 1: ?=K?M.sup.?. In Equation 1, ? is the intrinsic viscosity, M is the molecular weight, and K and ? are constants.

A polyarylene sulfide resin composition includes: 100 parts by weight of (A) a polyarylene sulfide; and 10 to 200 parts by weight of (B) a glass fiber, wherein, when a cumulative integral value from a molecular weight of 100 to a molecular weight of 10,000 in a molecular weight distribution curve of (A) the polyarylene sulfide is taken as 100, the cumulative integrated value at a molecular weight of 4,000 is 48 to 53, and when a melt flow rate of the polyarylene sulfide is defined as MFR1, and when the melt flow rate obtained after mixing the polyarylene sulfide with an epoxy silane coupling agent at a weight ratio of 100:1, and heating the resulting mixture at 315.5? C. for 5 minutes is defined as MFR2, a rate of change represented by MFR2/MFR1 is not more than 0.085.