The present invention relates to an anti-reflective film that comprises a low moisture permeable polymer film, a hard coating layer and a low refractive index layer and that has low reflectance deviation and light transmittance deviation, can simultaneously realize high scratch resistance and anti-fouling property, and can increase screen sharpness of a display apparatus, a polarizing plate and a display apparatus comprising the same.

Addition curable composition containing specific silicone resins containing aliphatically unsaturated groups and an. organic compound containing unsaturated groups such as acrylate or methacrylate groups are suitable when used with fine and coarse fillers to produce artificial stone with both high hardness and high flexural strength.

Disclosed herein is an anti-reflective film including: a hard coating layer; and a low-refractive layer containing a binder resin, and hollow inorganic nanoparticles and solid inorganic nanoparticles which are dispersed in the binder resin, wherein the low-refractive layer includes a first layer containing at least 70 vol % of the entire solid inorganic nanoparticles and a second layer containing at least 70 vol % of the entire hollow inorganic nanoparticles, and at the time of fitting polarization ellipticity measured by ellipsometry for the first layer or/and the second layer included in the low-refractive layer using a Cauchy model represented by the following General Equation 1, the second layer satisfies a predetermined condition.

The present invention relates to an anti-reflective film exhibiting one or more peaks (q.sub.max) at a scattering vector of 0.0758 to 0.1256 nm.sup.1, in a graph showing a log value of scattering intensity to a scattering vector defined in small-angle X-ray scattering.

The present invention relates to an anti-reflective film exhibiting one or more peaks (q.sub.max) at a scattering vector of 0.0758 to 0.1256 nm.sup.1, in a graph showing a log value of scattering intensity to a scattering vector defined in small-angle X-ray scattering.

A decorative film includes: a substrate; and a polymer layer including on a surface thereof an uneven structure provided with projections at a pitch not longer than a wavelength of visible light. The substrate contains a polycarbonate at least in its surface close to the polymer layer. The polymer layer is a cured product of a polymerizable composition. The polymerizable composition contains a release agent, a polyfunctional acrylate containing one or both of an ethylene oxide group and a propylene oxide group, and 2-(2-vinyloxyethoxy)ethyl acrylate. The polymerizable composition contains, in terms of active components, given proportions of the release agent and the 2-(2-vinyloxyethoxy)ethyl acrylate. The polymerizable composition contains, in terms of active components, a given total amount of the ethylene oxide group and the propylene oxide group in the polyfunctional acrylate and the 2-(2-vinyloxyethoxy)ethyl acrylate.

The antifouling film includes a polymer layer that includes on a surface thereof an uneven structure provided with multiple projections at a pitch not longer than a wavelength of visible light. The polymer layer has a proportion of the number of fluorine atoms relative to the sum of the numbers of carbon atoms, nitrogen atoms, oxygen atoms, and fluorine atoms of 33 atom % or more on the surface of the uneven structure. The polymer layer has at least one local maximum of the proportion of the number of nitrogen atoms relative to the sum of the numbers of carbon atoms, nitrogen atoms, oxygen atoms, and fluorine atoms in a region 5 to 90 nm deep from the surface of the uneven structure. The local maximum is 0.3 atom % or more greater than the average value in a region 90 to 120 nm deep from the surface of the uneven structure.

Described herein is an anti-reflective film including: a hard coating layer; and a low-refractive layer containing a binder resin and hollow inorganic nanoparticles and solid inorganic nanoparticles dispersed in the binder resin. The hollow and solid inorganic particles are dispersed in the low-refractive layer such that the amount of the solid inorganic nanoparticles positioned close to an interface between the hard coating layer and the low-refractive layer is larger than that of the hollow inorganic nanoparticles. Also described is a manufacturing method of the anti-reflective film including: applying a resin composition containing a photopolymerizable compound or a (co)polymer thereof, a fluorine-containing compound including a photoreactive functional group, a photoinitiator, hollow inorganic nanoparticles, and solid inorganic nanoparticles on a hard coating layer, and drying the applied resin composition at a temperature of 35 C. to 100 C.; and photocuring the dried resin composition.

Embodiments relate to a hard coat-laminated film for a touch panel display face plate, the hard coat-laminated film including: a transparent resin film, and a hard coat formed on at least one surface of the transparent resin film from a coating material including an active energy ray-curable resin composition. The hard coat-laminated film meets the following requirements (1-i) to (1-v): (1-i) a total light transmittance of 80% or higher, (1-ii) a haze of 3.0% or lower, (1-iii) a yellowness index of 3 or lower, (1-iv) a water contact angle of a touch surface of 100 or larger; and (1-v) a water contact angle of the touch surface of 100 or larger after 20,000-times reciprocal cotton wiping of the touch panel.

Provided is an oxime ester phenylcarbazole compound useful as a photoinitiator for photocrosslinking. Specifically, the carbon atom forming a double bond with the nitrogen atom in the oxime ester moiety of the oxime ester phenylcarbazole compound is bonded to the phenylcarbazole group and is directly bonded to a (C.sub.1-C.sub.20)alkyl or (C.sub.6-C.sub.20)aryl group. Also provided is a photopolymerizable composition including the oxime ester phenylcarbazole compound. The oxime ester phenylcarbazole compound and the photopolymerizable composition have improved solubilities, are highly photosensitive, and exhibit excellent physical properties in terms of residual film ratio, pattern stability, resist adhesiveness. Due to these advantages, the oxime ester phenylcarbazole compound and the photopolymerizable composition are suitable for use in black resists, color resists, overcoats, column spacers, and organic insulating films of LCDs.