A composite barrier film has a base layer of polyester with a barrier layer modified polyvinyl amine (mPVA). The mPVA is polyvinyl alcohol/polyvinyl amine copolymer crosslinked with citric acid and an optional additional crosslinking agent such as epichlorohydrin. The barrier layer can be applied by deposition of a reactive aqueous solution onto the base layer, heating and drying to remove water and crosslink the reactants. Excellent barrier properties of the film are obtained by applying and crosslinking the barrier layer during the transverse stretching steps of a biaxial oriented polymer film continuous fabrication process. Superior barrier properties are achieved with transverse stretching by a factor of about 3-4.

Technologies are generally described to increase a surface smoothness of a 3D printed article implementing a water-based treatment using layer by layer (LBL) deposition. An initial 3D printed article having an anionic surface may be treated with a first aqueous solution comprising at least one polycation that may bind to the anionic surface to produce a first treated surface, which may be rinsed with water to remove the first aqueous solution. The first treated surface may be treated with a second aqueous solution comprising at least one anionic microparticle that may bind to the polycation to produce a final 3D printed article having. a second treated surface, which may be rinsed with water to remove the second aqueous solution. The bound polycation and anionic microparticle may be present as a single layer in the final 3D printed article that may act as a conformal coating to increase the surface smoothness.

The present invention relates to an anti-tack formulation of high solids content that uses effective amounts of a fine particle size talc, a water soluble cationic polymer, one or more nonionic surfactants, and one or more alkali metal fatty acid soaps. The high solids content anti-tack formulation is capable of being easily shipped to a customer's location and is stable and easily pumped after shipment to a customer. The high solids content anti-tack formulation generates a micro-flocculated pigment dispersion that can be subsequently diluted to a low solids content formulation for use in anti-tack applications, particularly rubber slab dipping applications. The anti-tack formulation provides improved anti-tack performance when coating uncured rubber products.

The present invention relates to a gas-barrier coating composition containing a metal oxide, a phosphoric acid compound, and an amine compound. The present invention provides a gas-barrier film that features excellent oxygen-barrier property, excellent water vapor-barrier property as well as excellent transparency, and a gas-barrier laminate that includes the film.