A double network hydrogel including a polymer (A) having a persistence length between 10 and 1000 nm; a flexible polymer (B), wherein the persistence length is measured according to single molecule force microscopy measurement, wherein polymer (B) has an extended coil conformation at a first condition and a collapsed globular conformation at a second condition. Polymer (A) preferably is a polyisocyanate, while polymer (B) is a crosslinked flexible polymer like for example PNIPAM. A method for making a double network hydrogel.

The present invention relates to a method of preparing a poly-γ-glutamic acid hydrogel using ultraviolet ray and to a use of the poly-γ-glutamic acid hydrogel prepared by the method, and the method of preparing poly-γ-glutamic acid hydrogel using ultraviolet irradiation according to the present invention solved the problem of microbial contamination in the poly-γ-glutamic acid solution, and produced poly-γ-glutamic acid hydrogel in high yield by only a simple treatment process, and as it was confirmed that the poly-γ-glutamic acid hydrogel has improved storage stability in a solution, the poly-gamma-glutamic acid hydrogel prepared by the method of preparing the same of the present invention can be provided as a tissue engineering scaffold, artificial organs and bio-ink for 3D printing.

The present invention relates to a method of preparing a poly-γ-glutamic acid hydrogel using ultraviolet ray and to a use of the poly-γ-glutamic acid hydrogel prepared by the method, and the method of preparing poly-γ-glutamic acid hydrogel using ultraviolet irradiation according to the present invention solved the problem of microbial contamination in the poly-γ-glutamic acid solution, and produced poly-γ-glutamic acid hydrogel in high yield by only a simple treatment process, and as it was confirmed that the poly-γ-glutamic acid hydrogel has improved storage stability in a solution, the poly-gamma-glutamic acid hydrogel prepared by the method of preparing the same of the present invention can be provided as a tissue engineering scaffold, artificial organs and bio-ink for 3D printing.

In some aspects, the present disclosure pertains to multi-arm polymers that comprise a core, a plurality of polymer segments having a first end that is covalently attached to the core and a second end comprising a moiety that comprises a reactive group, wherein the polymer segments comprise one or more free-radical-polymerizable monomers. In some aspects, systems are provided that comprise a first composition comprising such a multi-arm polymer and a second composition comprising a multifunctional compound that comprises functional groups that are reactive with the reactive groups of the multi-arm polymer. In some aspects, systems are provided that comprise crosslinked reaction products of such a multi-arm polymer and such a multifunctional compound.

Disclosed herein are a fiber-reinforced material and an article made of the same. The fiber-reinforced material includes a fiber assembly and a matrix material coating the fiber assembly, the matrix material is a thermoplastic resin composition obtained by blending a polyolefin resin, a polyamide resin, and a modified elastomer that reacts with the polyamide resin. When a puncture test is performed at a striker speed of 1-4 msec and when a maximum impact force is applied is defined as P.sub.M and a deflection at break is defined as P.sub.B, P.sub.B/P.sub.M4. When the amount of energy absorbed before a maximum impact force is applied is E.sub.1, the amount of energy absorbed after a maximum impact force is applied and before break is E.sub.2, and a total amount of absorbed energy of E.sub.1 and E.sub.2 is E.sub.T, the ratio of E.sub.2:E.sub.T is 70% or more.

Disclosed is a preparation method of an all-weather self-healing stretchable conductive material, which uses acrylic acid and modified polyglutamic acid as a substrate, adds Fe.sup.3+ to form coordination, adjusts the volume ratio of water and glycerin, and heats to generate radical polymerization, so as to obtain a uniform double-layer three-dimensional network structure. The obtained polyacrylic acid and polyglutamic acid composite hydrogel has good mechanical properties and characteristics of rapid self-healing. A composite carbon film is prepared by depositing a metal layer of 20 nm to 80 nm thick on a single-layer aligned carbon film by magnetron sputtering, and then the composite hydrogel is adhered to each of the upper and lower sides of the composite carbon film respectively to form an all-weather self-healing stretchable conductive material of a sandwich structure. The preparation method of the invention is simple, the source of raw materials is plenty, and the obtained materials have good electrical and mechanical properties and have broad application prospects in the fields of flexible stretchable devices, wearable devices, and soft-bodied robots and the like.

A double network hydrogel including a polymer (A) having a persistence length between 10 and 1000 nm; a flexible polymer (B), wherein the persistence length is measured according to single molecule force microscopy measurement, wherein polymer (B) has an extended coil conformation at a first condition and a collapsed globular conformation at a second condition. Polymer (A) preferably is a polyisocyanate, while polymer (B) is a crosslinked flexible polymer like for example PNIPAM. A method for making a double network hydrogel.

A prepreg containing at least the following components [A]-[F], wherein the ratio Ne/Nd of the number of structures Ne of component [F] present in a range of outside 110% of the particle diameter of component [E] and the number of structures Nd of component [F] present in a range outside 110% of the particle diameter of component [D] is 0.25 or higher. [A]: Carbon fibers, [B] thermosetting resin, [C]: curing agent, [D]: particles composed mainly of thermoplastic resin having a primary particle number-average particle size of 5-50 m, [E]: conductive particles different from component [D] and having a primary particle number-average particle size in the range of a specific expression, [F]: filler comprising a carbon material.

The present disclosure provides an edible gelatin base film and preparation method thereof, relating to material fields. The preparation method can improve the mechanical property of the film. The films prepared by the method have antibacterial properties, low-temperature stability and high-temperature dissolution, environmental-friendly components. The method includes the following steps: a) preparing gel nanoparticles; b) preparing bacterial cellulose nanoparticles; c) preparing the gelatin base film: mixing pullulan, glycerin, nisin, antibacterial peptide, the gel nanoparticles obtained from step a) and the bacterial cellulose nanoparticles obtained from step b), ultrasonically degassing, then being subjected to coating and drying to obtain the gelatin base film. The preparation method is used to prepare an edible gelatin base film.

The objective of the present invention is to provide a prepreg and a fiber reinforced composite material using this prepreg. This prepreg has good handleability, is suitable for producing a reinforced composite material in a short-time and without using an autoclave, and is capable of yielding a fiber reinforced composite material exhibiting excellent impact resistance, wherein the occurrence of voids has been suppressed. To attain the objective, this prepreg comprises a reinforced fiber [A] that is layered and partially impregnated with an epoxy resin composition containing an epoxy resin [B] and a hardener [C], the impregnation rate being 30 to 95%. In this prepreg, a thermoplastic resin [D] insoluble in the epoxy resin [B] is distributed unevenly over a surface on one side of the prepreg, and a portion not impregnated with the epoxy resin composition is localized in the layer of the reinforced fiber [A] on the side where the thermoplastic resin [D] is distributed unevenly. This prepreg has a localization parameter , which defines the degree of the localization to be in the range of 0.10<<0.45.