Patent classifications
C08J2477/06
POLYESTER-BASED RESIN COMPOSITION AND PRODUCTION PROCESS THEREFOR, MOLDED OBJECT AND PRODUCTION PROCESS THEREFOR, AND MASTERBATCH
Provided is a polyester-based resin composition capable of giving a molded article excellent in transparency and gas-barrier property even though the molded article requires stretching treatment, and also provided is a method for producing the composition. The method for producing a polyester-based resin composition includes a step of obtaining a master batch (M) containing a polyester resin (A) having a cyclic acetal structure or an alicyclic hydrocarbon structure, and a polyamide resin (B), and a step of melt-kneading the master batch (M) with a polyester resin (R) in which 70 mol % or more of the dicarboxylic acid unit is derived from an aromatic dicarboxylic acid and 70 mol % or more of the diol unit is derived from an aliphatic diol, thereby giving a polyester-based resin composition, in this order,. The glass transition temperature of the polyester resin (A) is 105 C. or lower, the content of the polyester resin (A) in the polyester-based resin composition is 0.5 to 15.0% by mass, and the content of the polyamide resin (B) is 0.5 to 10.0% by mass.
Matrix resins toughened with hybrid polyamide particles
Pre-impregnated composite material (prepreg) that can be cured/molded to form aerospace composite parts. The prepreg includes carbon reinforcing fibers and an uncured resin matrix. The resin matrix includes an epoxy component, polyethersulfone as a toughening agent, and a curing agent. The resin matrix is also composed of a thermoplastic particle component that includes hybrid polyamide particles wherein each hybrid particle contains a mixture of amorphous and semi-crystalline polyamide.
Polyamide mixture having improved fluidity
The invention relates to a thermoplastic composition having improved fluidity in the molten state, comprising at least: (a) a polyamide that has a melt viscosity greater than or equal to 50 Pa.Math.s, and (b) a non-evolutive polyamide having a melt viscosity lower than the melt viscosity of said polyamide (a), above 0.8 Pa.Math.s, and having a number-average molecular weight Mn lower than that of said polyamide (a), said composition having a melt viscosity that is stabilized at a value below the melt viscosity of said polyamide (a), said polyamide (b) having: a concentration of amine end groups (AEG) and/or of carboxyl end groups (CEG) less than or equal to 20 meq/kg, or a concentration of amine end groups (AEG) greater than or equal to 25 meq/kg; a concentration of acid end groups (CEG) greater than or equal to 25 meq/kg; and a concentration of blocked end groups (BEG) greater than or equal to 25 meq/kg.
WATER-SOLUBLE MATRIX, PRE-MOLDED ARTICLE CONTAINING RESIN PARTICLES, AND METHOD FOR PRODUCING RESIN PARTICLES
Provided are: a water-soluble matrix whose melt-kneading temperature can be adjusted according to the melting point or glass transition temperature of a resin; a pre-molded article in which resin particles are dispersed in the water-soluble matrix; and a method for producing resin particles. This production method includes melt-kneading a water-soluble matrix containing a modified polyvinyl alcohol-based resin and a water-soluble saccharide at a weight ratio of the former/the latter=from 99/1 to 50/50 and a thermoplastic resin, and bringing the pre-molded article in which the resin particles are dispersed into contact with an aqueous solvent to elute the matrix. The modified polyvinyl alcohol-based resin contains in a side chain thereof an alkyl group including at least one hydroxyl group (for example, a 1,2-dihydroxyalkyl group).
POLYAMIDE MOULDING COMPOSITIONS FOR GLASS COMPOSITES
Thermoplastic polyamide moulding composition consisting of: (A) 30-99.9 percent by weight of at least one polyamide selected from the group consisting of: at least one aliphatic or semiaromatic polyamide, in each case with C:N ratio at least 8; at least one aliphatic or semiaromatic polyamide composed of at least one dicarboxylic acid and of at least one diamine and also optionally a proportion below 50 mol percent based on the entirety of dicarboxylic acids and diamine as 100 mol percent, of lactams and/or aminocarboxylic acids; and mixtures thereof; (B) 0.1-5.0 percent by weight of polyethyleneimine (PEI) or copolymers or derivatives thereof; (C) 0-60 percent by weight of fillers and/or reinforcing materials; (D) 0-5.0 percent by weight of additives;
where the entirety of (A)-(D) provides 100% of the thermoplastic polyamide moulding composition, and also uses of such moulding compositions in particular in the context of components bonded to mineral glass.
Materials and methods for nucleating aligned thermoplastic crystals while fabricating thermoplastic carbon fiber reinforced polymer structures
The present disclosure relates to methods and systems for making thermoplastic resin materials and composite resin systems and materials made from the thermoplastic resins, by seeding one melted thermoplastic material with a second thermoplastic material in a crystalline state that comprises an amount of ferromagnetic material.
Glass-fiber-reinforced polyamide resin composition
The present invention is a glass-fiber-reinforced polyamide resin composition which contains a crystalline aliphatic polyamide resin (A), an amorphous polyamide resin (B), an acrylic resin (C), mica (D), glass fiber (E) and carbon black (F) in a ratio by mass of (10 to 40):(2 to 20):(1 to 10):(2 to 25):(20 to 50):(0.1 to 5), respectively and further contains a copper compound (G) in a rate of 0.005 to 1.0 part by mass when a total amount of the ingredients (A) to (F) is taken as 100 parts by mass.
Polyamide resin composition
The polyamide resin composition according to the present invention contains a polyamide resin (A) wherein an average carbon number of an alkylene group between amide groups is 5 or less and a polyamide resin (B) wherein an average carbon number of an alkylene group between amide groups is more than 5, wherein a ratio by mass (A)/(B) of the polyamide resin (A) to the polyamide resin (B) is from 98/2 to 40/60, and wherein, to 100 parts by mass of a total amount of the polyamide resin (A) and the polyamide resin (B), 0.5 to 20 part(s) by mass of a metal cyanide salt of a composition formula (1) (A.sub.x[M(CN).sub.y]) is compounded.
Co-extruded backsheet for solar cell modules
This invention relates to a solar-cell module backing layer obtained by co-extruding obtained by melt co-extruding (i) a first polymer composition comprising (a) a polyamide, (b) an elastomer and (c) an elastomer that contains groups that bond chemically and/or interact physically with the polyamide, and wherein the first polymer composition comprises from 10 to 90 wt. % of the polyamide (a) and from 10 to 90 wt. % of the elastomer (b) and (c) (of the total weight of polyamide (a) and elastomer (b) and (c) present in the first polymer composition) and (ii) a second polymer composition comprising from 50-98 wt. % of elastomer and from 0.15-5 wt. % of groups (based on the total weight of the second polymer composition) that bond chemically and/or interact physically with the solar cell and optionally with the first polymer composition.
PROCESS FOR PREPARING A BIAXIALLY ORIENTED MULTILAYERED FILM
The invention relates to a process for preparing a biaxially oriented multilayered film, the film comprising at least one layer comprising a polyolefin composition and at least one layer comprising a polyamide composition, the process comprising the steps of: a) Melting a polyamide composition comprising: i. a semi-crystalline polyamide Y comprising: monomeric units derived from caprolactam in an amount of at least 75 wt %; monomeric units derived from an aliphatic diamine in an amount of between 2.5 and 12.5 wt %; monomeric units derived from an aromatic diacid in an amount of between 2.5 and 12.5 wt %; wherein the weight percentage is given with respect to the total weight of the polyamide Y; ii. an amorphous polyamide in an amount of between 2.5 and 50 wt % with respect to the total weight of the polyamide composition; wherein the amorphous polyamide comprises: monomeric units derived from an aliphatic diamine X in an amount of between 30 and 70 wt %; monomeric units derived from an aromatic diacid in an amount of between 30 and 70 wt %; wherein the weight percentage is given with respect to the total weight of the amorphous polyamide; b) Melting a composition comprising a polyolefin; c) Co-extruding at least the melts obtained from a) and b) to form a film of at least two layers; d) Cooling the film to a temperature of at most 50 C., while the film is transported in a direction, referred to as machine direction; e) Stretching the film obtained in step d) with a stretch ratio of at least 13, at a temperature between the Tg of polyamide Y and Tm of the polyolefin, wherein the stretch ratio is defined as being the product of the stretch ratio parallel to the machine direction and the stretch ratio perpendicular to the machine direction. The invention also relates to a biaxially oriented multilayered film obtainable by the process.