Patent classifications
C08K5/36
COMPOSITIONS AND METHODS FOR MAKING FIRE-RESISTANT EPDM RUBBER
The disclosure herein relates to ethylene propylene diene monomer (EPDM) rubber. More specifically, the present disclosure relates to fire-resistant EPDM rubber. In one embodiment, the fire-resistant EPDM is a membrane used for weatherproofing buildings. In another embodiment, the fire-resistant EPDM membrane is a roofing material. In other embodiments, the fire-resistant EPDM rubber can be used in the electrical field.
POLYMER COMPOSITION COMPRISING A CROSSLINKABLE POLYOLEFIN WITH HYDROLYSABLE SILANE GROUPS AND CATALYST
The present invention relates to a polymer composition, which is a silanol condensation catalyst masterbatch, comprises a matrix, comprising a silane containing drying agent, and at least one silanol condensation catalyst, wherein each catalyst has a water content which is 0.1% by weight, or lower, and is selected from: i) a compound of formula I ArSO.sub.3H (I) or a precursor thereof, wherein Ar is an 1 to 4 alkyl groups substituted aryl, wherein the aryl is phenyl or naphthyl; and wherein each alkyl group, independently, is a linear or branched alkyl with 10 to 30 carbons, wherein total number of carbons in the alkyl groups is 20 to 80 carbons; ii) a derivative of i) selected from the group consisting of an anhydride, an ester, an acetylate, an epoxy blocked ester and an amine salt thereof which is hydrolysable to the corresponding compound of formula I; and iii) a metal salt of i) wherein the metal ion is selected from the group consisting of copper, aluminum, tin and zinc; an article, for example, a coating, a wire or a cable, comprising the polymer composition, and process for producing an article.
POLYMER COMPOSITION COMPRISING A CROSSLINKABLE POLYOLEFIN WITH HYDROLYSABLE SILANE GROUPS AND CATALYST
The present invention relates to a polymer composition, which is a silanol condensation catalyst masterbatch, comprises a matrix, comprising a silane containing drying agent, and at least one silanol condensation catalyst, wherein each catalyst has a water content which is 0.1% by weight, or lower, and is selected from: i) a compound of formula I ArSO.sub.3H (I) or a precursor thereof, wherein Ar is an 1 to 4 alkyl groups substituted aryl, wherein the aryl is phenyl or naphthyl; and wherein each alkyl group, independently, is a linear or branched alkyl with 10 to 30 carbons, wherein total number of carbons in the alkyl groups is 20 to 80 carbons; ii) a derivative of i) selected from the group consisting of an anhydride, an ester, an acetylate, an epoxy blocked ester and an amine salt thereof which is hydrolysable to the corresponding compound of formula I; and iii) a metal salt of i) wherein the metal ion is selected from the group consisting of copper, aluminum, tin and zinc; an article, for example, a coating, a wire or a cable, comprising the polymer composition, and process for producing an article.
POLYMER COMPOSITION COMPRISING A CROSSLINKABLE POLYOLEFIN WITH HYDROLYSABLE SILANE GROUPS AND CATALYST
The present invention relates to a polymer composition, which is a silanol condensation catalyst masterbatch, comprises a matrix, comprising a silane containing drying agent, and at least one silanol condensation catalyst, wherein each catalyst has a water content which is 0.1% by weight, or lower, and is selected from: i) a compound of formula I ArSO.sub.3H (I) or a precursor thereof, wherein Ar is an 1 to 4 alkyl groups substituted aryl, wherein the aryl is phenyl or naphthyl; and wherein each alkyl group, independently, is a linear or branched alkyl with 10 to 30 carbons, wherein total number of carbons in the alkyl groups is 20 to 80 carbons; ii) a derivative of i) selected from the group consisting of an anhydride, an ester, an acetylate, an epoxy blocked ester and an amine salt thereof which is hydrolysable to the corresponding compound of formula I; and iii) a metal salt of i) wherein the metal ion is selected from the group consisting of copper, aluminum, tin and zinc; an article, for example, a coating, a wire or a cable, comprising the polymer composition, and process for producing an article.
Polyolefin Photovoltaic Backsheet Comprising a Stabilized Polypropylene Layer
Polyolefin photovoltaic (PV) backsheets comprise a polypropylene layer stabilized with (A) at least one hindered amine with 2,2,6,6-tetraalkylpiperdine or 2,2,6,6 -tetraakylpiperazinone, either or both in combination with a triazine moiety, (B) a thioester, and, optionally, (C) at least one hindered hydroxybenzoate, and/or (D) an ortho hydroxyl triazine compound. These PV backsheets exhibit a low flame spread index of <100 without the use of FR agents, and the polypropylene layer exhibits good weatherability while providing the required long term heat aging performance necessary for PV modules.
Polyolefin Photovoltaic Backsheet Comprising a Stabilized Polypropylene Layer
Polyolefin photovoltaic (PV) backsheets comprise a polypropylene layer stabilized with (A) at least one hindered amine with 2,2,6,6-tetraalkylpiperdine or 2,2,6,6 -tetraakylpiperazinone, either or both in combination with a triazine moiety, (B) a thioester, and, optionally, (C) at least one hindered hydroxybenzoate, and/or (D) an ortho hydroxyl triazine compound. These PV backsheets exhibit a low flame spread index of <100 without the use of FR agents, and the polypropylene layer exhibits good weatherability while providing the required long term heat aging performance necessary for PV modules.
Polyolefin Photovoltaic Backsheet Comprising a Stabilized Polypropylene Layer
Polyolefin photovoltaic (PV) backsheets comprise a polypropylene layer stabilized with (A) at least one hindered amine with 2,2,6,6-tetraalkylpiperdine or 2,2,6,6 -tetraakylpiperazinone, either or both in combination with a triazine moiety, (B) a thioester, and, optionally, (C) at least one hindered hydroxybenzoate, and/or (D) an ortho hydroxyl triazine compound. These PV backsheets exhibit a low flame spread index of <100 without the use of FR agents, and the polypropylene layer exhibits good weatherability while providing the required long term heat aging performance necessary for PV modules.
ACRYLIC RUBBER AND CROSSLINKABLE COMPOSITION THEREOF
An acrylic rubber that is a copolymer in which 1 to 4 wt. % of a reactive halogen group-containing vinyl monomer is copolymerized as a crosslinkable comonomer, wherein 45 to 65 wt. % of n-butyl acrylate, 10 to 35 wt. % of 2-methoxyethyl acrylate and 8 to 30 wt. % of ethoxyethoxyethyl acrylate are copolymerized in 100 wt. % of comonomers other than the crosslinkable comonomer. This ethoxyethoxyethyl acrylate-copolymerized acrylic rubber can suppress the reduction of oil resistance while improving cold resistance represented by a TR-10 value, and by compounding it with a vulcanizing agent corresponding to the crosslinkable group thereof, a crosslinkable composition is formed.
ACRYLIC RUBBER AND CROSSLINKABLE COMPOSITION THEREOF
An acrylic rubber that is a copolymer in which 1 to 4 wt. % of a reactive halogen group-containing vinyl monomer is copolymerized as a crosslinkable comonomer, wherein 45 to 65 wt. % of n-butyl acrylate, 10 to 35 wt. % of 2-methoxyethyl acrylate and 8 to 30 wt. % of ethoxyethoxyethyl acrylate are copolymerized in 100 wt. % of comonomers other than the crosslinkable comonomer. This ethoxyethoxyethyl acrylate-copolymerized acrylic rubber can suppress the reduction of oil resistance while improving cold resistance represented by a TR-10 value, and by compounding it with a vulcanizing agent corresponding to the crosslinkable group thereof, a crosslinkable composition is formed.
Compositions and methods for crosslinking polymers in the presence of atmospheric oxygen
Embodiments of organic peroxide formulations provide significant improvements in surface tackiness (often including tack-free surfaces) when curing elastomers in the presence of oxygen. The peroxide formulations may include, for example, one or more compounds selected from sulfur-containing compounds, organophosphite compounds, HALS (Hindered Amine Light Stabilizer) compounds, aliphatic allyl urethane compounds, and blends comprising nitroxides (e.g., 4-hydroxy-TEMPO) and quinones (e.g., mono-tert-butylhydroquinone).