Photocurable colloid binders are provided that overcome deficiencies associated with 3D printing of high molecular weight polymers via VAT photopolymerization. Methods of additive manufacturing are also provided using the binders. The approaches described herein effectively decouple the viscosity-molecular weight relationship by synthesizing and processing photo-reactive aqueous colloids that are sequestered within a photocrosslinkable scaffold. Sequestering polymers within discrete internal phases prevents inter-particle entanglement of the polymer chains, thus ensuring low viscosity. VP of polymer colloids results in a solid green body embedded with high molecular weight polymer particles. A post-processing heated drying step allows the polymers to coalesce and further entangle, forming a semi-interpenetrating network with mechanical performance of the high molecular weight material. The resins can further include inorganic particles such as silica and other ceramics, metal particles, and the like. The coalescence can result in the particles being encapsulated in polymer, yielding unique hybrid materials with tunable properties.

Photocurable colloid binders are provided that overcome deficiencies associated with 3D printing of high molecular weight polymers via VAT photopolymerization. Methods of additive manufacturing are also provided using the binders. The approaches described herein effectively decouple the viscosity-molecular weight relationship by synthesizing and processing photo-reactive aqueous colloids that are sequestered within a photocrosslinkable scaffold. Sequestering polymers within discrete internal phases prevents inter-particle entanglement of the polymer chains, thus ensuring low viscosity. VP of polymer colloids results in a solid green body embedded with high molecular weight polymer particles. A post-processing heated drying step allows the polymers to coalesce and further entangle, forming a semi-interpenetrating network with mechanical performance of the high molecular weight material. The resins can further include inorganic particles such as silica and other ceramics, metal particles, and the like. The coalescence can result in the particles being encapsulated in polymer, yielding unique hybrid materials with tunable properties.

A thermally releasable adhesive member includes a base resin and microcapsules dispersed in the base resin. At least one of the microcapsules includes a shell part which comprises a hydrophobic polymer material, and a hollow part which is defined by the shell part and contains an organic solvent.

A polymer additive powder composition comprising (a) slip agent(s); (b) antiblock agent(s); and (c) optionally one or more components; wherein the slip to antiblock agent(s) is in the range of 80:20 to 95:5 parts by weight and wherein the slip agent encapsulates the antiblock agent(s).

A polymer additive powder composition comprising (a) slip agent(s); (b) antiblock agent(s); and (c) optionally one or more components; wherein the slip to antiblock agent(s) is in the range of 80:20 to 95:5 parts by weight and wherein the slip agent encapsulates the antiblock agent(s).

A polymer additive powder composition comprising (a) slip agent(s); (b) antiblock agent(s); and (c) optionally one or more components; wherein the slip to antiblock agent(s) is in the range of 80:20 to 95:5 parts by weight and wherein the slip agent encapsulates the antiblock agent(s).

A fluororubber composition that is a kneaded mixture of a carbon nanotube masterbatch comprising 4 to 20 parts by weight of multilayer carbon nanotubes, which are fibrous carbon nanostructures that do not contain monolayer carbon nanotubes, based on 100 parts by weight of a fluororubber polymer, and a fluororubber raw material comprising at least a fluororubber polymer and a reinforcing filler, in which the multilayer carbon nanotubes are compounded in an amount of 0.5 to 6 wt. % in the kneaded mixture. The kneading is performed using a roll or a kneader when the fluororubber composition is produced. The fluororubber composition can provide a fluororubber crosslinked molded article that exhibits abrasion resistance and blister resistance.

A fluororubber composition that is a kneaded mixture of a carbon nanotube masterbatch comprising 4 to 20 parts by weight of multilayer carbon nanotubes, which are fibrous carbon nanostructures that do not contain monolayer carbon nanotubes, based on 100 parts by weight of a fluororubber polymer, and a fluororubber raw material comprising at least a fluororubber polymer and a reinforcing filler, in which the multilayer carbon nanotubes are compounded in an amount of 0.5 to 6 wt. % in the kneaded mixture. The kneading is performed using a roll or a kneader when the fluororubber composition is produced. The fluororubber composition can provide a fluororubber crosslinked molded article that exhibits abrasion resistance and blister resistance.

A layered structure including a luminescent layer including a quantum dot polymer composite pattern; an inorganic layer disposed on the luminescent layer, the inorganic layer including a metal oxide, a metal nitride, a metal oxynitride, a metal sulfide, or a combination thereof; and an organic layer being disposed between the luminescent layer and the inorganic layer, the organic layer including an organic polymer, a method of producing the same, and a liquid crystal display including the same. The quantum dot polymer composite pattern includes a repeating section including a polymer matrix; and a plurality of quantum dots (e.g., dispersed) in the polymer matrix, the repeating unit including a first section configured to emit light of a first light, and wherein the inorganic layer is disposed on at least a portion of a surface of the repeating section.

A layered structure including a luminescent layer including a quantum dot polymer composite pattern; an inorganic layer disposed on the luminescent layer, the inorganic layer including a metal oxide, a metal nitride, a metal oxynitride, a metal sulfide, or a combination thereof; and an organic layer being disposed between the luminescent layer and the inorganic layer, the organic layer including an organic polymer, a method of producing the same, and a liquid crystal display including the same. The quantum dot polymer composite pattern includes a repeating section including a polymer matrix; and a plurality of quantum dots (e.g., dispersed) in the polymer matrix, the repeating unit including a first section configured to emit light of a first light, and wherein the inorganic layer is disposed on at least a portion of a surface of the repeating section.