A ply-bonding agent or adhesive composition characterized by a viscosity and a surface tension for the manufacture of paper tissue and paper towel, includes: (a) water; (b) nanofibrillated cellulose; and (c) one or more modifiers effective to modify either or both of (i) the viscosity of the composition or (ii) the surface tension of the composition, wherein the one or more additional modifiers are selected from the group consisting of components (iii), (iv), (v), (vi), (vii) or (viii), wherein: (iii) is PVOH and a viscosity modifier; (iv) is a viscosity modifier; (v) is a viscosity modifier and a surface tension modifier other than PVOH; (vi) is a water-soluble cellulose derivative; (vii) is a water soluble polyol; and (viii) is a surface tension modifier other than PVOH. The compositions are particularly useful for ply-bonding multi-ply absorbent sheet when the plies are treated with debonder.

A ply-bonding agent or adhesive composition characterized by a viscosity and a surface tension for the manufacture of paper tissue and paper towel, includes: (a) water; (b) nanofibrillated cellulose; and (c) one or more modifiers effective to modify either or both of (i) the viscosity of the composition or (ii) the surface tension of the composition, wherein the one or more additional modifiers are selected from the group consisting of components (iii), (iv), (v), (vi), (vii) or (viii), wherein: (iii) is PVOH and a viscosity modifier; (iv) is a viscosity modifier; (v) is a viscosity modifier and a surface tension modifier other than PVOH; (vi) is a water-soluble cellulose derivative; (vii) is a water soluble polyol; and (viii) is a surface tension modifier other than PVOH. The compositions are particularly useful for ply-bonding multi-ply absorbent sheet when the plies are treated with debonder.

A fine cellulose fiber composite in which a modifying group is bound to a carboxy group of fine cellulose fibers, the fine cellulose fibers having a carboxy group content of 0.1 mmol/g or more, wherein the fine cellulose fiber composite has an average aspect ratio of 1 or more and 150 or less; and a resin composition containing the fine cellulose fiber composite and a resin. The resin composition containing a fine cellulose fiber composite of the present invention has excellent heat resistance, and the molded article of this resin composition has excellent mechanical strength, heat resistance, and dimensional stability. Accordingly, the present invention can be suitably used in various industrial applications such as daily sundries, household electric appliance parts, wrapping materials for household electric appliance parts, and automobile parts.

A fine cellulose fiber composite in which a modifying group is bound to a carboxy group of fine cellulose fibers, the fine cellulose fibers having a carboxy group content of 0.1 mmol/g or more, wherein the fine cellulose fiber composite has an average aspect ratio of 1 or more and 150 or less; and a resin composition containing the fine cellulose fiber composite and a resin. The resin composition containing a fine cellulose fiber composite of the present invention has excellent heat resistance, and the molded article of this resin composition has excellent mechanical strength, heat resistance, and dimensional stability. Accordingly, the present invention can be suitably used in various industrial applications such as daily sundries, household electric appliance parts, wrapping materials for household electric appliance parts, and automobile parts.

A method for manufacturing a fibrous cellulose having a high resin reinforcing effect and a method for manufacturing a fibrous cellulose composite resin having high strength. A method for manufacturing a fibrous cellulose includes: a step of subjecting a cellulose raw material and at least one of urea and a derivative of urea to a heat treatment to replace a part or all of hydroxyl groups of the cellulose raw material with carbamate groups; and a step of defibrating the cellulose raw material within a range in which an average fiber width is 0.1 μm or more. The heat treatment is performed under a condition that organic acid ions are added in an amount of 0.001 mmol or more with respect to 1 g of the urea and the derivative of urea. In addition, a fibrous cellulose thus obtained and a resin are kneaded to manufacture a fibrous cellulose composite resin.

The present invention relates to a product comprising cellulose fibers wherein the cellulose fibers are at least partly modified to contain dialcohol cellulose and a melt-processing method of preparing the same.

The present invention relates to a product comprising cellulose fibers wherein the cellulose fibers are at least partly modified to contain dialcohol cellulose and a melt-processing method of preparing the same.

A fibrous cellulose-containing material capable of significantly improving resin strength and a method of preparation thereof, as well as a fibrous cellulose composite resin excellent in strength. The fibrous cellulose-containing material contains fibrous cellulose which is a carbamate-modified microfiber cellulose having hydroxyl groups, part or all of which are substituted with carbamate groups, and having an average fiber width of not smaller than 0.1 μm, and contains powder that is non-interactive with the fibrous cellulose. The fibrous cellulose composite resin contains fibrous cellulose which is the above-mentioned fibrous cellulose-containing material, and part or all of the resin is powdered resin. The method for preparing a fibrous cellulose-containing material includes adding at least either of powder that is non-interactive with fibrous cellulose and a dispersion thereof, to a dispersion of carbamate-modified microfiber cellulose to obtain a mixed liquid, and removing the dispersion medium from the mixed liquid.

A fibrous cellulose-containing material capable of significantly improving resin strength and a method of preparation thereof, as well as a fibrous cellulose composite resin excellent in strength. The fibrous cellulose-containing material contains fibrous cellulose which is a carbamate-modified microfiber cellulose having hydroxyl groups, part or all of which are substituted with carbamate groups, and having an average fiber width of not smaller than 0.1 μm, and contains powder that is non-interactive with the fibrous cellulose. The fibrous cellulose composite resin contains fibrous cellulose which is the above-mentioned fibrous cellulose-containing material, and part or all of the resin is powdered resin. The method for preparing a fibrous cellulose-containing material includes adding at least either of powder that is non-interactive with fibrous cellulose and a dispersion thereof, to a dispersion of carbamate-modified microfiber cellulose to obtain a mixed liquid, and removing the dispersion medium from the mixed liquid.

A fibrous cellulose has an average fiber width of 0.1 .Math.m or more and has a part or all of hydroxyl groups replaced with carbamate groups, in which a replacement ratio with the carbamate group is 1.0 mmol/g or more, and a fine ratio is 30% or more. A fibrous cellulose composite resin contains a fibrous cellulose and a resin, and the above fibrous cellulose In manufacturing fibrous cellulose, a cellulose raw material and urea or the like are subjected to a heat treatment to replace a part or all of hydroxyl groups of the cellulose raw material with carbamate groups, defibration is performed within a range in which an average fiber width is 0.1 .Math.m or more, the heat treatment is performed such that a replacement ratio with the carbamate group is 1.0 mmol/g or more, and the defibration is performed until a fine ratio reaches 30% or more.