A method for producing a dip-molded article, the method including steps of immersing a mold for dip molding in a coagulant solution to deposit the coagulant on the mold for dip molding; providing a latex composition containing a carboxy-modified conjugated diene polymer latex which is a dispersion of carboxy-modified conjugated diene polymer particles having a volume average particle size of 500 to 2,000 nm in water; and immersing the mold for dip molding having the coagulant deposited thereon in the latex composition to obtain a dip-molded article having a thickness of 0.02 to 0.19 mm.

Disclosed is a dip-formed article comprising a layer derived from a latex composition for dip-forming, wherein the latex composition for dip-forming contains a carboxylic acid-modified nitrile-based copolymer latex, the carboxylic acid-modified nitrile-based copolymer latex contains a carboxylic acid-modified nitrile-based copolymer, and the dip-formed article has an elongation of more than 650% and satisfies the following Expressions 1 and 2,

[Expression 1]

k.sub.1′+k.sub.2′+k.sub.3′≤9.3 N/mm  (1)

[Expression 2]

0.55≤k.sub.1′/(k.sub.1′+k.sub.2′+k.sub.3′)  (2)

wherein k.sub.1′ is a value obtained by dividing an equilibrium coefficient k.sub.1 by a thickness of a test piece, and k.sub.2′ and k.sub.3′ are values obtained by dividing viscous coefficients k.sub.2 and k.sub.3 by the thickness of the test piece, respectively.

Provided is a chloroprene rubber latex adhesive composition superior in initial adhesive strength and normal adhesive strength and also in thermal creep resistance with adherend. A chloroprene rubber latex adhesive composition includes a carboxy-modified chloroprene-based copolymer latex (A) containing a copolymer of chloroprene monomer and an ethylenic unsaturated carboxylic acid and a polyvinylalcohol, a chloroprene-based polymer latex (B) containing a chloroprene homopolymer or a copolymer of chloroprene monomer and other monomer and a rosin acid metal salt and a chlorinated polyolefin resin emulsion (C), wherein the content ratio of the carboxy-modified chloroprene-based copolymer latex (A) to the chloroprene-based polymer latex (B) is 80:20 to 20:80 as solid matter.

Provided is a chloroprene rubber latex adhesive composition superior in initial adhesive strength and normal adhesive strength and also in thermal creep resistance with adherend. A chloroprene rubber latex adhesive composition includes a carboxy-modified chloroprene-based copolymer latex (A) containing a copolymer of chloroprene monomer and an ethylenic unsaturated carboxylic acid and a polyvinylalcohol, a chloroprene-based polymer latex (B) containing a chloroprene homopolymer or a copolymer of chloroprene monomer and other monomer and a rosin acid metal salt and a chlorinated polyolefin resin emulsion (C), wherein the content ratio of the carboxy-modified chloroprene-based copolymer latex (A) to the chloroprene-based polymer latex (B) is 80:20 to 20:80 as solid matter.

A semi transparent nitrile glove comprising nitrile latex, caustic alkali, accelerators, vulcanizing agents, stabilizer and antifoaming agent, wherein the nitrile latex is any one selected from either acrylonitrile butadiene copolymer or carboxylated acrylonitrile butadiene copolymer, wherein the caustic alkali is a combination of either potassium hydroxide and ammonia or sodium hydroxide and ammonia, wherein the accelerators are chemical compounds of dithiocarbamates, wherein the vulcanizing agents are selected from both ionic and covalent vulcanizing agents, wherein the stabilizer is any one of either sodium dodecylbenzene sulfonate or sodium dodecyl sulfate and wherein the antifoaming agent is any one from a group consisting of silicone based antifoam, non-silicone based antifoam, oil based antifoam and water based antifoam wherein the semi transparent glove is without pigment and without titanium dioxide.

A semi transparent nitrile glove comprising nitrile latex, caustic alkali, accelerators, vulcanizing agents, stabilizer and antifoaming agent, wherein the nitrile latex is any one selected from either acrylonitrile butadiene copolymer or carboxylated acrylonitrile butadiene copolymer, wherein the caustic alkali is a combination of either potassium hydroxide and ammonia or sodium hydroxide and ammonia, wherein the accelerators are chemical compounds of dithiocarbamates, wherein the vulcanizing agents are selected from both ionic and covalent vulcanizing agents, wherein the stabilizer is any one of either sodium dodecylbenzene sulfonate or sodium dodecyl sulfate and wherein the antifoaming agent is any one from a group consisting of silicone based antifoam, non-silicone based antifoam, oil based antifoam and water based antifoam wherein the semi transparent glove is without pigment and without titanium dioxide.

A latex composition having a nitrile rubber containing an α,β-ethylenically unsaturated nitrile monomer unit and a conjugated diene monomer unit, wherein the nitrile rubber has a weight average molecular weight of 50,000 to 100,000, and the weight of methanol extractables in all solids present in the latex composition is 2 to 20 wt % based on the weight of all the solids.

A latex composition having a nitrile rubber containing an α,β-ethylenically unsaturated nitrile monomer unit and a conjugated diene monomer unit, wherein the nitrile rubber has a weight average molecular weight of 50,000 to 100,000, and the weight of methanol extractables in all solids present in the latex composition is 2 to 20 wt % based on the weight of all the solids.

A latex composition having a nitrile rubber containing an α,β-ethylenically unsaturated nitrile monomer unit and a conjugated diene monomer unit, wherein the nitrile rubber has a weight average molecular weight of 50,000 to 100,000, and the weight of methanol extractables in all solids present in the latex composition is 2 to 20 wt % based on the weight of all the solids.

Provided is a carboxylic acid-modified nitrile-based copolymer latex, and more particularly, provided are a carboxylic acid-modified nitrile-based copolymer latex which includes a carboxylic acid-modified nitrile-based copolymer including a monomer-derived repeating unit; and a repeating unit derived from a monomer represented by Chemical Formula 1 below, the monomer-derived repeating unit including a conjugated diene-based monomer-derived repeating unit, an ethylenically unsaturated nitrile-based monomer-derived repeating unit, and an ethylenically unsaturated acid monomer-derived repeating unit (see description of the present invention), a method for preparing a carboxylic acid-modified nitrile-based copolymer latex, a latex composition for dip-forming including the copolymer latex, and an article formed by the composition.