A surface-mineralized substrate having an enhanced functional capability, for example, enhanced antibacterial activity, a method of making the surface-mineralized substrate, and an article of manufacture, for example, packaging for fresh produce, comprising or formed from or of the surface-mineralized substrate.

Disclosed are compounds of Formula 1, including all geometric and stereoisomers, N-oxides, and salts thereof,

##STR00001##

wherein

Q is

##STR00002##

and A, R.sup.1, m, X.sup.1, X.sup.2, X.sup.3, X.sup.4, Y.sup.1, Y.sup.2 and Y.sup.3 are as defined in the disclosure. Also disclosed are compositions containing the compounds of Formula 1 and methods for controlling an invertebrate pest comprising contacting the invertebrate pest or its environment with a biologically effective amount of a compound or a composition of the invention.

Disclosed are compounds of Formula 1, including all geometric and stereoisomers, N-oxides, and salts thereof,

##STR00001##

wherein

Q is

##STR00002##

and A, R.sup.1, m, X.sup.1, X.sup.2, X.sup.3, X.sup.4, Y.sup.1, Y.sup.2 and Y.sup.3 are as defined in the disclosure. Also disclosed are compositions containing the compounds of Formula 1 and methods for controlling an invertebrate pest comprising contacting the invertebrate pest or its environment with a biologically effective amount of a compound or a composition of the invention.

Granular compositions comprising at least one herbicide that inhibits microtubule assembly, at least one herbicide that inhibits cell wall synthesis, and a surfactant, and methods for making and using such compositions, are generally described.

Granular compositions comprising at least one herbicide that inhibits microtubule assembly, at least one herbicide that inhibits cell wall synthesis, and a surfactant, and methods for making and using such compositions, are generally described.

Architectural structures including an inorganic material carrier including cement and particles or fibers of a glass including a plurality of Cu.sup.1+ ions. In aspects, the glass may have a glass phase and a cuprite phase. In aspects, the glasses may include a plurality of Cu.sup.1+ ions, a degradable phase including B.sub.2O.sub.3, P.sub.2O.sub.5 and K.sub.2O and a durable phase including SiO.sub.2. In other aspects, the glass can have a plurality of Cu.sup.1+ ions disposed on the surface of the glass and in the glass network and/or the glass matrix. The glasses and articles disclosed herein can exhibit a 2 log reduction or greater in a concentration of at least one of Staphylococcus aureus, Enterobacter aerogenes, Pseudomonas aeruginosa bacteria, Methicillin Resistant Staphylococcus aureus, and E. coli, under the EPA Test Method for Efficacy of Copper Alloy as a Sanitizer testing condition and under Modified JIS Z 2801 for Bacteria testing conditions.

Architectural structures including an inorganic material carrier including cement and particles or fibers of a glass including a plurality of Cu.sup.1+ ions. In aspects, the glass may have a glass phase and a cuprite phase. In aspects, the glasses may include a plurality of Cu.sup.1+ ions, a degradable phase including B.sub.2O.sub.3, P.sub.2O.sub.5 and K.sub.2O and a durable phase including SiO.sub.2. In other aspects, the glass can have a plurality of Cu.sup.1+ ions disposed on the surface of the glass and in the glass network and/or the glass matrix. The glasses and articles disclosed herein can exhibit a 2 log reduction or greater in a concentration of at least one of Staphylococcus aureus, Enterobacter aerogenes, Pseudomonas aeruginosa bacteria, Methicillin Resistant Staphylococcus aureus, and E. coli, under the EPA Test Method for Efficacy of Copper Alloy as a Sanitizer testing condition and under Modified JIS Z 2801 for Bacteria testing conditions.

Architectural structures including an inorganic material carrier including cement and particles or fibers of a glass including a plurality of Cu.sup.1+ ions. In aspects, the glass may have a glass phase and a cuprite phase. In aspects, the glasses may include a plurality of Cu.sup.1+ ions, a degradable phase including B.sub.2O.sub.3, P.sub.2O.sub.5 and K.sub.2O and a durable phase including SiO.sub.2. In other aspects, the glass can have a plurality of Cu.sup.1+ ions disposed on the surface of the glass and in the glass network and/or the glass matrix. The glasses and articles disclosed herein can exhibit a 2 log reduction or greater in a concentration of at least one of Staphylococcus aureus, Enterobacter aerogenes, Pseudomonas aeruginosa bacteria, Methicillin Resistant Staphylococcus aureus, and E. coli, under the EPA Test Method for Efficacy of Copper Alloy as a Sanitizer testing condition and under Modified JIS Z 2801 for Bacteria testing conditions.

Antimicrobial compositions comprising one or more compound components generally recognized as safe for human consumption, and related methods of use, such compositions and methods as can be employed in a wide range of agricultural, industrial, building, pharmaceutical and/or personal care products and applications.

Antimicrobial compositions comprising one or more compound components generally recognized as safe for human consumption, and related methods of use, such compositions and methods as can be employed in a wide range of agricultural, industrial, building, pharmaceutical and/or personal care products and applications.