Patent classifications
C08L27/22
Non-humidified proton-conductive membrane, method for producing the same, and fuel cell
A non-humidified proton-conductive membrane according to the present invention includes a polymer and a proton-conductive substance. The polymer includes a glassy or crystalline first site having a glass-transition temperature or melting temperature higher than the service temperature of the proton-conductive membrane and a second site capable of forming a noncovalent bond. The proton-conductive substance includes a proton-releasing/binding site capable of noncovalently binding to the second site of the polymer and a proton coordination site capable of coordinating to protons, the proton-releasing/binding site and the proton coordination site being included in different molecules that interact with each other or being included in the same molecule. A proton-conductive mixed phase that includes the second site to which the proton-releasing/binding site of the proton-conductive substance is bound and the proton-conductive substance is lower than the service temperature of the proton-conductive membrane. The amount of the proton-releasing/binding site is excessively large compared with the amount of the second site of the polymer.
Non-humidified proton-conductive membrane, method for producing the same, and fuel cell
A non-humidified proton-conductive membrane according to the present invention includes a polymer and a proton-conductive substance. The polymer includes a glassy or crystalline first site having a glass-transition temperature or melting temperature higher than the service temperature of the proton-conductive membrane and a second site capable of forming a noncovalent bond. The proton-conductive substance includes a proton-releasing/binding site capable of noncovalently binding to the second site of the polymer and a proton coordination site capable of coordinating to protons, the proton-releasing/binding site and the proton coordination site being included in different molecules that interact with each other or being included in the same molecule. A proton-conductive mixed phase that includes the second site to which the proton-releasing/binding site of the proton-conductive substance is bound and the proton-conductive substance is lower than the service temperature of the proton-conductive membrane. The amount of the proton-releasing/binding site is excessively large compared with the amount of the second site of the polymer.
Containers Containing Degradable Carriers
This disclosure relates to containers and substrates comprising a fluoropolymer and having a textured inner surface and to methods for cultivating and/or isolating a biological agent using such containers and substrates. In one embodiment, the disclosure provides a container (e.g., in the form of a bag) having an outer surface and a textured inner surface, the inner surface comprising a fluoropolymer, wherein the textured inner surface comprises one or more of (a) a plurality of functional groups attached to the fluoropolymer, and (b) a pattern of spaced features, the features having an average spacing within the range of 0.1 m to 200 m.
Containers Containing Degradable Carriers
This disclosure relates to containers and substrates comprising a fluoropolymer and having a textured inner surface and to methods for cultivating and/or isolating a biological agent using such containers and substrates. In one embodiment, the disclosure provides a container (e.g., in the form of a bag) having an outer surface and a textured inner surface, the inner surface comprising a fluoropolymer, wherein the textured inner surface comprises one or more of (a) a plurality of functional groups attached to the fluoropolymer, and (b) a pattern of spaced features, the features having an average spacing within the range of 0.1 m to 200 m.
CHLOROPRENE RUBBER LATEX ADHESIVE COMPOSITION
Provided is a chloroprene rubber latex adhesive composition superior in initial adhesive strength and normal adhesive strength and also in thermal creep resistance with adherend. A chloroprene rubber latex adhesive composition includes a carboxy-modified chloroprene-based copolymer latex (A) containing a copolymer of chloroprene monomer and an ethylenic unsaturated carboxylic acid and a polyvinylalcohol, a chloroprene-based polymer latex (B) containing a chloroprene homopolymer or a copolymer of chloroprene monomer and other monomer and a rosin acid metal salt and a chlorinated polyolefin resin emulsion (C), wherein the content ratio of the carboxy-modified chloroprene-based copolymer latex (A) to the chloroprene-based polymer latex (B) is 80:20 to 20:80 as solid matter.
CHLOROPRENE RUBBER LATEX ADHESIVE COMPOSITION
Provided is a chloroprene rubber latex adhesive composition superior in initial adhesive strength and normal adhesive strength and also in thermal creep resistance with adherend. A chloroprene rubber latex adhesive composition includes a carboxy-modified chloroprene-based copolymer latex (A) containing a copolymer of chloroprene monomer and an ethylenic unsaturated carboxylic acid and a polyvinylalcohol, a chloroprene-based polymer latex (B) containing a chloroprene homopolymer or a copolymer of chloroprene monomer and other monomer and a rosin acid metal salt and a chlorinated polyolefin resin emulsion (C), wherein the content ratio of the carboxy-modified chloroprene-based copolymer latex (A) to the chloroprene-based polymer latex (B) is 80:20 to 20:80 as solid matter.
FLUOROSULFONYL GROUP-CONTAINING COMPOUND, FLUOROSULFONYL GROUP-CONTAINING MONOMER, AND THEIR PRODUCTION METHODS
A method for producing a fluorosulfonyl group-containing compound to obtain a compound represented by the following formula 5 from a compound represented by the following formula 1 as a starting material and a method for producing a fluorosulfonyl group-containing monomer in which the fluorosulfonyl group-containing compound is used:
##STR00001##
wherein R.sup.1 and R.sup.2 are a C.sub.1-3 alkylene group, and R.sup.F1 and R.sup.F2 are a C.sub.1-3 perfluoroalkylene group.
FLUOROSULFONYL GROUP OR SULFONIC ACID GROUP-CONTAINING POLYMER, ITS PRODUCTION METHOD AND ITS APPLICATION
A fluorosulfonyl group-containing polymer having units represented by the following formula u1, a sulfonic acid group-containing polymer having fluorosulfonyl groups in the fluorosulfonyl group-containing polymer converted into sulfonic acid groups, its production method and its applications:
##STR00001##
wherein R.sup.F1 and R.sup.F2 are a C.sub.1-3 perfluoroalkylene group.
FLUOROSULFONYL GROUP OR SULFONIC ACID GROUP-CONTAINING POLYMER, ITS PRODUCTION METHOD AND ITS APPLICATION
A fluorosulfonyl group-containing polymer having units represented by the following formula u1, a sulfonic acid group-containing polymer having fluorosulfonyl groups in the fluorosulfonyl group-containing polymer converted into sulfonic acid groups, its production method and its applications:
##STR00001##
wherein R.sup.F1 and R.sup.F2 are a C.sub.1-3 perfluoroalkylene group.
FLUOROELASTOMER COMPOSITION AND MOLDED ARTICLE THEREOF
The invention provides a fluoroelastomer composition that can be crosslinked at an industrially sufficient rate without the use of a graphene having specific surface properties and can provide a fluoroelastomer molded article having higher tensile strength and better abrasion resistance than conventional fluoroelastomer molded articles even though having a similar tensile modulus to conventional fluoroelastomer molded articles. The fluoroelastomer composition contains a fluoroelastomer that contains a crosslinkable group-containing monomer unit and an elongated sheet-shaped graphene. The graphene exhibits a ratio (L/W) of a maximum length (L) and a width (W) of 2 to 10.sup.5, and the graphene exhibits a ratio (L/T) of the maximum length (L) and a thickness (T) of 110.sup.1 to 110.sup.7.