The present invention provides a maleimide-based copolymer, a method for producing same, and a resin composition obtained using same.

This maleimide-based copolymer contains 40-60 mass % of aromatic vinyl monomer units, 5-20 mass % of vinyl cyanide monomer units, and 35-50 mass % of maleimide monomer units, and is such that a 4 mass % tetrahydrofuran solution of the copolymer has a transmittance of 90% or more for light having a wavelength of 450 nm at an optical path length of 10 mm, and the residual maleimide-based monomer amount is less than 300 ppm. This maleimide-based copolymer preferably further contains 0-10 mass % of unsaturated dicarboxylic acid anhydride monomer units, and preferably has a glass transition temperature of 165° C. or higher.

The present invention provides a maleimide-based copolymer, a method for producing same, and a resin composition obtained using same.

This maleimide-based copolymer contains 40-60 mass % of aromatic vinyl monomer units, 5-20 mass % of vinyl cyanide monomer units, and 35-50 mass % of maleimide monomer units, and is such that a 4 mass % tetrahydrofuran solution of the copolymer has a transmittance of 90% or more for light having a wavelength of 450 nm at an optical path length of 10 mm, and the residual maleimide-based monomer amount is less than 300 ppm. This maleimide-based copolymer preferably further contains 0-10 mass % of unsaturated dicarboxylic acid anhydride monomer units, and preferably has a glass transition temperature of 165° C. or higher.

A process for increasing the chemical resistance of a polymeric composition is provided. The method includes a step of blending: a) the (meth)acrylic polymer AP1 and b) a copolymer CP1. The copolymer CP1 includes at least 41 wt % of vinyl aromatic monomer units by weight of the copolymer CPI. The polymeric composition includes at least 5 wt % of the copolymer CP1, by weight of the polymeric composition. A chemical resistance of the polymeric composition is better than a chemical resistance of the (meth)acrylic polymer AP1 without CP1. Chemical resistance is measured by a time to crack at 120° C. when subjected to an outer radius bending strain of 75% and wetted with a cloth soaked in isopropanol 99%.

A process for increasing the chemical resistance of a polymeric composition is provided. The method includes a step of blending: a) the (meth)acrylic polymer AP1 and b) a copolymer CP1. The copolymer CP1 includes at least 41 wt % of vinyl aromatic monomer units by weight of the copolymer CPI. The polymeric composition includes at least 5 wt % of the copolymer CP1, by weight of the polymeric composition. A chemical resistance of the polymeric composition is better than a chemical resistance of the (meth)acrylic polymer AP1 without CP1. Chemical resistance is measured by a time to crack at 120° C. when subjected to an outer radius bending strain of 75% and wetted with a cloth soaked in isopropanol 99%.

Polar silane linkers are provided that attach to resins to form silane-functionalized resins. The functionalized resins can be bound to hydroxyl groups on the surface of silica particles to improve the dispersibility of the silica particles in rubber mixtures. Further disclosed are synthetic routes to provide the silane-functionalized resins, as well as various uses and end products that benefit from the unexpected properties of the silane-functionalized resins. Silane-functionalized resins impart remarkable properties on various rubber compositions, such as tires, belts, hoses, brakes, and the like. Automobile tires incorporating the silane-functionalized resins are shown to possess excellent results in balancing the properties of rolling resistance, tire wear, and wet braking performance.

Polar silane linkers are provided that attach to resins to form silane-functionalized resins. The functionalized resins can be bound to hydroxyl groups on the surface of silica particles to improve the dispersibility of the silica particles in rubber mixtures. Further disclosed are synthetic routes to provide the silane-functionalized resins, as well as various uses and end products that benefit from the unexpected properties of the silane-functionalized resins. Silane-functionalized resins impart remarkable properties on various rubber compositions, such as tires, belts, hoses, brakes, and the like. Automobile tires incorporating the silane-functionalized resins are shown to possess excellent results in balancing the properties of rolling resistance, tire wear, and wet braking performance.

Provided is a heat-resistant resin composition which includes: a graft copolymer prepared by graft polymerization of a diene-based rubber polymer with an aromatic vinyl-based monomer and a vinyl cyan-based monomer; a first styrene-based copolymer including a maleimide-based unit and an aromatic vinyl-based unit; a second styrene-based copolymer including a vinyl cyan-based unit and an aromatic vinyl-based unit; and a third styrene-based copolymer including a vinyl cyan-based unit and an aromatic vinyl-based unit, wherein the second styrene-based copolymer and the third styrene-based copolymer include a vinyl cyan-based unit in mutually different amounts.

Provided is a heat-resistant resin composition which includes: a graft copolymer prepared by graft polymerization of a diene-based rubber polymer with an aromatic vinyl-based monomer and a vinyl cyan-based monomer; a first styrene-based copolymer including a maleimide-based unit and an aromatic vinyl-based unit; a second styrene-based copolymer including a vinyl cyan-based unit and an aromatic vinyl-based unit; and a third styrene-based copolymer including a vinyl cyan-based unit and an aromatic vinyl-based unit, wherein the second styrene-based copolymer and the third styrene-based copolymer include a vinyl cyan-based unit in mutually different amounts.

Provided herein are a thermoplastic resin composition for a low gloss non-painting, a method for manufacturing a molded article using the same, and a molded article. The thermoplastic resin composition includes a first polycarbonate; a polysiloxane-polycarbonate copolymer; polyester; a master batch including carbon black; a heat resistance improver; and an additive. The molded article manufactured using the same has excellent chemical resistance, mechanical properties, light resistance, hydrolysis resistance, and low gloss properties.

Provided herein are a thermoplastic resin composition for a low gloss non-painting, a method for manufacturing a molded article using the same, and a molded article. The thermoplastic resin composition includes a first polycarbonate; a polysiloxane-polycarbonate copolymer; polyester; a master batch including carbon black; a heat resistance improver; and an additive. The molded article manufactured using the same has excellent chemical resistance, mechanical properties, light resistance, hydrolysis resistance, and low gloss properties.