The present invention relates to moisture curable compositions based on silane-terminated polymers in paste form that can be used as 3D printing materials and provide isotropic and elastomeric properties. The invention further relates to the use thereof as 3D printing materials and printing methods using said compositions.

The present invention relates to moisture curable compositions based on silane-terminated polymers in paste form that can be used as 3D printing materials and provide isotropic and elastomeric properties. The invention further relates to the use thereof as 3D printing materials and printing methods using said compositions.

A branched organosilicon compound (“compound”) is provided having the general formula: (R.sup.1).sub.3Si—X—NR.sup.2R.sup.3, where X is a divalent linking group; R.sup.2 is H or R; R.sup.3 comprises an acryloxy moiety; each R.sup.1 is selected from R and —OSi(R.sup.4).sub.3, with the proviso that at least one R.sup.1 is —OSi(R.sup.4).sub.3; where each R.sup.4 is selected from R, —OSi(R.sup.5).sub.3, and —[OSiR.sub.2]mOSiR.sub.3; where each R.sup.5 is selected from R, —OSi(R.sup.6).sub.3, and —[OSiR.sup.2].sub.mOSiR.sub.3; and where each R.sup.6 is selected from R and —[OSiR.sub.2].sub.mOSiR.sub.3, with the proviso that at least one of R.sup.4, R.sup.5 and R.sup.6 is —[OSiR.sub.2].sub.mOSiR.sub.3; 0≤m≤100; and each R is a substituted or unsubstituted hydrocarbyl group. Also provided is a method of preparing the compound, a copolymer comprising the reaction product of the compound and a second compound reactive with the compound, a method of forming the copolymer, and a composition including at least one of the compound and the copolymer.

A multi-part curable composition includes: an A part including a polyoxyalkylene polymer (A) having a reactive silicon group, a (meth)acrylic ester polymer (B) having a reactive silicon group, and an epoxy resin curing agent (D); and a B part including an epoxy resin (C) and a silanol condensation catalyst (E). The (meth)acrylic ester polymer (B) is a polymer containing constituent monomers including 40 to 70% by weight of an alkyl (meth)acrylate (b1) having an alkyl having 1 to 3 carbon atoms, a monomer (b2) having a reactive silicon group and a polymerizable unsaturated group, and a macromonomer (b3) that is a (meth)acrylic ester polymer having a polymerizable unsaturated group.

A multi-part curable composition includes: an A part including a polyoxyalkylene polymer (A) having a reactive silicon group, a (meth)acrylic ester polymer (B) having a reactive silicon group, and an epoxy resin curing agent (D); and a B part including an epoxy resin (C) and a silanol condensation catalyst (E). The (meth)acrylic ester polymer (B) is a polymer containing constituent monomers including 40 to 70% by weight of an alkyl (meth)acrylate (b1) having an alkyl having 1 to 3 carbon atoms, a monomer (b2) having a reactive silicon group and a polymerizable unsaturated group, and a macromonomer (b3) that is a (meth)acrylic ester polymer having a polymerizable unsaturated group.

A copolymer having excellent water resistance and sebum resistance while also exhibiting high washability is provided. Also provided is a composition and cosmetic material containing the copolymer. The copolymer is generally polymerized from a monomer composition comprising: (A) a carbosiloxane dendrimer monomer having a radically polymerizable organic group; and (B) an unsaturated monomer having at least one acidic group or a salt thereof per molecule; wherein monomer (A) is present in the monomer composition in an amount greater than or equal to 30 wt. % relative to the weight of the monomer composition, and a weight ratio (A/B) of monomer (A) to monomer (B) is from 1.0 to 20.0.

A copolymer having excellent water resistance and sebum resistance while also exhibiting high washability is provided. Also provided is a composition and cosmetic material containing the copolymer. The copolymer is generally polymerized from a monomer composition comprising: (A) a carbosiloxane dendrimer monomer having a radically polymerizable organic group; and (B) an unsaturated monomer having at least one acidic group or a salt thereof per molecule; wherein monomer (A) is present in the monomer composition in an amount greater than or equal to 30 wt. % relative to the weight of the monomer composition, and a weight ratio (A/B) of monomer (A) to monomer (B) is from 1.0 to 20.0.

A catalyst system comprising a combination of a tin-based moisture-cure catalyst, a titanium(IV) compound that is titanium dioxide or a titanium alkoxide, and zinc oxide. A catalyst masterbatch comprising the catalyst system and a carrier resin. A moisture-curable prepolymer formulation comprising the catalyst masterbatch and a (hydrolyzable silyl group)-functional polyolefin prepolymer. Methods of making and using same. Cured polymer products made therefrom. Articles containing or made from same.

A catalyst system comprising a combination of a tin-based moisture-cure catalyst, a titanium(IV) compound that is titanium dioxide or a titanium alkoxide, and zinc oxide. A catalyst masterbatch comprising the catalyst system and a carrier resin. A moisture-curable prepolymer formulation comprising the catalyst masterbatch and a (hydrolyzable silyl group)-functional polyolefin prepolymer. Methods of making and using same. Cured polymer products made therefrom. Articles containing or made from same.

A curable composition containing a polyoxyalkylene polymer (A) having a reactive silyl group and a (meth)acrylic ester polymer (B) having a reactive silyl group is provided. In the polyoxyalkylene polymer (A), an average ratio per molecule of a number of reactive silyl groups to a number of ends of a polymer backbone is 0.80 or more. In the (meth)acrylic ester polymer (B), an average number per molecule of the reactive silyl groups bonded at ends of a polymer backbone is from 0.30 to 1.00, and the average number per molecule of the reactive silyl groups bonded inside the polymer backbone is from 0 to less than 0.30.