C08L51/02

VINYL ACRYLIC COPOLYMERS AND METHODS OF MAKING AND USE THEREOF
20220363797 · 2022-11-17 ·

Described herein are compositions comprising a vinyl acrylic copolymer derived in the presence of maltodextrin. In some examples, the compositions comprise a copolymer derived from: vinyl acetate; an acrylate monomer having a T.sub.g of −30° C. or less; a carboxylic acid, a carboxylic acid anhydride, or a combination thereof; and an organosilane; in the presence of maltodextrin. The copolymer can be provided as an aqueous dispersion. In some examples, the aqueous dispersion can have an overall solids content of from 40% to 75%. Also disclosed herein are carpet tiles having a surface coated with the adhesive formulations disclosed herein. In some examples, the carpet tile with the adhesive formulation applied thereto can pass the British spill test. Also disclosed herein are methods of making the compositions disclosed herein.

Composite for cellulose fiber dispersion and cellulose fiber composition

Provided are a composite for cellulose fiber dispersion that can inexpensively and sufficiently disperse cellulose fibers, particularly nanocellulose, in a hydrophobic resin and a cellulose fiber composition containing the composite. A composite for cellulose fiber dispersion according to the present invention has a structure in which a vinyl polymer is grafted to a cellulose derivative. A cellulose fiber composition according to the present invention contains the composite and cellulose fibers and more specifically also contains an organic solvent, a resin precursor, or a resin.

Vinyl acrylic copolymers and methods of making and use thereof
11427667 · 2022-08-30 · ·

Described herein are compositions comprising a vinyl acrylic copolymer derived in the presence of maltodextrin. In some examples, the compositions comprise a copolymer derived from: vinyl acetate; an acrylate monomer having a Tg of −30° C. or less; a carboxylic acid, a carboxylic acid anhydride, or a combination thereof; and an organosilane; in the presence of maltodextrin. The copolymer can be provided as an aqueous dispersion. In some examples, the aqueous dispersion can have an overall solids content of from 40% to 75%. Also disclosed herein are carpet tiles having a surface coated with the adhesive formulations disclosed herein. In some examples, the carpet tile with the adhesive formulation applied thereto can pass the British spill test. Also disclosed herein are methods of making the compositions disclosed herein.

Vinyl acrylic copolymers and methods of making and use thereof
11427667 · 2022-08-30 · ·

Described herein are compositions comprising a vinyl acrylic copolymer derived in the presence of maltodextrin. In some examples, the compositions comprise a copolymer derived from: vinyl acetate; an acrylate monomer having a Tg of −30° C. or less; a carboxylic acid, a carboxylic acid anhydride, or a combination thereof; and an organosilane; in the presence of maltodextrin. The copolymer can be provided as an aqueous dispersion. In some examples, the aqueous dispersion can have an overall solids content of from 40% to 75%. Also disclosed herein are carpet tiles having a surface coated with the adhesive formulations disclosed herein. In some examples, the carpet tile with the adhesive formulation applied thereto can pass the British spill test. Also disclosed herein are methods of making the compositions disclosed herein.

RESIN COMPOSITION, METHOD FOR PRODUCING RESIN COMPOSITION, AND MOLDED ARTICLE
20220235217 · 2022-07-28 · ·

A resin composition or the like may exhibit high vibration damping properties even at a relatively high temperature, have good moldability, and have excellent impact resistance. The resin composition contains a thermoplastic resin (A), a thermoplastic resin (B), and a polar resin (C), wherein the resin composition satisfies (1) to (3): (1) the thermoplastic resin (B) has at least one of a reactive functional group and a monomer unit containing a hetero atom; (2) the thermoplastic resin (A) and the thermoplastic resin (B) are different types of resins; (3) with respect to the total mass of the resin composition, the content of the thermoplastic resin (A) is 1 to 30% by mass, the content of the thermoplastic resin (B) is 1 to 30% by mass, and the content of the polar resin (C) is 40 to 98% by mass.

RESIN COMPOSITION, METHOD FOR PRODUCING RESIN COMPOSITION, AND MOLDED ARTICLE
20220235217 · 2022-07-28 · ·

A resin composition or the like may exhibit high vibration damping properties even at a relatively high temperature, have good moldability, and have excellent impact resistance. The resin composition contains a thermoplastic resin (A), a thermoplastic resin (B), and a polar resin (C), wherein the resin composition satisfies (1) to (3): (1) the thermoplastic resin (B) has at least one of a reactive functional group and a monomer unit containing a hetero atom; (2) the thermoplastic resin (A) and the thermoplastic resin (B) are different types of resins; (3) with respect to the total mass of the resin composition, the content of the thermoplastic resin (A) is 1 to 30% by mass, the content of the thermoplastic resin (B) is 1 to 30% by mass, and the content of the polar resin (C) is 40 to 98% by mass.

COMPOSITE FOR CELLULOSE FIBER DISPERSION AND CELLULOSE FIBER COMPOSITION

Provided are a composite for cellulose fiber dispersion that can inexpensively and sufficiently disperse cellulose fibers, particularly nanocellulose, in a hydrophobic resin and a cellulose fiber composition containing the composite. A composite for cellulose fiber dispersion according to the present invention has a structure in which a vinyl polymer is grafted to a cellulose derivative. A cellulose fiber composition according to the present invention contains the composite and cellulose fibers and more specifically also contains an organic solvent, a resin precursor, or a resin.

BIAXIALLY AND MONOAXIALLY ORIENTED FILMS, LAMINATES AND OTHER STRUCTURES INCLUDING STARCH-BASED POLYMERIC MATERIALS

Described herein are starch-based materials, and formulations including such for use in directional alignment extrusion processes. The present compositions exhibit critical shear stress characteristics that allow extrusion at high shear rates and line speeds, without onset of melt flow instability. The present compositions provide sufficient melt strength to allow such compositions to be directionally oriented by stretching the heated polymer (e.g., the polymer melt) following initial extrusion, directionally aligning the molecular chains of the heated polymer blend in the machine-direction, the cross-direction, or both. In an embodiment, the starch-based material is blended with one or more thermoplastic materials having desired melt flow index value(s), which serves as a diluent, allowing the very viscous starch-based component to be processed under such conditions. The starch-based materials (and masterbatches thereof) may exhibit high molecular weight, high shear sensitivity, strain hardening behavior, and/or a very high critical shear stress (e.g., at least 125 kPa).

BIAXIALLY AND MONOAXIALLY ORIENTED FILMS, LAMINATES AND OTHER STRUCTURES INCLUDING STARCH-BASED POLYMERIC MATERIALS

Described herein are starch-based materials, and formulations including such for use in directional alignment extrusion processes. The present compositions exhibit critical shear stress characteristics that allow extrusion at high shear rates and line speeds, without onset of melt flow instability. The present compositions provide sufficient melt strength to allow such compositions to be directionally oriented by stretching the heated polymer (e.g., the polymer melt) following initial extrusion, directionally aligning the molecular chains of the heated polymer blend in the machine-direction, the cross-direction, or both. In an embodiment, the starch-based material is blended with one or more thermoplastic materials having desired melt flow index value(s), which serves as a diluent, allowing the very viscous starch-based component to be processed under such conditions. The starch-based materials (and masterbatches thereof) may exhibit high molecular weight, high shear sensitivity, strain hardening behavior, and/or a very high critical shear stress (e.g., at least 125 kPa).

POLYMER MICROSPHERES OF HIERARCHICALLY STRUCTURED CELLULOSE NANOCRYSTALS AND METHOD TO PRODUCE THE SAME
20210395509 · 2021-12-23 ·

It is provided a microspherical structure comprising an external shell of structured cellulose nanocrystals (CNCs) and at least one polymer, and a core, wherein the core can be hollow or filled with an immiscible medium. It is also provided a method for producing the same comprising spray-drying the mixture of CNCs and polymer through an atomizer and into a drying chamber forming droplets, wherein the solvent used to suspend the CNCs is evaporated and the microspherical structures are formed. These microstructural spheres can have wide industrial, medical and pharmaceutical applications, whereby their ingredients and structure are tuned and controlled.