A thermoplastic resin composition of the present invention comprises: a polycarbonate resin; a rubber-modified vinyl-based graft copolymer; a large particle size rubbery polymer having an average particle size of about 400 to about 1,500 nm; an aromatic vinyl-based copolymer resin; a phosphorus-based flame retardant; talc; wollastonite; a maleic anhydride grafted rubbery polymer; and a black pigment. The thermoplastic resin composition is superior in terms of adhesion to metal, strength, flame retardancy, fluidity, and appearance.

A thermoplastic resin composition of the present invention comprises: a polycarbonate resin; a rubber-modified vinyl-based graft copolymer; a large particle size rubbery polymer having an average particle size of about 400 to about 1,500 nm; an aromatic vinyl-based copolymer resin; a phosphorus-based flame retardant; talc; wollastonite; a maleic anhydride grafted rubbery polymer; and a black pigment. The thermoplastic resin composition is superior in terms of adhesion to metal, strength, flame retardancy, fluidity, and appearance.

The present invention relates to curable compositions which comprise (meth)acrylic monomers, ethylenically unsaturated oligomers and a specific multistage polymer additive. The additive is used as a processing aid to reduce cure shrinkage and reduce or prevent the formation of cracks during the polymerization of the composition.

The present invention relates to curable compositions which comprise (meth)acrylic monomers, ethylenically unsaturated oligomers and a specific multistage polymer additive. The additive is used as a processing aid to reduce cure shrinkage and reduce or prevent the formation of cracks during the polymerization of the composition.

A graft copolymer resin obtainable by graft-polymerizing a vinyl monomer comprising a vinyl cyanide monomer and an aromatic vinyl monomer to a rubbery polymer, in which a free resin contained in the graft copolymer resin comprises 10 to 35% by mass of a constituent unit derived from a (meth)acrylic acid alkyl ester having an alkyl group containing 4 or more carbon atoms, based on the total amount of the free resins, and the graft copolymer resin satisfies at least one of the following requirements (1) and (2): (1) the rubbery polymer comprises a constituent unit derived from a (meth)acrylic acid alkyl ester having an alkyl group containing 4 or more carbon atoms; and (2) the vinyl monomer further comprises a (meth)acrylic acid alkyl ester having an alkyl group containing 4 or more carbon atoms.

A graft copolymer resin obtainable by graft-polymerizing a vinyl monomer comprising a vinyl cyanide monomer and an aromatic vinyl monomer to a rubbery polymer, in which a free resin contained in the graft copolymer resin comprises 10 to 35% by mass of a constituent unit derived from a (meth)acrylic acid alkyl ester having an alkyl group containing 4 or more carbon atoms, based on the total amount of the free resins, and the graft copolymer resin satisfies at least one of the following requirements (1) and (2): (1) the rubbery polymer comprises a constituent unit derived from a (meth)acrylic acid alkyl ester having an alkyl group containing 4 or more carbon atoms; and (2) the vinyl monomer further comprises a (meth)acrylic acid alkyl ester having an alkyl group containing 4 or more carbon atoms.

The present invention relates to a moulding compound containing: A) at least one polymer selected from the group consisting of polycarbonate and polyester carbonate; B) a polymer containing B1) at least one rubber-modified vinyl(co)polymer containing B1.1) 80 to 95 wt. %, based on B1, of at least one vinyl monomer and B1.2) 5 to 20 wt. %, based on B1, of one or more rubber-elastic polybutadiene-containing graft foundations, wherein B1 contains polybutadiene-containing rubber particles, which are grafted with the vinyl monomers B1.1 and contain inclusions of vinyl(co)polymer consisting of the vinyl monomers B1.1, and a vinyl(co)polymer matrix which consists of the vinyl monomers B1.1 and is not bonded to these rubber particles and not enclosed in rubber particles, and optionally B2) further rubber particles, grafted with vinyl monomers, from B2.1) 5 to 75 wt. %, based on B.2, of at least one vinyl monomer grafted onto B2.2) 25 to 95 wt. %, based on B2, of one or more rubber-elastic graft foundations, wherein the weight ratio of the components B1 to B2 is at least 5:1; C) a master batch, which is solid at room temperature, containing C1) one or more copolymers containing structural units derived from an olefin and structural units derived from a polar comonomer; C2) a vulcanised silicone elastomer. The invention also relates to a method for preparing the moulding compound, to the use of the moulding compound for producing moulded bodies, and to the moulded bodies themselves.

The present invention relates to a moulding compound containing: A) at least one polymer selected from the group consisting of polycarbonate and polyester carbonate; B) a polymer containing B1) at least one rubber-modified vinyl(co)polymer containing B1.1) 80 to 95 wt. %, based on B1, of at least one vinyl monomer and B1.2) 5 to 20 wt. %, based on B1, of one or more rubber-elastic polybutadiene-containing graft foundations, wherein B1 contains polybutadiene-containing rubber particles, which are grafted with the vinyl monomers B1.1 and contain inclusions of vinyl(co)polymer consisting of the vinyl monomers B1.1, and a vinyl(co)polymer matrix which consists of the vinyl monomers B1.1 and is not bonded to these rubber particles and not enclosed in rubber particles, and optionally B2) further rubber particles, grafted with vinyl monomers, from B2.1) 5 to 75 wt. %, based on B.2, of at least one vinyl monomer grafted onto B2.2) 25 to 95 wt. %, based on B2, of one or more rubber-elastic graft foundations, wherein the weight ratio of the components B1 to B2 is at least 5:1; C) a master batch, which is solid at room temperature, containing C1) one or more copolymers containing structural units derived from an olefin and structural units derived from a polar comonomer; C2) a vulcanised silicone elastomer. The invention also relates to a method for preparing the moulding compound, to the use of the moulding compound for producing moulded bodies, and to the moulded bodies themselves.

The present invention relates to a moulding compound containing: A) at least one polymer selected from the group consisting of polycarbonate and polyester carbonate; B) a polymer containing B1) at least one rubber-modified vinyl(co)polymer containing B1.1) 80 to 95 wt. %, based on B1, of at least one vinyl monomer and B1.2) 5 to 20 wt. %, based on B1, of one or more rubber-elastic polybutadiene-containing graft foundations, wherein B1 contains polybutadiene-containing rubber particles, which are grafted with the vinyl monomers B1.1 and contain inclusions of vinyl(co)polymer consisting of the vinyl monomers B1.1, and a vinyl(co)polymer matrix which consists of the vinyl monomers B1.1 and is not bonded to these rubber particles and not enclosed in rubber particles, and optionally B2) further rubber particles, grafted with vinyl monomers, from B2.1) 5 to 75 wt. %, based on B.2, of at least one vinyl monomer grafted onto B2.2) 25 to 95 wt. %, based on B2, of one or more rubber-elastic graft foundations, wherein the weight ratio of the components B1 to B2 is at least 5:1; C) a master batch, which is solid at room temperature, containing C1) one or more copolymers containing structural units derived from an olefin and structural units derived from a polar comonomer; C2) a vulcanised silicone elastomer. The invention also relates to a method for preparing the moulding compound, to the use of the moulding compound for producing moulded bodies, and to the moulded bodies themselves.

Provided is a heat-resistant resin composition which includes: a graft copolymer prepared by graft polymerization of a diene-based rubber polymer with an aromatic vinyl-based monomer and a vinyl cyan-based monomer; a first styrene-based copolymer including a maleimide-based unit and an aromatic vinyl-based unit; a second styrene-based copolymer including a vinyl cyan-based unit and an aromatic vinyl-based unit; and a third styrene-based copolymer including a vinyl cyan-based unit and an aromatic vinyl-based unit, wherein the second styrene-based copolymer and the third styrene-based copolymer include a vinyl cyan-based unit in mutually different amounts.