A crosslinking composition includes a compound having at least two functional groups that are each independently represented by Chemical Structure (I):

##STR00001##

X is an oxygen, sulfur, or nitrogen; R.sup.1 is an alkyl group, an aryl group, or an alkylaryl group; R.sup.2, R.sup.3, and R.sup.4 are each independently an alkyl group, an aryl group, an alkylaryl group, or a hydrogen; R.sup.5 is an alkyl group, an aryl group, an alkylaryl group, or a hydrogen; z is 0 when X is oxygen or sulfur and z is 1 when X is nitrogen; and when a double bond is formed between a carbon atom bonded to R.sup.3 and an adjacent nitrogen, m is 0, and when a single bond is formed between the carbon atom bonded to R.sup.3 and the adjacent nitrogen, m is 1.

The invention relates to the field of powder coatings, and specifically discloses a heat-curable powder coating composition and a preparation method thereof. The powder coating composition comprises: i) component A comprising at least one amorphous solid polyester resin compound having a Michael donor reactive group; ii) component B comprising at least one amorphous ethylenically unsaturated solid polyester resin with a Michael acceptor reactive group; iii) component C comprising at least one (semi) crystalline solid reactive diluent; iv) component D comprising at least one epoxy group-containing solid substance; v) component E comprising at least one basic catalyst. The present invention also discloses a preparation method of the above heat-curable powder coating composition. By adopting the invention, ultra-low temperature curing can be realized. The curing temperature is as low as 90-110° C., and the curing time is short.

The invention relates to the field of powder coatings, and specifically discloses a heat-curable powder coating composition and a preparation method thereof. The powder coating composition comprises: i) component A comprising at least one amorphous solid polyester resin compound having a Michael donor reactive group; ii) component B comprising at least one amorphous ethylenically unsaturated solid polyester resin with a Michael acceptor reactive group; iii) component C comprising at least one (semi) crystalline solid reactive diluent; iv) component D comprising at least one epoxy group-containing solid substance; v) component E comprising at least one basic catalyst. The present invention also discloses a preparation method of the above heat-curable powder coating composition. By adopting the invention, ultra-low temperature curing can be realized. The curing temperature is as low as 90-110° C., and the curing time is short.

A crosslinking composition includes a compound having at least two functional groups that are each independently represented by Chemical Structure (I): ##STR00001##
X is an oxygen, sulfur, or nitrogen; R.sup.1 is an alkyl group, an aryl group, or an alkylaryl group; R.sup.2, R.sup.3, and R.sup.4 are each independently an alkyl group, an aryl group, an alkylaryl group, or a hydrogen; R.sup.5 is an alkyl group, an aryl group, an alkylaryl group, or a hydrogen; z is 0 when X is oxygen or sulfur and z is 1 when X is nitrogen; and when a double bond is formed between a carbon atom bonded to R.sup.3 and an adjacent nitrogen, m is 0, and when a single bond is formed between the carbon atom bonded to R.sup.3 and the adjacent nitrogen, m is 1.

A crosslinking composition includes a compound having at least two functional groups that are each independently represented by Chemical Structure (I): ##STR00001##
X is an oxygen, sulfur, or nitrogen; R.sup.1 is an alkyl group, an aryl group, or an alkylaryl group; R.sup.2, R.sup.3, and R.sup.4 are each independently an alkyl group, an aryl group, an alkylaryl group, or a hydrogen; R.sup.5 is an alkyl group, an aryl group, an alkylaryl group, or a hydrogen; z is 0 when X is oxygen or sulfur and z is 1 when X is nitrogen; and when a double bond is formed between a carbon atom bonded to R.sup.3 and an adjacent nitrogen, m is 0, and when a single bond is formed between the carbon atom bonded to R.sup.3 and the adjacent nitrogen, m is 1.

The present invention relates to a polyester elastomer resin composition comprising: a thermoplastic polyester elastomer (A); a thickening agent (B); and a urea compound scavenger (C), wherein the thermoplastic polyester elastomer (A) is composed of a hard segment and a soft segment that are linked to each other; the hard segment being composed of a crystalline polyester formed from an aromatic dicarboxylic acid and an aliphatic and/or alicyclic diol, the soft segment being at least one member selected from aliphatic polyethers, aliphatic polyesters, or aliphatic polycarbonates; the urea compound scavenger (C) has an amine value of 50 eq/t or more; the thickening agent (B) is present in an amount of 0 to 5 parts by mass, and the urea compound scavenger (C) is present in an amount of 0.1 to 10 parts by mass, per 100 parts by mass of the thermoplastic polyester elastomer (A). The invention can decrease the deterioration of physical properties of a polyester elastomer caused by the elastomer coming into contact with grease in an environment at a temperature exceeding 140° C.

The present invention relates to a polyester elastomer resin composition comprising: a thermoplastic polyester elastomer (A); a thickening agent (B); and a urea compound scavenger (C), wherein the thermoplastic polyester elastomer (A) is composed of a hard segment and a soft segment that are linked to each other; the hard segment being composed of a crystalline polyester formed from an aromatic dicarboxylic acid and an aliphatic and/or alicyclic diol, the soft segment being at least one member selected from aliphatic polyethers, aliphatic polyesters, or aliphatic polycarbonates; the urea compound scavenger (C) has an amine value of 50 eq/t or more; the thickening agent (B) is present in an amount of 0 to 5 parts by mass, and the urea compound scavenger (C) is present in an amount of 0.1 to 10 parts by mass, per 100 parts by mass of the thermoplastic polyester elastomer (A). The invention can decrease the deterioration of physical properties of a polyester elastomer caused by the elastomer coming into contact with grease in an environment at a temperature exceeding 140° C.

The present invention relates to a polyester elastomer resin composition comprising: a thermoplastic polyester elastomer (A); a thickening agent (B); and a urea compound scavenger (C), wherein the thermoplastic polyester elastomer (A) is composed of a hard segment and a soft segment that are linked to each other; the hard segment being composed of a crystalline polyester formed from an aromatic dicarboxylic acid and an aliphatic and/or alicyclic diol, the soft segment being at least one member selected from aliphatic polyethers, aliphatic polyesters, or aliphatic polycarbonates; the urea compound scavenger (C) has an amine value of 50 eq/t or more; the thickening agent (B) is present in an amount of 0 to 5 parts by mass, and the urea compound scavenger (C) is present in an amount of 0.1 to 10 parts by mass, per 100 parts by mass of the thermoplastic polyester elastomer (A). The invention can decrease the deterioration of physical properties of a polyester elastomer caused by the elastomer coming into contact with grease in an environment at a temperature exceeding 140° C.

The present invention relates to a polyester elastomer resin composition comprising: a thermoplastic polyester elastomer (A); a thickening agent (B); and a urea compound scavenger (C), wherein the thermoplastic polyester elastomer (A) is composed of a hard segment and a soft segment that are linked to each other; the hard segment being composed of a crystalline polyester formed from an aromatic dicarboxylic acid and an aliphatic and/or alicyclic diol, the soft segment being at least one member selected from aliphatic polyethers, aliphatic polyesters, or aliphatic polycarbonates; the urea compound scavenger (C) has an amine value of 50 eq/t or more; the thickening agent (B) is present in an amount of 0 to 5 parts by mass, and the urea compound scavenger (C) is present in an amount of 0.1 to 10 parts by mass, per 100 parts by mass of the thermoplastic polyester elastomer (A). The invention can decrease the deterioration of physical properties of a polyester elastomer caused by the elastomer coming into contact with grease in an environment at a temperature exceeding 140° C.

The present invention provides an epoxy resin composition that serves to produce a cured epoxy resin that simultaneously realizes a high heat resistance, a high elastic modulus, and a low color and to produce a molded article having a good appearance without suffering the formation of white spots on the surface thereof when used as matrix resin in a fiber reinforced composite material. The epoxy resin composition includes an epoxy resin as component [A] and an imidazole compound as component [B] and meets certain conditions (a) to (d).