Provided are hollow particles which have a high void ratio, hardly collapse, and have a reduced amount of volatile compounds. The hollow particles comprising a shell and a hollow portion surrounded by the shell, and having a void ratio of 50% or more and 90% or less, wherein the shell has a thickness of 0.2 μm or more and 0.9 μm or less, and the shell contains a polymer derived from a polymerizable monomer for shell, which is composed of 70% by mass or more and 100% by mass or less of a crosslinkable monomer and 0% by mass or more and 30% by mass or less of a non-crosslinkable monomer, and a polar resin selected from the group consisting of polymers containing a repeating unit which contains a hetero atom.

Provided are hollow particles which have a high void ratio, hardly collapse, and have a reduced amount of volatile compounds. The hollow particles comprising a shell and a hollow portion surrounded by the shell, and having a void ratio of 50% or more and 90% or less, wherein the shell has a thickness of 0.2 μm or more and 0.9 μm or less, and the shell contains a polymer derived from a polymerizable monomer for shell, which is composed of 70% by mass or more and 100% by mass or less of a crosslinkable monomer and 0% by mass or more and 30% by mass or less of a non-crosslinkable monomer, and a polar resin selected from the group consisting of polymers containing a repeating unit which contains a hetero atom.

The present disclosure relates to a thermoplastic resin composition and a molded article including the same. More particularly, the present disclosure relates to a thermoplastic resin composition including 100 parts by weight of a styrene-based resin and 1 to 10 parts by weight of a surface modifier and having a skewness (Rsk) of 0.65 to 1.35 and a molded article including the thermoplastic resin composition. In addition, the present disclosure provides a thermoplastic resin composition that is capable of imparting a rough feeling to the surface of a product and has excellent weather resistance while maintaining mechanical properties and processability equal or superior to those of conventional ASA resins; and a molded article including the thermoplastic resin composition. In particular, due to these properties of the thermoplastic resin composition, a product manufactured using the thermoplastic resin composition may have a luxurious appearance without an artificial plastic feel.

The present disclosure relates to a thermoplastic resin composition and a molded article including the same. More particularly, the present disclosure relates to a thermoplastic resin composition including 100 parts by weight of a styrene-based resin and 1 to 10 parts by weight of a surface modifier and having a skewness (Rsk) of 0.65 to 1.35 and a molded article including the thermoplastic resin composition. In addition, the present disclosure provides a thermoplastic resin composition that is capable of imparting a rough feeling to the surface of a product and has excellent weather resistance while maintaining mechanical properties and processability equal or superior to those of conventional ASA resins; and a molded article including the thermoplastic resin composition. In particular, due to these properties of the thermoplastic resin composition, a product manufactured using the thermoplastic resin composition may have a luxurious appearance without an artificial plastic feel.

A system for manufacturing a thermoplastic prepreg includes a double belt mechanism that is configured to compress a fiber mat, web, or mesh that is passed through the double belt mechanism, a resin applicator that is configured to apply monomers or oligomers to the fiber mat, web, or mesh, and a curing oven that is configured to effect polymerization of the monomers or oligomers and thereby form the thermoplastic polymer as the fiber mat, web, or mesh is moved through the curing oven. The double belt mechanism compresses the fiber mat, web, or mesh and the applied monomers or oligomers as the fiber mat, web, or mesh is passed through the curing oven so that the monomers or oligomers fully saturate the fiber mat, web, or mesh. Upon polymerization of the monomers or oligomers, the fiber mat, web, or mesh is fully impregnated with the thermoplastic polymer.

A system for manufacturing a thermoplastic prepreg includes a double belt mechanism that is configured to compress a fiber mat, web, or mesh that is passed through the double belt mechanism, a resin applicator that is configured to apply monomers or oligomers to the fiber mat, web, or mesh, and a curing oven that is configured to effect polymerization of the monomers or oligomers and thereby form the thermoplastic polymer as the fiber mat, web, or mesh is moved through the curing oven. The double belt mechanism compresses the fiber mat, web, or mesh and the applied monomers or oligomers as the fiber mat, web, or mesh is passed through the curing oven so that the monomers or oligomers fully saturate the fiber mat, web, or mesh. Upon polymerization of the monomers or oligomers, the fiber mat, web, or mesh is fully impregnated with the thermoplastic polymer.

The disclosure describes composite fibers reinforced with inorganic nanostructures of high aspect ratio with homogeneous dispersion and alignment along the fiber axis and a process for producing said composite fibers. A composite fiber comprising an array of inorganic nanowires embedded in a polymer matrix. The nanowires have a diameter <100 nm and high aspect ratio of at least 5 with homogenous dispersion and polymer chains of the polymer matrix and the nanowires are oriented along the fiber axis. The nanowire wt % in the composite fiber is in the range of 0.01 to 2 wt %. The inorganic nanowires are non conducting and include at least one of ZnO, or aluminosilicate clay tubes.

The disclosure describes composite fibers reinforced with inorganic nanostructures of high aspect ratio with homogeneous dispersion and alignment along the fiber axis and a process for producing said composite fibers. A composite fiber comprising an array of inorganic nanowires embedded in a polymer matrix. The nanowires have a diameter <100 nm and high aspect ratio of at least 5 with homogenous dispersion and polymer chains of the polymer matrix and the nanowires are oriented along the fiber axis. The nanowire wt % in the composite fiber is in the range of 0.01 to 2 wt %. The inorganic nanowires are non conducting and include at least one of ZnO, or aluminosilicate clay tubes.

Provided is a polyamide resin molded article having high mechanical properties and dimensional accuracy as well as low friction coefficient, low wear, and/or low abrasion property. The present invention provides a polyamide resin molded article composed of a polyamide resin composition including (A) a polyamide resin, (B) chemically modified cellulose microfibers having a weight average molecular weight (Mw) of 100,000 or more, a ratio (Mw/Mn) of the weight average molecular weight (Mw) and the number average molecular weight (Mn) of 6 or less, an alkali-soluble polysaccharides average content of 12 mass percent or less, and a degree of crystallization of 60% or more, and (C) a dispersant having a melting point of 80° C. or less and a number average molecular weight of 1000-50,000, wherein the melting point (Tm) and the crystallization temperature (Tc) of the polyamide resin molded article satisfy formula (1): Tm−Tc≥30° C. . . . (1).

Provided is a polyamide resin molded article having high mechanical properties and dimensional accuracy as well as low friction coefficient, low wear, and/or low abrasion property. The present invention provides a polyamide resin molded article composed of a polyamide resin composition including (A) a polyamide resin, (B) chemically modified cellulose microfibers having a weight average molecular weight (Mw) of 100,000 or more, a ratio (Mw/Mn) of the weight average molecular weight (Mw) and the number average molecular weight (Mn) of 6 or less, an alkali-soluble polysaccharides average content of 12 mass percent or less, and a degree of crystallization of 60% or more, and (C) a dispersant having a melting point of 80° C. or less and a number average molecular weight of 1000-50,000, wherein the melting point (Tm) and the crystallization temperature (Tc) of the polyamide resin molded article satisfy formula (1): Tm−Tc≥30° C. . . . (1).