Patent classifications
C08L85/02
Thermoplastic resin composition and molded article manufactured therefrom
A thermoplastic resin composition of the present invention comprises: a polycarbonate resin; a rubber-modified vinyl-based graft copolymer; a large particle size rubbery polymer having an average particle size of about 400 to about 1,500 nm; an aromatic vinyl-based copolymer resin; a phosphorus-based flame retardant; talc; wollastonite; a maleic anhydride grafted rubbery polymer; and a black pigment. The thermoplastic resin composition is superior in terms of adhesion to metal, strength, flame retardancy, fluidity, and appearance.
Thermoplastic resin composition and molded article manufactured therefrom
A thermoplastic resin composition of the present invention comprises: a polycarbonate resin; a rubber-modified vinyl-based graft copolymer; a large particle size rubbery polymer having an average particle size of about 400 to about 1,500 nm; an aromatic vinyl-based copolymer resin; a phosphorus-based flame retardant; talc; wollastonite; a maleic anhydride grafted rubbery polymer; and a black pigment. The thermoplastic resin composition is superior in terms of adhesion to metal, strength, flame retardancy, fluidity, and appearance.
FLAME-RETARDANT POLYCARBONATE COMPOSITION
The present invention relates to a flame-retardant polycarbonate composition comprising the following components:
A) 50-90 parts by weight of aromatic polycarbonate,
B) 3-20 parts by weight of non-core-shell impact modifier,
C) 2-15 parts by weight of at least one cyclic phosphazene of formula (V):
##STR00001##
where
k is an integer from 1 to 10, the trimer content (k=1) being more than 98 mol %, based on component C, and where
R are in each case identical or different and are an amine radical, C.sub.1-C.sub.8-alkyl in each case optionally halogenated, C.sub.1-C.sub.8-alkoxy, C.sub.5-C.sub.6-cycloalkyl in each case optionally substituted by alkyl and/or halogen, C.sub.6-C.sub.20-aryloxy in each case optionally substituted by alkyl and/or halogen, and/or hydroxyl, C.sub.7-C.sub.12-aralkyl in each case optionally substituted by alkyl and/or halogen, a halogen radical, or an OH radical,
D) 0-30 parts by weight of filler,
E) 0.05-5 parts by weight of antidripping agent; and
F) 0-15 parts by weight of additional additives,
the total weight of the composition is 100 parts by weight,
preferably, the composition consists to at least 90 wt. %, more preferably at least 95 wt. %, most preferably 100 wt % of components A-F, relative to the total weight of the composition.
The present invention also relates to a shaped article produced from the composition. The polycarbonate composition according to the present invention has a good combination of flame retardancy, hydrolytic stability and impact resistance, meanwhile there is no feeding issue during its production.
FLAME-RETARDANT POLYCARBONATE COMPOSITION
The present invention relates to a flame-retardant polycarbonate composition comprising the following components:
A) 50-90 parts by weight of aromatic polycarbonate,
B) 3-20 parts by weight of non-core-shell impact modifier,
C) 2-15 parts by weight of at least one cyclic phosphazene of formula (V):
##STR00001##
where
k is an integer from 1 to 10, the trimer content (k=1) being more than 98 mol %, based on component C, and where
R are in each case identical or different and are an amine radical, C.sub.1-C.sub.8-alkyl in each case optionally halogenated, C.sub.1-C.sub.8-alkoxy, C.sub.5-C.sub.6-cycloalkyl in each case optionally substituted by alkyl and/or halogen, C.sub.6-C.sub.20-aryloxy in each case optionally substituted by alkyl and/or halogen, and/or hydroxyl, C.sub.7-C.sub.12-aralkyl in each case optionally substituted by alkyl and/or halogen, a halogen radical, or an OH radical,
D) 0-30 parts by weight of filler,
E) 0.05-5 parts by weight of antidripping agent; and
F) 0-15 parts by weight of additional additives,
the total weight of the composition is 100 parts by weight,
preferably, the composition consists to at least 90 wt. %, more preferably at least 95 wt. %, most preferably 100 wt % of components A-F, relative to the total weight of the composition.
The present invention also relates to a shaped article produced from the composition. The polycarbonate composition according to the present invention has a good combination of flame retardancy, hydrolytic stability and impact resistance, meanwhile there is no feeding issue during its production.
Systems and methods for optimized patient specific tissue engineering vascular grafts
It has been established that optimizing cell seeding onto tissue engineering vascular grafts (TEVG) is associated with reduced inflammatory responses and reduced post-operative stenosis of TEVG. Cell seeding increased TEVG patency in a dose dependent manner, and TEVG patency improved when more cells were seeded, however duration of incubation time showed minimal effect on TEVG patency. Methods of engineering patient specific TEVG including optimal numbers of cells to maintain graft patency and reduce post-operative stenosis are provided. Closed, single-use customizable systems for seeding TEVG are also provided. Preferably the systems are custom-designed based on morphology of the patient specific graft, to enhance the efficacy of cell seeding.
Systems and methods for optimized patient specific tissue engineering vascular grafts
It has been established that optimizing cell seeding onto tissue engineering vascular grafts (TEVG) is associated with reduced inflammatory responses and reduced post-operative stenosis of TEVG. Cell seeding increased TEVG patency in a dose dependent manner, and TEVG patency improved when more cells were seeded, however duration of incubation time showed minimal effect on TEVG patency. Methods of engineering patient specific TEVG including optimal numbers of cells to maintain graft patency and reduce post-operative stenosis are provided. Closed, single-use customizable systems for seeding TEVG are also provided. Preferably the systems are custom-designed based on morphology of the patient specific graft, to enhance the efficacy of cell seeding.
Weather-resistant flame-retardant resin composition, optical fiber cable, and electric wire
A weather-resistant flame-retardant resin composition includes: a polyolefin resin; a mixture of (poly) phosphate compounds, a total content of which is from 10 to 50 parts by mass with respect to 100 parts by mass of the polyolefin resin; 0.1 to 10 parts by mass a non-crosslinked silicone raw rubber having a number-average molecular weight of 10,000 to 1,000,000; and 0.1 to 20 parts by mass of an inorganic UV light shielding agent, and an electric wire and an optical fiber cable whose jacket is formed by the weather-resistant flame-retardant resin.
Weather-resistant flame-retardant resin composition, optical fiber cable, and electric wire
A weather-resistant flame-retardant resin composition includes: a polyolefin resin; a mixture of (poly) phosphate compounds, a total content of which is from 10 to 50 parts by mass with respect to 100 parts by mass of the polyolefin resin; 0.1 to 10 parts by mass a non-crosslinked silicone raw rubber having a number-average molecular weight of 10,000 to 1,000,000; and 0.1 to 20 parts by mass of an inorganic UV light shielding agent, and an electric wire and an optical fiber cable whose jacket is formed by the weather-resistant flame-retardant resin.
FAST-CHARGING, HIGH-ENERGY, FLEXIBLE LITHIUM-SULFUR BATTERIES BASED ON HIERARCHICALLY ORDERED SULFUR PARTICLES AND PREPARATION METHOD THEREOF
The present disclosure relates to a cathode active material for a secondary battery, comprising a poly(S-co-VPA) vulcanized polymer, a preparation method thereof, and a lithium-sulfur secondary battery comprising the same.
PREPARATION METHOD OF FLAME-RETARDANT LITHIUM-ION BATTERY ELECTROLYTE EASILY SOLUBLE IN ORGANIC SOLVENT
A lithium salt easily soluble in an organic solvent and having a flame-retardant function and a lithium-ion battery flame-retardant electrolyte thereof are provided. The lithium salt is poly(lithium phosphate) phosphazene partially substituted by alkyl aromatic oxy groups, and has a structural general formula: [(R—Ar—O).sub.x(P═N).sub.n(Li.sub.2O.sub.3P).sub.2n-x]. The novel flame-retardant electrolyte is compounded from the lithium salt and a phosphate intermediate thereof [(R—Ar—O).sub.x(P═N).sub.n(R′.sub.2O.sub.3P).sub.2n-x] according to a mass ratio of 10:1-1:1. The electrolyte is easily soluble in an organic solvent. A liquid electrolyte is prepared according to an amount of 8%-45% to obtain the novel flame-retardant liquid electrolyte. The liquid electrolyte has good lithium ion conductivity and good flame-retardant properties, and is used in lithium-ion batteries, lithium-sulfur batteries, lithium carbon fluoride batteries or lithium-oxygen batteries.