Patent classifications
C08L93/04
Biorenewable hydrocarbon compositions and their uses
Disclosed are compositions comprising dimeric decarboxylated rosins (DDCRs), methods for making them, and applications thereof. DDCR of purity from 50-100 wt. % is obtained by decarboxylating a dimeric rosin acid or by dimerizing a decarboxylated rosin, in the presence of a catalyst, followed by one or more purification steps separation on differences in boiling point. The isolated DDCR fractions display unexpectedly high T.sub.g/M.sub.n ratios, softening points and viscosities, and low polydispersities. The DDCR product comprises 50 to 100 wt. % of polycyclic hydrocarbon compounds having one or more aliphatic, unsaturated or aromatic groups, and 34-80 carbon atoms, with a molecular weight M.sub.n of 250-900 Da, and an oxygen to carbon ratio of <5%. The DDCR product has at least 50%, and up to 100% as dimeric species, with the remainder being trimeric and larger polymeric species.
Biorenewable hydrocarbon compositions and their uses
Disclosed are compositions comprising dimeric decarboxylated rosins (DDCRs), methods for making them, and applications thereof. DDCR of purity from 50-100 wt. % is obtained by decarboxylating a dimeric rosin acid or by dimerizing a decarboxylated rosin, in the presence of a catalyst, followed by one or more purification steps separation on differences in boiling point. The isolated DDCR fractions display unexpectedly high T.sub.g/M.sub.n ratios, softening points and viscosities, and low polydispersities. The DDCR product comprises 50 to 100 wt. % of polycyclic hydrocarbon compounds having one or more aliphatic, unsaturated or aromatic groups, and 34-80 carbon atoms, with a molecular weight M.sub.n of 250-900 Da, and an oxygen to carbon ratio of <5%. The DDCR product has at least 50%, and up to 100% as dimeric species, with the remainder being trimeric and larger polymeric species.
Biorenewable hydrocarbon compositions and their uses
Disclosed are compositions comprising dimeric decarboxylated rosins (DDCRs), methods for making them, and applications thereof. DDCR of purity from 50-100 wt. % is obtained by decarboxylating a dimeric rosin acid or by dimerizing a decarboxylated rosin, in the presence of a catalyst, followed by one or more purification steps separation on differences in boiling point. The isolated DDCR fractions display unexpectedly high T.sub.g/M.sub.n ratios, softening points and viscosities, and low polydispersities. The DDCR product comprises 50 to 100 wt. % of polycyclic hydrocarbon compounds having one or more aliphatic, unsaturated or aromatic groups, and 34-80 carbon atoms, with a molecular weight M.sub.n of 250-900 Da, and an oxygen to carbon ratio of <5%. The DDCR product has at least 50%, and up to 100% as dimeric species, with the remainder being trimeric and larger polymeric species.
RUBBER COMPOSITION AND TIRE
The present invention is directed to a rubber composition comprising 70 phr to 100 phr of at least one styrene butadiene rubber, 0 phr to 30 phr of at least one further diene-based rubber, from 40 phr to 200 phr of at least one filler, at least 5 phr of aluminum hydroxide, and at least 0.5 phr of a rosin based resin. Moreover, the present invention is directed to a tire comprising such a rubber composition.
RUBBER COMPOSITION AND TIRE
The present invention is directed to a rubber composition comprising 70 phr to 100 phr of at least one styrene butadiene rubber, 0 phr to 30 phr of at least one further diene-based rubber, from 40 phr to 200 phr of at least one filler, at least 5 phr of aluminum hydroxide, and at least 0.5 phr of a rosin based resin. Moreover, the present invention is directed to a tire comprising such a rubber composition.
OIL-SOLUBLE THERMOSENSITIVE RESIN LOST CIRCULATION MATERIAL FOR PROTECTING A RESERVOIR AS WELL AS PREPARATION METHOD AND APPLICATION THEREOF
An oil-soluble thermosensitive resin lost circulation material for protecting a reservoir includes the following raw materials in parts by weight: 40-60 parts of resin matrix, 15-40 parts of modified asphalt, 5-12 parts of viscosity modifier, 2-5 parts of cross-linking agent, 6-15 parts of softening point modifier, and 1-3 parts of dispersant; it further provides a method for preparing the resin lost circulation material; the resin lost circulation material can melt and adhere in different temperature ranges, rapid plugging is realized, and the plugging time is long; the oil-soluble thermosensitive resin lost circulation material can be dissolved by oil flow during oil well production, so that the reservoir permeability is recovered, so as to achieve the purpose of protecting the hydrocarbon reservoir.
OIL-SOLUBLE THERMOSENSITIVE RESIN LOST CIRCULATION MATERIAL FOR PROTECTING A RESERVOIR AS WELL AS PREPARATION METHOD AND APPLICATION THEREOF
An oil-soluble thermosensitive resin lost circulation material for protecting a reservoir includes the following raw materials in parts by weight: 40-60 parts of resin matrix, 15-40 parts of modified asphalt, 5-12 parts of viscosity modifier, 2-5 parts of cross-linking agent, 6-15 parts of softening point modifier, and 1-3 parts of dispersant; it further provides a method for preparing the resin lost circulation material; the resin lost circulation material can melt and adhere in different temperature ranges, rapid plugging is realized, and the plugging time is long; the oil-soluble thermosensitive resin lost circulation material can be dissolved by oil flow during oil well production, so that the reservoir permeability is recovered, so as to achieve the purpose of protecting the hydrocarbon reservoir.
OIL-SOLUBLE THERMOSENSITIVE RESIN LOST CIRCULATION MATERIAL FOR PROTECTING A RESERVOIR AS WELL AS PREPARATION METHOD AND APPLICATION THEREOF
An oil-soluble thermosensitive resin lost circulation material for protecting a reservoir includes the following raw materials in parts by weight: 40-60 parts of resin matrix, 15-40 parts of modified asphalt, 5-12 parts of viscosity modifier, 2-5 parts of cross-linking agent, 6-15 parts of softening point modifier, and 1-3 parts of dispersant; it further provides a method for preparing the resin lost circulation material; the resin lost circulation material can melt and adhere in different temperature ranges, rapid plugging is realized, and the plugging time is long; the oil-soluble thermosensitive resin lost circulation material can be dissolved by oil flow during oil well production, so that the reservoir permeability is recovered, so as to achieve the purpose of protecting the hydrocarbon reservoir.
AMPHIPHILIC ADDITIVES AS COMPATIBILIZERS FOR ROSIN TACKIFIERS IN POLYOLEFIN HOT-MELT ADHESIVES
Presently described are bio-based hot-melt adhesive compositions including rosin acids or derivatives thereof and an amphiphilic agent that provide adhesives with a high softening point, improved heat resistance, low melt viscosity, and compatibility with hydrocarbon compositions including polyolefins and waxes used in hot-melt adhesives.
AMPHIPHILIC ADDITIVES AS COMPATIBILIZERS FOR ROSIN TACKIFIERS IN POLYOLEFIN HOT-MELT ADHESIVES
Presently described are bio-based hot-melt adhesive compositions including rosin acids or derivatives thereof and an amphiphilic agent that provide adhesives with a high softening point, improved heat resistance, low melt viscosity, and compatibility with hydrocarbon compositions including polyolefins and waxes used in hot-melt adhesives.