A method of forming a paving composition using reclaimed asphalt pavement (RAP) and/or reclaimed asphalt shingle (RAS) is provided. The method comprises: a) providing a rejuvenated asphalt binder consisting essentially of bitumen, a block copolymer and a bio-oil, wherein the rejuvenated asphalt binder has a rotational viscosity at 135 C. equal to or less than 1000 centipoise, an original G*/sin at 64 C. equal to or greater than 1 kPa where G* is the complex shear modulus and is the phase angle; a G*/sin at 64 C. equal to or greater than 2.2 kPa after aging in a Rolling Thin Film Oven (RTFO); b) providing a virgin asphalt; c) heating the virgin asphalt to 160-200 C.; d) providing a RAP and/or RAS; and e) mixing the heated virgin asphalt, RAP/RAS, and the rejuvenated asphalt binder under conditions suitable to form the paving composition.

A method of forming a paving composition using reclaimed asphalt pavement (RAP) and/or reclaimed asphalt shingle (RAS) is provided. The method comprises: a) providing a rejuvenated asphalt binder consisting essentially of bitumen, a block copolymer and a bio-oil, wherein the rejuvenated asphalt binder has a rotational viscosity at 135 C. equal to or less than 1000 centipoise, an original G*/sin at 64 C. equal to or greater than 1 kPa where G* is the complex shear modulus and is the phase angle; a G*/sin at 64 C. equal to or greater than 2.2 kPa after aging in a Rolling Thin Film Oven (RTFO); b) providing a virgin asphalt; c) heating the virgin asphalt to 160-200 C.; d) providing a RAP and/or RAS; and e) mixing the heated virgin asphalt, RAP/RAS, and the rejuvenated asphalt binder under conditions suitable to form the paving composition.

Disclosed herein are asphalt compositions. In some embodiments, the asphalt compositions can include asphalt, a polymer, and a basic salt such as aluminum sulfate. In some embodiments, the asphalt compositions can include asphalt, a polymer, and an inorganic acid such as phosphoric acid. The asphalt compositions can include asphalt in an amount of from 50 wt % to 99.9 wt %, based on the weight of the asphalt composition. In some embodiments, the asphalt compositions can include a styrene-butadiene copolymer in an amount of from 0.05 wt % to 10 wt %, based on the weight of the asphalt composition. The basic salt can be present in an amount of from 0.01 wt % to 5 wt %, based on the weight of the asphalt compositions. The acid can be present in an amount of from 0.005 wt % to 0.1 wt %, based on the weight of the asphalt compositions. Methods of making and using the asphalt compositions are also disclosed.

Disclosed herein are asphalt compositions. In some embodiments, the asphalt compositions can include asphalt, a polymer, and a basic salt such as aluminum sulfate. In some embodiments, the asphalt compositions can include asphalt, a polymer, and an inorganic acid such as phosphoric acid. The asphalt compositions can include asphalt in an amount of from 50 wt % to 99.9 wt %, based on the weight of the asphalt composition. In some embodiments, the asphalt compositions can include a styrene-butadiene copolymer in an amount of from 0.05 wt % to 10 wt %, based on the weight of the asphalt composition. The basic salt can be present in an amount of from 0.01 wt % to 5 wt %, based on the weight of the asphalt compositions. The acid can be present in an amount of from 0.005 wt % to 0.1 wt %, based on the weight of the asphalt compositions. Methods of making and using the asphalt compositions are also disclosed.

Compositions and methods are provided for treating a pavement such as by microsurfacing or slurry sealing. The compositions contain iron chelants that are effective in reducing discoloration of the pavement surface.

Compositions and methods are provided for treating a pavement such as by microsurfacing or slurry sealing. The compositions contain iron chelants that are effective in reducing discoloration of the pavement surface.

Asphalt binders are modified using fractional products from waste tire pyrolysis, using an initial step of i) at least partially pyrolyzing, separately from such asphaltic binder, whole rubber articles or size-reduced rubber particles to provide one or more pyrolyzed rubber fractions including a pyrolyzed oil fraction having a selected minimum initial boiling point or flash point, and ii) removing some or all polycyclic aromatic hydrocarbon (PAH) compounds from such pyrolyzed oil fraction to provide a reduced-PAH and preferably translucent pyrolyzed oil fraction that may be combined with an asphaltic binder to provide a modified asphalt composition.

Asphalt binders are modified using fractional products from waste tire pyrolysis, using an initial step of i) at least partially pyrolyzing, separately from such asphaltic binder, whole rubber articles or size-reduced rubber particles to provide one or more pyrolyzed rubber fractions including a pyrolyzed oil fraction having a selected minimum initial boiling point or flash point, and ii) removing some or all polycyclic aromatic hydrocarbon (PAH) compounds from such pyrolyzed oil fraction to provide a reduced-PAH and preferably translucent pyrolyzed oil fraction that may be combined with an asphaltic binder to provide a modified asphalt composition.

A coupled block copolymer composition with a combination of high viscosity at manufacturing, finishing and handling conditions, low viscosity at asphalt blending conditions and suitable viscosity stability is provided for use in asphalt compositions. The composition comprises: (i) a diblock copolymer, (ii) at least a linear triblock copolymer having a peak molecular weight that is 1.5 to 3.0 times the peak molecular weight of the diblock copolymer, and (iii) at least a multiarm coupled block copolymer having a peak molecular weight that is 1.5 to 9.0 times the peak molecular weight of the diblock copolymer, and mixtures thereof. The block copolymer composition is characterized as having a melt viscosity at 110 C. or less of greater than 2.0E7 Poise and a coupling efficiency after 24 hours at 180 C. is less than 25%.

A coupled block copolymer composition with a combination of high viscosity at manufacturing, finishing and handling conditions, low viscosity at asphalt blending conditions and suitable viscosity stability is provided for use in asphalt compositions. The composition comprises: (i) a diblock copolymer, (ii) at least a linear triblock copolymer having a peak molecular weight that is 1.5 to 3.0 times the peak molecular weight of the diblock copolymer, and (iii) at least a multiarm coupled block copolymer having a peak molecular weight that is 1.5 to 9.0 times the peak molecular weight of the diblock copolymer, and mixtures thereof. The block copolymer composition is characterized as having a melt viscosity at 110 C. or less of greater than 2.0E7 Poise and a coupling efficiency after 24 hours at 180 C. is less than 25%.