Amines and amine derivatives that improve the buffering range, and/or reduce the chelation and other negative interactions of the buffer and the system to be buffered. The reaction of amines or polyamines with various molecules to form polyamines with differing pKa's will extend the buffering range, derivatives that result in polyamines that have the same pKa yields a greater buffering capacity. Derivatives that result in zwitterionic buffers improve yield by allowing a greater range of stability.

A non-carboxylated styrene-butadiene copolymer, preparation method and use thereof are provided. The non-carboxylated styrene-butadiene copolymer is prepared by hot polymerization in the absence of acid monomers and is used in asphalt-based systems such as asphalt emulsions.

A mineral-compatible cationic emulsion composition with polymer stabilizers, and methods for utilizing same in paving and other applications is disclosed. In one aspect, a bitumen-in-water emulsion composition includes at least one bitumen material, at least one polymer stabilizer, at least one emulsifier, and water, where the emulsifier is a cationic surfactant, an amphoteric surfactant, or a mixture of both, and the polymer stabilizer is a natural or synthetic cationic polymer consisting of alkylene polyamines, alkyl polyamines, polyquaternary polymers, polyvinylamine, polyvinylimidazoline, polyester polyquaternary polymers, polyether polyquaternary polymers, or mixtures thereof. The inclusion of polymer stabilizer in the cationic emulsion increases the stability of the emulsion and increases the compatibility of the cationic emulsion with negatively charged minerals.

A mineral-compatible cationic emulsion composition with polymer stabilizers, and methods for utilizing same in paving and other applications is disclosed. In one aspect, a bitumen-in-water emulsion composition includes at least one bitumen material, at least one polymer stabilizer, at least one emulsifier, and water, where the emulsifier is a cationic surfactant, an amphoteric surfactant, or a mixture of both, and the polymer stabilizer is a natural or synthetic cationic polymer consisting of alkylene polyamines, alkyl polyamines, polyquaternary polymers, polyvinylamine, polyvinylimidazoline, polyester polyquaternary polymers, polyether polyquaternary polymers, or mixtures thereof. The inclusion of polymer stabilizer in the cationic emulsion increases the stability of the emulsion and increases the compatibility of the cationic emulsion with negatively charged minerals.

The invention relates to a construction block comprising petroleum coke and at least one binder, and having a vertical and/or horizontal water permeability of less than or equal to 0.005 mm/s.

The invention also relates to the use of a composition comprising petroleum coke and at least one binder, for the manufacture of a construction block.

Alkali-swellable rheology modifier comprising a core-shell polymer comprising a core polymer and a shell comprising at least one shell copolymer layer at least partially cross-linked and containing a mole percent of crosslinking agent greater than the mole percent of crosslinking agent in the core polymer, provided if the mole percent of crosslinking agent in the core polymer is zero, then either the core polymer is greater than 60 wt % of the core-shell polymer; the core polymer comprises at least one associative monomer; at least one shell copolymer layer copolymer comprises at least one associative monomer; and/or the at least one shell copolymer layer that is at least partially cross-linked comprises greater than 3 mole % crosslinking agent. Aqueous compositions comprising the alkali-swellable rheology modifier include personal care formulations, healthcare formulations, agricultural formulations, paint formulations, coating formulations, laundry and fabric care formulations, household cleaning formulations, and industrial and institutional cleaning formulations.

A counter tapered thermoplastic elastomer composition comprising: (a) a counter tapered diblock A-[A/B] copolymer with a peak molecular weight from 20,000 to 250,000, which includes a monovinyl aromatic homopolymer block A with a peak molecular weight of at least 8,000 and a counter tapered copolymer block [A/B] with a vinyl content of at least 15 weight percent based on the amount of conjugated diene units in the diblock copolymer; and (b) a block copolymer selected from the group consisting of linear triblock copolymers having a peak molecular weight that is at least about 1.5 times the peak molecular weight of the counter tapered diblock A-[A/B] copolymer described in (a), multiarm coupled block copolymers having a peak molecular weight that is at least about 2.5 times the peak molecular weight of the counter tapered diblock A-[A/B] copolymer described in (a), and mixtures thereof; and (c) wherein the ratio of (a) to (b) in the counter tapered thermoplastic elastomer composition is from about 1:5 to about 5:1. The counter tapered thermoplastic elastomer compositions provide in the applications: i) easy processing such as short dispersion time, low mixing temperature, low viscosity, excellent storage stability; and ii) better reinforcement such as high elastic response, wide range of performance grade, high adherence, higher filler loading capacity, and better compromise between high and low temperature properties; which make them suitable for a broad range of applications such as road paving, roofing, shingles, waterproofing membranes, adhesive tapes and labels, contact and sprayable adhesives, and sealants.

A counter tapered thermoplastic elastomer composition comprising: (a) a counter tapered diblock A-[A/B] copolymer with a peak molecular weight from 20,000 to 250,000, which includes a monovinyl aromatic homopolymer block A with a peak molecular weight of at least 8,000 and a counter tapered copolymer block [A/B] with a vinyl content of at least 15 weight percent based on the amount of conjugated diene units in the diblock copolymer; and (b) a block copolymer selected from the group consisting of linear triblock copolymers having a peak molecular weight that is at least about 1.5 times the peak molecular weight of the counter tapered diblock A-[A/B] copolymer described in (a), multiarm coupled block copolymers having a peak molecular weight that is at least about 2.5 times the peak molecular weight of the counter tapered diblock A-[A/B] copolymer described in (a), and mixtures thereof; and (c) wherein the ratio of (a) to (b) in the counter tapered thermoplastic elastomer composition is from about 1:5 to about 5:1. The counter tapered thermoplastic elastomer compositions provide in the applications: i) easy processing such as short dispersion time, low mixing temperature, low viscosity, excellent storage stability; and ii) better reinforcement such as high elastic response, wide range of performance grade, high adherence, higher filler loading capacity, and better compromise between high and low temperature properties; which make them suitable for a broad range of applications such as road paving, roofing, shingles, waterproofing membranes, adhesive tapes and labels, contact and sprayable adhesives, and sealants.

The invention relates to a method for manufacturing a road pavement comprising pipes of a device for a heat exchanger, comprising the following steps: a) digging a course to create grooves extending in a same direction and strips connecting the grooves, then b) laying the pipe having a crushing strength higher than 2 000N per linear metre of pipe at 100° C. into the grooves created in step a); and then c) filling the empty space left free by the pipe in the grooves with an asphalt mix having a working temperature lower than 160° C., based on: a hydrocarbon binder, at least 90% by weight, with respect to the total weight of the asphalt mix, of an aggregate fraction the elements of which have dimensions less than 10 mm, and comprising from 30% to 60% by weight, with respect to the total weight of the aggregate fraction, of sand, d) applying a surface course for a road pavement.

An asphalt-based sealcoat composition comprising high levels of titanium oxide particles is provided. In some embodiments, a highly solar reflective asphalt-based sealcoat composition comprising high levels of titanium oxide particles is provided. In some embodiments, an asphalt-based sealcoat composition capable of reducing pollutants comprising high levels of titanium oxide particles is provided. In some embodiments, methods for preparing asphalt-based sealcoat compositions as well as their application to asphalt surfaces is provided.