The present invention is directed to a heterophasic polypropylene composition with improved sterilization resistance and optical properties for blow molding applications, in particular for use in the blow-fill-seal process for preparing bottles. The present invention is further directed to a process for producing such a polypropylene composition using a single-site catalyst and to a container produced from such a polypropylene composition by blow molding, like a bottle, in particular a blow-fill-seal bottle, with improved haze before and after sterilization. The polypropylene composition comprises a blend of a propylene copolymer comprising 2.5 to 12.0 wt % of 1-hexene as a comonomer, and having a melt flow rate MFR.sub.2 of 0.5 to 20.0 g/10 min, and an ethylene homo- or copolymer having a melt flow rate MFR.sub.2 of 0.05 to 30.0 g/10 min and a density of 850 to 940 kg/m.sup.3, wherein the xylene cold solubles (XCS) content of the polypropylene composition is from 5.0 to 30.0 wt %.

The present disclosure describes bottle closure assemblies which are made at least in part with a polyethylene composition having good processability, good organoleptic properties and good dimensional stability. The bottle closure assembly includes a cap portion, an elongated tether portion, and a retaining means portion. The retaining means portions engages a bottle neck or an upper portion of a bottle. The elongated tether portion connects at least one point on the cap portion to at least one point on the retaining means portion so as to prevent loss of the cap portion from a bottle.

The present disclosure provides a fitment. In an embodiment, the fitment includes a top portion, a base, and a channel extending through the top portion and the base for passage of a flowable material. The fitment is composed of a polymeric composition. The polymeric composition comprises: (i) from 60 weight % to 90 weight % of a propylene-based polymer having a density of 0.900 g/cc and a melt flow rate greater than 10.0 g/10 min; and (ii) from 40 weight % to 10 weight % of a propylene-based plastomer or elastomer (“PBPE”) having a density less than 0.900 g/cc, and a melt flow rate (MFR) from 5 g/10 min to 30 g/10 min. The present disclosure also provides a process for sealing multilayer films to the base of the fitment and the resultant flexible container formed from the process.

Provided herein are methods of making blended polymer compositions having enhanced elasticity. The present methods comprise the steps of producing a first polymer composition using a VTP catalyst system, producing a second polymer composition using a HMP catalyst system and combining the first polymer composition and the second polymer composition to make the blended polymer composition. The present methods include blending/combining the polymer compositions produced by different catalyst systems. One such catalyst system includes (i) a vinyl-terminated polymer (VTP) catalyst system comprising a VTP catalyst compound (referred to herein also as a “VTP catalyst”) and one or more activators. Another catalyst system includes a high molecular-weight polymer (HMP) catalyst system comprising a HMP catalyst compound (referred to herein also as a “HMP catalyst”) and one or more activators. The activators of these different catalyst systems can be the same or different in whole or in part.

The present disclosure describes bottle closure assemblies which are made at least in part with a polyethylene composition having good processability, good organoleptic properties and good dimensional stability. The bottle closure assembly includes a cap portion, an elongated tether portion, and a retaining means portion. The retaining means portions engages a bottle neck or an upper portion of a bottle. The elongated tether portion connects at least one point on the cap portion to at least one point on the retaining means portion so as to prevent loss of the cap portion from a bottle.

Heterophasic polyolefin composition having an MFR of 7 to 100 g/10 min and having a Tm(1) of 150° C. or higher comprising a propylene butylene copolymer matrix phase and a rubber phase selected from ethylene/C3-C12 alpha olefin plastomers the composition being obtainable by blending A) 60.0 to 99.0 wt.-% of a propylene butylene copolymer which comprises monomer units derived from a) propylene in an amount of 88-98 wt.-% b) butylenes in an amount of 2-12 wt.-% with respect to the total weight the propylene butylene copolymer B) 1.0-40.0 wt.-% of ethylene/C3-C12 alpha olefin plastomers having a density of less than 904 kg/m.sup.3 and optionally a nucleating agent in an amount of less than 0.25 wt.-% with respect to the total of the heterophasic composition.

A polymer sheet includes a core layer containing a propylene impact copolymer (ICP), and a first additional layer comprising a first polymer composition. The propylene impact copolymer (ICP) in the core layer includes a matrix and a dispersed phase. The matrix comprises a polypropylene homopolymer or a propylene/alpha-olefin random copolymer which includes greater than 50 wt. % of units derived from propylene monomer. The dispersed phase includes a copolymer of ethylene and a C.sub.3-C.sub.8 α-olefin. The ICP has a first melting point being greater than 100° C. (e.g., in the range of from 100° C. to 130° C.) and a second melting point. The polymer sheet can also include a second additional layer containing a second polymer composition.

The invention provides a process for the preparation of a multimodal high density polyethylene (HDPE) having a melt flow rate (MFR.sub.2) of 0.1 to 4.0 g/10 min, said process comprising: (i) polymerising ethylene in a first polymerisation stage in the presence of a Ziegler-Natta catalyst to prepare a first ethylene homopolymer having a MFR.sub.2 from 10 to 500 g/10 min; (ii) polymerising ethylene in a second polymerisation stage in the presence of said catalyst and said first ethylene homopolymer to prepare an ethylene homopolymer mixture comprising said first ethylene homopolymer and a second ethylene homopolymer, said mixture having a MFR.sub.2 from 50 to 1000 g/10 min; and (iii) polymerising ethylene and at least one alpha-olefin comonomer in a third polymerisation stage in the presence of said catalyst and said ethylene homopolymer mixture to prepare said multimodal HDPE.

Compositions of compatibilized blends of polyamides in polyesters, methods and resins for forming such compositions, and containers made from such compositions which higher burst pressure, crystallization at higher temperatures during production and reduced haze as compared to than containers made from previous blends are disclosed.

A flame-retardant resin composition may include a base resin composed of polyethylene and an acid-modified polyolefin, a silicone compound, a fatty acid-containing compound, and a hindered amine-based compound that includes a hindered amine structure. The polyethylene may include a high-density polyethylene, a medium-density polyethylene and a low-density polyethylene, where the high-density polyethylene has a density of 945 kg/m.sup.3 or more, the medium-density polyethylene has a density of 914 kg/m.sup.3 or more and less than 945 kg/m.sup.3, and the low-density polyethylene has a density of 864 kg/m.sup.3 or more and less than 914 kg/m.sup.3. The base resin may contain the high-density polyethylene in an amount of 40 mass % or more and 60 mass % or less, the medium-density polyethylene in an amount of 1 mass % or more and 35 mass % or less, and the low-density polyethylene in an amount of 10 mass % or more and 30 mass % or less.