C08L2203/18

Polyethylene Pipe Resin with High Resistance to Slow Crack Growth

The present invention relates to a polyethylene composition comprising a base resin which comprises (A) a first ethylene homo- or copolymer fraction, and (B) a second ethylene-hexene-1 copolymer fraction, wherein fraction (A) has a lower molecular weight than fraction (B) and wherein fraction (B) is present in an amount of from 51.0 to 58.5 wt. %, preferably 52.0 to 57.5 wt. %, more preferably 53.0 to 57.0 wt. % based on the total weight of the base resin, wherein fraction (B) of the base resin has a content of units derived from hexene-1 from 0.80 to 1.45 mol %, preferably of from 0.82 to 1.35 mol % and more preferably of from 0.85 to 1.30 mol %, wherein the base resin has a number average molecular weight Mn of 8,500 g/mol or higher, and wherein the polyethylene composition has a melt flow rate MFRs from 0.10 to 0.30 g/10 min, preferably from 0.15 to 0.28, and still more preferably from 0.16 to 0.25 g/10 min, to a process for producing the polyethylene composition, to an article, especially a pipe comprising the polyethylene composition and to the use of the polyethylene composition for the production of an article, especially a pipe.

Polymers comprising 1,3-cyclobutane dimethanol (CBDO-1)

A polymer includes a plurality of repeated polymerized units according to scheme (2): ##STR00001##

NUCLEATED PROPYLENE POLYMER COMPOSITION WITH HIGH TOUGHNESS

The present invention is directed to a propylene polymer composition comprising (a) at least 90 wt. %, based on the weight of the total propylene homopolymer composition, of a propylene homopolymer having (i) a pentad isotacticity (mmmm) of equal or more than 98.0 mol.-%, determined by quantitative .sup.13C NMR spectroscopy, (ii) a relative amount of <2,1> erythro regio-defects of not more than 0.2 mol.-%, determined by quantitative .sup.13C NMR spectroscopy, as described herein, and (b) a nucleating agent (B) selective for the beta-modification of isotactic polypropylene in an amount of from 0.001 to 1.0 wt. %, based on the weight of the total propylene homopolymer composition, wherein said propylene homopolymer composition has a melt flow rate MFR.sub.2 (230° C., 2.16 kg) according to ISO 1133 of 0.1 to 10 g/10 min., a beta-phase content of not less than 80%, measured by wide angle x-ray scattering (WAXS). Further disclosed is a moulded propylene homopolymer product obtainable by compression moulding or extrusion of the propylene homopolymer composition.

Thermoplastic vulcanizate conduits for transporting hydrocarbon fluids

A conduit, particularly flexible conduit comprises an inner tubular housing, at least one reinforcing layer at least partially disposed around the inner housing, an outer protective sheath at least partially disposed around the at least one reinforcing layer, and optionally a thermally insulating layer disposed between the at least one reinforcing layer and the outer protective sheath. At least one of the outer protective sheath and the thermally insulating layer comprises a thermoplastic vulcanizate composition.

Polyethylene Having High Pressure Resistance and Crosslinked Polyethylene Pipe Comprising the Same

The present disclosure relates to a polyethylene having high pressure resistance and a crosslinked polyethylene pipe including the same. The polyethylene according to the present disclosure has high melt index and density and exhibits a sufficient degree of crosslinking, thereby exhibiting excellent strength and pressure resistance characteristics.

ADHESIVE POLYETHYLENE COMPOSITION

The present invention relates to an adhesive polyethylene composition comprising (A) from 60 to 90 wt % of a non-elastomeric polyethylene being a terpolymer of ethylene with two different alpha-olefin comonomer units selected from alpha-olefins having from 4 to 12 carbon atoms; (B) from 9.0 to 38 wt % of an elastomer; wherein onto component (A) or components (A) and (B) an acid grafting agent (C) has been grafted in an amount of from 0.01 to 3.0 wt %, all based on the total weight of the adhesive polyethylene composition, a multi-layer structure comprising said adhesive polyethylene composition and the use of said adhesive polyethylene composition for the production of a multi-layer structure.

ADHESIVE POLYETHYLENE COMPOSITION

The present invention relates to an adhesive polyethylene composition comprising (A) from 60 to 90 wt % of a non-elastomeric polyethylene; (B) from 9.0 to 38 wt % of an ethylene based elastomer being a copolymer of ethylene and alpha-olefin comonomer units having from 4 to 12 carbon atoms; wherein onto component (A) or components (A) and (B) an acid grafting agent (C) has been grafted in an amount of from 0.01 to 3.0 wt %, all based on the total weight of the adhesive polyethylene composition, a multi-layer structure comprising said adhesive polyethylene composition and the use of said adhesive polyethylene composition for the production of a multi-layer structure.

Gas Barrier Resin Composition, Method for Producing Gas Barrier Resin Composition, and Molded Product
20230250269 · 2023-08-10 · ·

Provided are: a gas barrier resin composition having sufficient long-run workability and superior gas barrier properties which compare favorably to those of fossil fuel-derived resins, while containing a biomass-derived raw material; a multilayer structure in which the gas barrier resin is used; and a method for producing such a gas barrier resin composition. The gas barrier resin composition contains at least one type of saponified ethylene-vinyl ester copolymer, wherein of ethylene and a vinyl ester, which are raw materials of the at least one type of saponified ethylene-vinyl ester copolymer, a part is derived from biomass, and a remainder is derived from a fossil fuel.

TUBE, AND POLYAMIDE RESIN COMPOSITION
20220127458 · 2022-04-28 · ·

Disclosed are: a tube containing a layer that contains 60 to 80% by mass of a semi-aromatic polyamide and 15 to 40% by mass of an elastomer modified with an unsaturated compound having at least one selected from a carboxy group and an acid anhydride group, wherein the layer has a phase-separated structure containing a phase (A) that contains the semi-aromatic polyamide, and a phase (B) that contains the elastomer, and the phase (A) is a continuous phase and the phase (B) is a disperse phase dispersed in the phase (A), and in a cross-sectional image of the layer as observed with an electron microscope, the average number of the phase (B) having a major axis diameter of 2 μm or more and existing per 100 square μm is 1/100 μm.sup.2 or less; and a polyamide resin composition prepared by melt-kneading a semi-aromatic polyamide and an elastomer modified with an unsaturated compound having at least one selected from a carboxy group and an acid anhydride group, wherein the total concentration of the carboxy group and the acid anhydride group in 1 g of the elastomer is 85 to 250 μeq/g.

Barrier layer for hoses

The invention relates to a hose having at least one barrier layer inner layer and an outer layer, wherein the barrier layer is obtainable by extrusion of a mixture comprising a) at least one thermoplastic fluoropolymer, b) at least one fluororubber and a crosslinking agent and/or at least one fluororubber elastomer and c) at least one carbon filler selected from carbon black, in particular conductivity carbon black, graphene, carbon nanofillers, in particular carbon nanotubes, carbon nanohorns, or a combination thereof in an amount of 0.05% by weight to 20% by weight of the carbon filler(s), or irradiated PTFE, and vulcanization. The hose exhibits a high fuel, diesel and oil stability and dynamic capability.