The present invention relates to a reactor system for a multimodal polyethylene polymerization process, comprising; (a) a first reactor; (b) a hydrogen removal unit arranged between the first reactor and a second reactor comprising at least one vessel connected with a depressurization equipment, preferably selected from vacuum pump, compressor, blower, ejector or a combination thereof, the depressurization equipment allowing to adjust an operating pressure to a pressure in a range of 100-200 kPa (abs); (c) the second reactor; and (d) a third reactor and the use thereof as a container.

The invention relates to bissilylamino-functionalized conjugated dienes, their preparation and their use in the production of rubbers. Further, the invention relates to rubbers and rubber compositions, and tires produced therefrom. The functionalized conjugated dienes are selected from the group of compounds of formula (Ia), (Ib), (Ic).

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Polymerization processes and reactor systems for producing multimodal ethylene polymers are disclosed in which at least one loop reactor and at least one fluidized bed reactor are utilized. Configurations include a loop reactor in series with a fluidized bed reactor and two loop reactors in series with a fluidized bed reactor.

A polyolefin resin composition is provided that is suitable for use in power cables by virtue of excellent insulation characteristics and to an article molded therefrom. The polyolefin resin composition is excellent in thermal resistance, breakdown voltage, DC insulation, and mechanical properties. Accordingly, the polyolefin resin article prepared therefrom can be advantageously used as an insulation layer of a power cable.

The invention relates to a polypropylene composition comprising a propylene homopolymer or propylene-ethylene copolymer having an ethylene content of at most (1.0) wt % based on the propylene-ethylene copolymer, wherein the amount of propylene homopolymer or propylene-ethylene copolymer is at least (98) wt %, for example at least (98.5) wt %, preferably at least (99) wt %, more preferably at least (99.5), for example at least (99.75) wt % based on the polypropylene composition, wherein the polypropylene composition has a melt flow rate in the range of (0.10) to less than (0.70) dg/min as measured according to ISO1133 (2.16 kg/230° C.), an Mw/Mn in the range from (7.0) to (13.0), wherein Mw stands for the weight average molecular weight and Mn stands for the number average weight, an Mz/Mn is in the range from (20) to (50), wherein Mz stands for the z-average molecular weight and wherein Mw, Mn and Mz are measured according to ASTM (D6474-12).

Polymerization processes and reactor systems for producing multimodal ethylene polymers are disclosed in which at least one loop reactor and at least one fluidized bed reactor are utilized. Configurations include a loop reactor in series with a fluidized bed reactor and two loop reactors in series with a fluidized bed reactor.

A method comprising introducing a polymerization feed comprising an α-olefin, a diluent, and a diene to a polymerization system, under polymerization conditions, whereby a polymer product is produced, wherein the diene is present at a level in the range of from about 1 ppm to about 1000 ppm based on the diluent.

New polypropylene composition which combines low sealing initiation temperature (SIT), low overall migration, good mechanical and optical properties, its use and articles made therefrom.

The present invention deals with a process for producing a multimodal ethylene polymer composition suitable for producing films by blow moulding and comprising the steps of (i) homopolymerising ethylene or copolymerising ethylene and an alpha-olefin comonomer in a first polymerisation step in the presence of a silica supported Ziegler-Natta catalyst to produce a first ethylene homo- or copolymer (PEI) having a density of from 940 to 980 kg/m.sup.3 and a melt flow rate MFR.sub.2 of from 2 to 1000 g/10 min, provided that if the first ethylene homo- or copolymer (PE1) is a copolymer, MFR.sub.2 thereof is in the range of 2 to 100 g/10 min; (ii) homopolymerising ethylene or copolymerising ethylene and an alpha-olefin comonomer in a second polymerisation step in the presence of the first ethylene homo- or copolymer to produce a first ethylene polymer mixture (PEM1) comprising the first ethylene homo- or copolymer and a second ethylene homo- or copolymer (PE2), said first ethylene polymer mixture having a density of from 940 to 980 kg/m.sup.3 and a melt flow rate MFR.sub.2 of from 10 to 1000 g/10 min; (iii) copolymerising ethylene and an alpha-olefin comonomer in a third polymerisation step in the presence of the first ethylene polymer mixture (PEM1) to produce a second ethylene polymer mixture (PEM2) comprising the first ethylene polymer mixture (PEM1) and a third ethylene copolymer (PE3), said second ethylene polymer mixture (PEM2) having a density of from 915 to 940 kg/m.sup.3 and a melt flow rate MFR.sub.5 of from 0.3 to 5 g/10 min, and wherein the second ethylene polymer mixture comprises from 10 to 35% by weight of the first ethylene homo- or copolymer, from 10 to 35% by weight of the second ethylene homo- or copolymer and from 45 to 70% by weight of the third ethylene copolymer.

Disclosed herein are ethylene-based polymers generally characterized by a density of at least 0.94 g/cm.sup.3, a high load melt index from 4 to 20 g/10 min, a zero-shear viscosity at 190° C. from 20,000 to 400,000 kPa-sec, and a relaxation time at 190° C. from 225 to 3000 sec. These ethylene polymers can be produced by peroxide-treating a broad molecular weight distribution Ziegler-catalyzed resin, and can be used in large diameter, thick wall pipes and other end-use applications.