Linear low density polyethylene (LLDPE) that is prepared with a single site catalyst has relatively low modulus in comparison to a polyethylene of similar melt index and density made with a conventional Zeigler Natta catalyst. Films that are prepared from polyethylene having a low modulus have a soft and flexible “feel”, which is undesirable for some packaging applications. The present invention provides a method to increase the modulus of single site catalyzed polyethylene.

The invention features hot melt adhesive compositions including from 50% by weight to 95% by weight of a non-single site catalyzed amorphous poly alpha-olefin copolymer derived from propylene and at least one monomer selected from the group consisting of butene and hexene and having a viscosity of no greater 10,000 cP at 190° C. and from 5% by weight to 45% by weight of a polybutene-1 polymer.

Ethylene-based polymers are characterized by a density from 0.92 to 0.955 g/cm.sup.3, a HLMI of less than 35 g/10 min, and a ratio of a number of short chain branches (SCBs) per 1000 total carbon atoms at Mz to a number of SCBs per 1000 total carbon atoms at Mn in a range from 11.5 to 22. These polymers can have a higher molecular weight (HMW) component and a lower molecular weight (LMW) component, in which a ratio of a number of SCBs per 1000 total carbon atoms at Mn of the HMW component to a number of SCBs per 1000 total carbon atoms at Mn of the LMW component is in a range from 10.5 to 22. These ethylene polymers can be produced using a dual catalyst system containing an unbridged metallocene compound with an indenyl group having at least one halogen-substituted hydrocarbyl substituent with at least two halogen atoms, and a single atom bridged metallocene compound with a fluorenyl group and a cyclopentadienyl group.

The present invention relates to a tyre for vehicle wheels, in particular automobile wheels, characterised by a tread comprising at least one iso-styrene/trans-butadiene/terpene random terpolymer. Said tread is characterised by a greater tear resistance and a greater grip of the tyre to the roadbed.

The present disclosure generally relates to catalyst systems, polyethylene compositions, and uses of such compositions in, e.g., films. In an embodiment is provided a film that includes a polyethylene composition, comprising: ethylene and a C.sub.3-C.sub.40 olefin comonomer, the polyethylene composition having at least 65 wt % ethylene content and from 0 wt % to 35 wt % of a C.sub.3-C.sub.40 olefin comonomer content based upon the total weight of the composition, the film having: an average of MD and TD 1% secant modulus of 43,000 psi or greater, and a Dart Drop Impact Strength of greater than 500 g/mil. In another embodiment is provided a process for producing a polyethylene composition that includes introducing ethylene and a C.sub.3-C.sub.40 alpha-olefin to a catalyst system, the catalyst system comprising a first catalyst compound, a second catalyst compound, and an activator; and forming a polyethylene composition.

The present invention relates to a rotomolded article, comprising at least one layer, wherein said at least one layer comprising comprises at least one metallocene-catalyzed polyethylene resin comprising at least two metallocene-catalyzed polyethylene fractions A and B; and at least one ionomer;

wherein the polyethylene resin comprises: at least 25% to at most 55% by weight of polyethylene fraction A based on the total weight of the polyethylene resin, wherein fraction A has a density at least 0.005 g/cm.sup.3 higher than the density of the polyethylene resin; and wherein the polyethylene resin has a density of at least 0.930 g/cm.sup.3 to at most 0.954 g/cm.sup.3 as measured according to ASTM D-1505 at 23° C.; a melt index MI2 of at least 1.0 g/10 min to at most 25.0 g/10 min as determined according to ISO 1133, condition D, at 190° C. and under a load of 2.16 kg.

The present invention also relates to a process for preparing said rotomolded article.

The inventors have discovered that certain hot melt adhesives can be used to form a stable stacked pallet that can limit the need for additional packaging materials e.g. inter-layer and pallet wrap.

New C.sub.2C.sub.3 random copolymers, which combine low sealing initiation temperature (SIT), high hot-tack, low C6-solubles, good optical properties and an improved stiffness/impact balance, which are particularly suited for preparing blown films. The present invention is furthermore related to the manufacture of said copolymers and to their use, as well as to the blown films comprising such C.sub.2C.sub.3 random copolymers.

Disclosed are a sealing material for solar cell modules and a manufacturing method thereof capable of endowing good transparency and heat resistance to the sealing material for solar cell modules while using a polyethylene-based resin. The disclosed sealing material for solar cell modules uses a polyethylene-based resin with a density of 0.900 g/cm3 or less, and an MFR between 0.1 g/10 min and 1.0 g/10 min. The sealing material is obtained by melt molding a resin composition containing a polyethylene-based resin with density 0.890 g/cm3 or less, and a polymerization initiator contained at 0.02 mass % or more but less than 0.5 mass % of the composition, wherein the density difference of the resin composition before and after the melt molding is within 0.05 g/cm3, and the MFR difference of the resin composition before and after the melt molding is 1.0 g/10 min or greater.

Disclosed are a sealing material for solar cell modules and a manufacturing method thereof capable of endowing good transparency and heat resistance to the sealing material for solar cell modules while using a polyethylene-based resin. The disclosed sealing material for solar cell modules uses a polyethylene-based resin with a density of 0.900 g/cm3 or less, and an MFR between 0.1 g/10 min and 1.0 g/10 min. The sealing material is obtained by melt molding a resin composition containing a polyethylene-based resin with density 0.890 g/cm3 or less, and a polymerization initiator contained at 0.02 mass % or more but less than 0.5 mass % of the composition, wherein the density difference of the resin composition before and after the melt molding is within 0.05 g/cm3, and the MFR difference of the resin composition before and after the melt molding is 1.0 g/10 min or greater.