C08L2314/06

Metallocene Catalyzed Polyethylene Resin
20170321047 · 2017-11-09 ·

The present invention relates to a metallocene-catalyzed polyethylene resin comprising at least two metallocene-catalyzed polyethylene fractions A and B, wherein the polyethylene resin comprises: at least 25% to at most 55% by weight of polyethylene fraction A based on the total weight of the polyethylene resin, wherein fraction A has a density at least 0.005 g/cm.sup.3 higher than the density of the polyethylene resin; and a melt index MI2 of at least 25.0 g/10 min as determined according to ISO 1133, condition D, at 190° C. and under a load of 2.16 kg; and wherein the polyethylene resin has a density of at least 0.938 g/cm.sup.3 to at most 0.954 g/cm.sup.3 as measured according to ASTM D-1505 at 23° C.; a melt index MI2 of at least 2.5 g/10 min to at most 25.0 g/10 min as determined according to ISO 1133, condition D, at 190° C. and under a load of 2.16 kg and a molecular weight distribution M.sub.w/M.sub.n of at least 2.6 to at most 4.2, with M.sub.w being the weight-average molecular weight and M.sub.n being the number-average molecular weight.

The present invention also relates to an article comprising said resin.

Rotomolded Articles Comprising Metallocene-Catalyzed Polyethylene Resin

The present invention relates to a rotomolded article, comprising at least one metallocene-catalyzed polyethylene resin comprising at least two metallocene-catalyzed polyethylene fractions A and B, wherein the polyethylene resin comprises: at least 25% to at most 55% by weight of polyethylene fraction A based on the total weight of the polyethylene resin, wherein fraction A has a melt index MI2 of at least 25.0 g/10 min as determined according to ISO 1133, condition D, at 190° C. and under a load of 2.16 kg, and a density at least 0.005 g/cm.sup.3 higher than the density of the polyethylene resin; and wherein the polyethylene resin has a density of at least 0.938 g/cm.sup.3 to at most 0.950 g/cm.sup.3 as measured according to ASTM D-1505 at 23° C.; a melt index MI2 of at least 1.0 g/10 min to at most 25.0 g/10 min as determined according to ISO 1133, condition D, at 190° C. and under a load of 2.16 kg.

The present invention also relates to a process for preparing said rotomolded article.

POLYMER COMPOSITIONS AND EXTRUSION COATED ARTICLES
20170321048 · 2017-11-09 · ·

The present invention relates to a polymer composition (A) comprising a blend of i) 60 to 90 wt-% of propylene polymer composition (a) comprising a blend of (a-1) 55 to 95 wt-% of propylene polymer and (a-2) 5 to 45 wt-% of low density ethylene polymer and ii) 10 to 40 wt-% of a plastomer (b) of ethylene copolymer. The invention relates also to extrusion coating articles, comprising at least a substrate layer and a heat sealable layer, wherein composition (A) is used as said heat sealable layer, process for producing the extrusion coated articles as well use of the composition (A) as a heat sealable layer in an extrusion coated article.

ROTOMOLDED ARTICLES

This disclosure relates to rotomolded articles, having a wall structure, where the wall structure contains at least one layer containing an ethylene interpolymer product, or a blend containing an ethylene interpolymer product and an ethylene polymer, where the ethylene interpolymer product has a Dilution Index (Y.sub.d) greater than 0 and improved Environmental Stress Crack Resistance (ESCR). The ethylene interpolymer product has a melt index from about 0.5 to about 15 dg/minute, a density from about 0.930 to about 0.955 g/cm.sup.3, a polydispersity (M.sub.w/M.sub.n) from about 2 to about 6 and a CDBI.sub.50 from about 50% to about 98%. Further, the ethylene interpolymer products are a blend of at least two ethylene interpolymers; where one ethylene interpolymer is produced with a single-site catalyst formulation and at least one ethylene interpolymer is produced with a heterogeneous catalyst formulation.

C2C3 RANDOM COPOLYMER

New C.sub.2C.sub.3 random copolymer (RACO), which shows improved sealing behaviour due to low sealing initiation temperature (SIT) and high hot tack force. In addition, the inventive C.sub.2C.sub.3 random copolymer (RACO) shows an excellent sterilization behaviour, i.e. retention of low haze level after sterilization. The present invention is furthermore related to the manufacture of said C.sub.2C.sub.3 random copolymer (RACO) and to its use.

ENHANCED ESCR AND DUCTILITY BIMODAL ROTOMOLDING RESIN

A polyethylene composition having a high flow index and a bimodal composition provides an outstanding combination of environmental stress crack resistance (ESCR) and ductility in rotomolded articles. The composition is easy to process/mold.

Heterophasic Polyolefin Composition

A heterophasic polyolefin composition comprising 55 to 95 wt.-% based on the total weight of the heterophasic polyolefin composition of a propylene butene random copolymer (A) having an MFR.sub.2 (230° C.) of 0.3 to 100.0 g/10 min and a butene content of 1.5 to 8.0 wt.-%, wherein the propylene butene random copolymer is obtained by a process using a single site catalyst (I) and 5 to 45 wt.-% based on the total weight of the heterophasic polyolefin composition of a copolymer of ethylene (B) having a density in the range of 910 to 935 kg/m.sup.3 and an MFR.sub.2 (190° C.) of 0.5 to 10 g/10 min, wherein the copolymer of ethylene (B) is obtained by a process using a single site catalyst (II).

Polypropylene-Based Composite

The present invention relates to a polypropylene-based composite, including (A) polypropylene, and (B) an olefin-based polymer satisfying the following conditions: (1) a melt index (MI, 190° C., 2.16 kg load conditions) is from 0.1 g/10 min to 10.0 g/10 min, (2) a density (d) is from 0.860 g/cc to 0.880 g/cc, and (3) T(90)-T(50)≤50 and T(95)-T(90)≥10 are satisfied, wherein T(50), T(90) and T(95) are temperatures at which 50%, 90%, and 95% are melted, respectively, when fractionating a temperature-heat capacity curve from measurement results by the differential scanning calorimetry precise measurement method (SSA). The polypropylene-based composite of the present invention may show excellent impact strength.

Injection-molded articles comprising metallocene-catalyzed polyethylene resin

The present invention relates to an injection-molded article, comprising at least one metallocene-catalyzed polyethylene resin comprising at least two metallocene-catalyzed polyethylene fractions A and B, wherein the at least one metallocene-catalyzed polyethylene resin comprises: at least 40% to at most 50% by weight of polyethylene fraction A based on the total weight of the at least one metallocene-catalyzed polyethylene resin, wherein fraction A has a melt index MI2 of at least 100.0 g/10 min as determined according to ISO 1133, condition D, at 190° C. and under a load of 2.16 kg; and
wherein the at least one metallocene-catalyzed polyethylene resin has a density of at least 0.940 g/cm.sup.3 to at most 0.950 g/cm.sup.3 as measured on pellets according to ISO 1183 at 23° C.; a melt index MI2 of at least 1.4 g/10 min to at most 2.5 g/10 min as measured on pellets according to ISO 1133, condition D, at 190° C. and under a load of 2.16 kg. The present invention also relates to a process for preparing said injection-molded article, comprising the steps of a) providing at least one metallocene-catalyzed polyethylene resin as described herein; and b) injection-molding said polyethylene resin into an article.

A POLYMER COMPOSITION SUITABLE FOR GAMMA-RAY STERILIZATION
20210395503 · 2021-12-23 ·

The present invention is directed to a polymer composition (C) comprising a first propylene homopolymer (H-PP), at least one hydrocarbon oil, at least one nucleating agent and at least one antioxidant, a moulded article formed from said polymer composition, a process for gamma-ray sterilization of said moulded article and uses of hydrocarbon oil in said polymer composition for improving resistance to gamma-ray radiation and reducing discoloration after gamma-ray sterilization in said polymer composition.