This invention relates to an improved method for the preparation of highly or substantially pure Indigotindisulfonate sodium (1). It further relates to the novel crystalline form I of Indigotindisulfonate sodium (1) and the process for its preparation.

This invention relates to an improved method for the preparation of highly or substantially pure Indigotindisulfonate sodium (1). It further relates to the novel crystalline form I of Indigotindisulfonate sodium (1) and the process for its preparation.

Process for preparing disodium 5,5-indigosulfonate, the feedstock being indigo, this process including the following steps: i) the indigo is subjected to a sulfonation treatment resulting in a mixture that contains 5,5-indigosulfonic acid, this process including: ii) a reduction treatment is applied to the mixture obtained in step i), and optionally a purification step, so as to obtain a composition including leuco-5,5-indigosulfonic acid, iii) the leuco-5,5-indigosulfonic acid is isolated from the composition resulting from step ii), iv) the leuco-5,5-indigosulfonic acid resulting from step iii) is oxidized to give disodium 5,5-indigosulfonate.

Process for preparing disodium 5,5-indigosulfonate, the feedstock being indigo, this process including the following steps: i) the indigo is subjected to a sulfonation treatment resulting in a mixture that contains 5,5-indigosulfonic acid, this process including: ii) a reduction treatment is applied to the mixture obtained in step i), and optionally a purification step, so as to obtain a composition including leuco-5,5-indigosulfonic acid, iii) the leuco-5,5-indigosulfonic acid is isolated from the composition resulting from step ii), iv) the leuco-5,5-indigosulfonic acid resulting from step iii) is oxidized to give disodium 5,5-indigosulfonate.

The present disclosure provides dye compounds for use in dyeing textiles.

The present disclosure provides dye compounds for use in dyeing textiles.

The invention relates to: a compound derived from 7,7-diazaisoindigo; an organogel, formed by these compounds, having an aggregation-induced emission (AIE) in the red region of the visible spectrum (600-800 nm); and a xerogel produced by drying said organogel. Due to these properties, said organogel or xerogel can be applied to optoelectronic devices or fluorescent sensors.

The present disclosure provides dye compounds for use in dyeing textiles.

The present invention refers to a process for purifying leucoindigo salt solutions, for removal of aromatic amines, particularly aniline and N-methylaniline, comprising: adding to a purification vessel a leucoindigo salt solution containing aromatic amines, said solution in the form of a stationary mass; bubbling with a controlled flow rate an inert gas in the purification vessel, by means of a device submerged at the surface of the stationary mass; injecting with a controlled flow rate a gas purification current into the vessel, by means of a device submerged at the stationary mass; and recovering the purified solution from the vessel. It also refers to the use of inert gas in a process for purifying leucoindigo salt solutions, acting as a gas anti-foaming agent, to reduce foam and chances of product stripping during processing.

The present invention refers to a process for purifying leucoindigo salt solutions, for removal of aromatic amines, particularly aniline and N-methylaniline, comprising: adding to a purification vessel a leucoindigo salt solution containing aromatic amines, said solution in the form of a stationary mass; bubbling with a controlled flow rate an inert gas in the purification vessel, by means of a device submerged at the surface of the stationary mass; injecting with a controlled flow rate a gas purification current into the vessel, by means of a device submerged at the stationary mass; and recovering the purified solution from the vessel. It also refers to the use of inert gas in a process for purifying leucoindigo salt solutions, acting as a gas anti-foaming agent, to reduce foam and chances of product stripping during processing.