Disclosed in the present invention are near-infrared reflecting functional pigment, paint, and panel, especially, used for a vehicle pigment or the like. The pigment according to the present invention comprises: a platelet-like substrate; a first metal oxide layer coated on at least a portion of the substrate and having a refractive index of 1.8 or larger, and a second metal oxide layer coated on at least a portion of the first metal oxide layer and containing an absorbent material, wherein the pigment reflects on average at least 30% of an IR electron beam of 850-950 nm.

Provided are a coating film that has high radio wave permeability and low haze in addition to excellent infrared light reflectivity and visible light permeability, and an article comprising such a coating film. The coating film is a coating film produced using a coating composition, wherein the coating composition comprises flat pigment particles and a resin component, the flat pigment particles comprise a laminate of dielectric layers and a metallic thin film layer, the dielectric layer and the metallic thin film layer are stacked alternately in the laminate, and the dielectric layers are outermost layers of the laminate, an aspect ratio of the flat pigment particles is 10 to 400, a pigment surface density of the flat pigment particles in the coating film is 50% to 300%, and a film thickness of the coating film is 1 m or more. The article comprises the coating film.

A LiDAR reflecting dark colored pigment includes a core layer formed from a reflecting material and a first layer formed from a first absorber material or a first dielectric material extending across the core layer. A second layer formed from a second absorber material different than the third absorber material extends across the first layer and a third layer formed from a third absorber material or a second dielectric material extends across the second layer. The third absorber material is different than the second absorber material. The LiDAR reflecting dark colored pigment reflects less than 10% of incident visible electromagnetic radiation and more than 60% of incident near-IR electromagnetic radiation with wavelengths between and including 850 nm and 950 nm for all incident angles of the visible and near-IR electromagnetic radiation between and including 0 and 45. A color reflected by the multilayer stack has a lightness in CIELAB color space less than or equal to 40.

Provided is an infrared-reflective coating composition that includes: a scale-like infrared-reflective pigment; and a resin component, wherein the pigment includes a layered body that has dielectric layers and a metal thin film layer layered in an alternate fashion with the dielectric layer on the outermost layer; the dielectric layer is formed from one or more materials such as titanium dioxide; the metal thin film layer is formed from a silver compound; a film thickness of the metal thin film layer is 5 to 15 nm; a film thickness of the dielectric layer is ((N)/(4r))20 nm (N=1, 2 or 3) wherein wavelength of incident light is 250 to 980 nm, and r is a refractive index of the dielectric layer; and a proportion of the infrared-reflective pigment having a particle diameter of 1 m or smaller is 10% by volume or smaller.

Provided is a multi-layer coating film including a base film and an infrared-reflective film, wherein the infrared-reflective film includes a scale-like infrared-reflective pigment and a resin; the pigment includes a layered body that has dielectric layers and a metal layer layered in an alternate fashion with the dielectric layer on the outermost layer; the dielectric layer is formed from one or more materials such as titanium dioxide; the metal layer is made from a silver compound; a film thickness of the metal layer is 5 to 15 nm; a film thickness of the dielectric layer is ((N)/(4r))20 nm (N is 1, 2 or 3, wavelength is 250 to 980 nm, r is the refractive index of the dielectric layer); the infrared reflectance R1 of the base film is smaller than 80% and is smaller than the infrared reflectance R2 of the infrared-reflective film.

An encapsulated palette flake includes a palette flake having a first surface and a second surface, and a layer on at least one of the first surface and the second surface. A blackness My of the encapsulated palette flake is greater than or equal to 110 and less than or equal to 140. A reflectivity of the encapsulated palette flake in a visible spectrum of electromagnetic radiation that is less than or equal to 10.0%. A reflectivity of the encapsulated palette flake in a near-IR and LiDAR spectrum of electromagnetic radiation that is between 10% and 90%. A method for forming an encapsulated palette flake includes combining a base solution comprising palette flakes and a precipitating agent with a solution comprising a copper source, drying the precipitate, and calcining the dried precipitate. The precipitating agent is selected from sodium hydroxide, sodium carbonate, or ammonium carbonate.

To provide an infrared-reflective pigment and infrared-reflective coating composition provided with both high infrared-light reflecting properties and high visible-light transparency. Provided is a flake-shaped infrared-reflective pigment, the infrared-reflective pigment 1 characterized by being provided with a layered body 13 having at least one metal thin-film layer 11 and at least two transparent dielectric layers 12, the film thickness of the dielectric layer 12 being (an integer multiple of /4n)10 nm, where is the wavelength of incident light in a visible-light peripheral region and n is the refractive index of the dielectric layer 12. Also provided is an infrared-reflective coating composition containing the infrared-reflective pigment 1.

There is disclosed a functional lamellar particle including an unconverted portion of the lamellar particle, wherein the unconverted portion includes a first metal, a converted portion of the lamellar particle disposed external to a surface of the unconverted portion, wherein the converted portion includes a chemical compound of the first metal; and a functional coating disposed external to a surface of the converted portion.

There is disclosed a lamellar particle including an unconverted portion of the lamellar particle, wherein the unconverted portion includes a first metal, a converted portion of the lamellar particle disposed radially outward of at least one of a surface of the unconverted portion, wherein the converted portion includes a chemical compound of the first metal.

The invention relates to a pigment which reflects IR radiation, comprising an IR-reflecting core, the IR-reflecting core being provided with a substantially enveloping coating which is transparent to IR radiation, and in that the IR-reflecting pigment is substantially white. The invention further relates to a process for producing these pigments and also to their use.