Compositions and methods are described which provide a protective coating to coils or springs via a polymerization process such as by covalent bonding that includes grafting to the metal surface.

Parts made by additive manufacturing are often structural in nature, rather than having functional properties conveyed by a polymer or other component present therein. Printed parts having piezoelectric properties may be formed using compositions comprising a plurality of piezoelectric particles and a polymer material comprising at least one thermoplastic polymer and at least one thermally curable polymer precursor. At a sufficient temperature, the at least one thermally curable polymer precursor may undergo a reaction, optionally also undergoing a reaction with the piezoelectric particles, and form an at least partially cured printed part. The piezoelectric particles may be mixed with the polymer material and remain substantially non-agglomerated when combined with the polymer material. The compositions may define a form factor such as a composite filament, a composite pellet, or an extrudable composite paste, which may be utilized in forming printed part by extrusion, layer-by-layer deposition, and thermal curing.

Parts made by additive manufacturing are often structural in nature, rather than having functional properties conveyed by a polymer or other component present therein. Printed parts having piezoelectric properties may be formed using compositions comprising a plurality of piezoelectric particles and a polymer material comprising at least one thermoplastic polymer and at least one thermally curable polymer precursor. At a sufficient temperature, the at least one thermally curable polymer precursor may undergo a reaction, optionally also undergoing a reaction with the piezoelectric particles, and form an at least partially cured printed part. The piezoelectric particles may be mixed with the polymer material and remain substantially non-agglomerated when combined with the polymer material. The compositions may define a form factor such as a composite filament, a composite pellet, or an extrudable composite paste, which may be utilized in forming printed part by extrusion, layer-by-layer deposition, and thermal curing.

An anti-fog material comprising a zwitterionic-doped hydrogel made up of charged monomers, at least a portion of which comprise zwitterionic monomers, uncharged hydrophilic monomers, and at least one crosslinking agent is disclosed. A composition for forming the hydrogel and a transparent, removable article comprising the anti-fog material are also disclosed. The article, which may be in the form of a film or decal, may comprise an active layer attached to a backing layer, the active layer comprising an anti-fog material described herein. A method of making a surface of a substrate resistant to fogging by applying the transparent and removable article thereto is also disclosed.

An anti-fog material comprising a zwitterionic-doped hydrogel made up of charged monomers, at least a portion of which comprise zwitterionic monomers, uncharged hydrophilic monomers, and at least one crosslinking agent is disclosed. A composition for forming the hydrogel and a transparent, removable article comprising the anti-fog material are also disclosed. The article, which may be in the form of a film or decal, may comprise an active layer attached to a backing layer, the active layer comprising an anti-fog material described herein. A method of making a surface of a substrate resistant to fogging by applying the transparent and removable article thereto is also disclosed.

The present disclosure provides a window protective film and a display device. The display device includes the window protective film. The window protective film includes a base layer, a soft coating layer disposed on the base layer, and an anti-fingerprint coating layer disposed on the soft coating layer. The soft coating layer includes a conductive polymer layer disposed on and in contact with a first surface of the base layer, a silica coating layer disposed on at least one side of the conductive polymer layer and that includes a plurality of silica nano particles, and a cover layer disposed on at least one side of the silica coating layer.

The present disclosure provides a window protective film and a display device. The display device includes the window protective film. The window protective film includes a base layer, a soft coating layer disposed on the base layer, and an anti-fingerprint coating layer disposed on the soft coating layer. The soft coating layer includes a conductive polymer layer disposed on and in contact with a first surface of the base layer, a silica coating layer disposed on at least one side of the conductive polymer layer and that includes a plurality of silica nano particles, and a cover layer disposed on at least one side of the silica coating layer.

An object of the invention is to provide a photo-alignment copolymer capable of improving upper layer coatability after layer formation, a binder composition, a binder layer, an optical laminate, and an image display device. A photo-alignment copolymer according to the embodiment of the invention has a repeating unit A including a photo-alignment group, a repeating unit B including a crosslinkable group which causes a crosslinking reaction by the action of at least one selected from the group consisting of light, heat, an acid, and a base, and a repeating unit C including a cleaving group which decomposes by the action of at least one selected from the group consisting of light, heat, an acid, and a base to produce a polar group, and the repeating unit C has the cleaving group on a side chain, and has a group of atoms which is provided on a side closer to a terminal than the cleaving group on the side chain to be able to unevenly distribute the photo-alignment copolymer on an air interface side.

An object of the invention is to provide a photo-alignment copolymer capable of improving upper layer coatability after layer formation, a binder composition, a binder layer, an optical laminate, and an image display device. A photo-alignment copolymer according to the embodiment of the invention has a repeating unit A including a photo-alignment group, a repeating unit B including a crosslinkable group which causes a crosslinking reaction by the action of at least one selected from the group consisting of light, heat, an acid, and a base, and a repeating unit C including a cleaving group which decomposes by the action of at least one selected from the group consisting of light, heat, an acid, and a base to produce a polar group, and the repeating unit C has the cleaving group on a side chain, and has a group of atoms which is provided on a side closer to a terminal than the cleaving group on the side chain to be able to unevenly distribute the photo-alignment copolymer on an air interface side.

This invention relates to a one-step process for making a polymer composite suspension for coating plastic films characterized in that a first polymer is synthesized in-situ optionally in the presence of other polymers and in the presence of clay. Preferably the polymer composite suspension comprises a) 1.0 to 11.0 wt % of clay or silane modified clay, b) 0.1 to 10.0 wt % of poly (acrylic acid), which is a copolymer of acrylic acid (AA) with at least one other monomer selected from 2-ethylhexyl acrylate (EHA), β-carboxyethyl acrylate (β-CEA), methacrylamidoethyl ethylene urea (WAM II) and ethoxylated behenyl methacrylate (β-FM), c) 1.0 to 15.0 wt % of other polymers, preferably poly (vinyl alcohol) and d) 70 to 97 wt % of water or mixture of water with 2-propanol. The coating films made from the suspensions show good barrier capabilities against water vapor and oxygen can be used to make barrier layers on or within plastic films for packaging applications. The invention also relates to methods for making silane modified clay usable in the process for making the suspensions.