This invention relates to a one-step process for making a polymer composite suspension for coating plastic films characterized in that a first polymer is synthesized in-situ optionally in the presence of other polymers and in the presence of clay. Preferably the polymer composite suspension comprises a) 1.0 to 11.0 wt % of clay or silane modified clay, b) 0.1 to 10.0 wt % of poly (acrylic acid), which is a copolymer of acrylic acid (AA) with at least one other monomer selected from 2-ethylhexyl acrylate (EHA), β-carboxyethyl acrylate (β-CEA), methacrylamidoethyl ethylene urea (WAM II) and ethoxylated behenyl methacrylate (β-FM), c) 1.0 to 15.0 wt % of other polymers, preferably poly (vinyl alcohol) and d) 70 to 97 wt % of water or mixture of water with 2-propanol. The coating films made from the suspensions show good barrier capabilities against water vapor and oxygen can be used to make barrier layers on or within plastic films for packaging applications. The invention also relates to methods for making silane modified clay usable in the process for making the suspensions.

Disclosed methods include formulating azobenzene-based polymer networks to induce a modulus change in a highly crosslinked polymer, in vivo, with no external heat requirement and using a benign light as the source of stimuli. A modulus change can be achieved via a coating on the substrate and within the bulk of the substrate via photoexposure. The azobenzene-based polymer network can be formed as a coating or in the bulk of a material from either a glassy composition comprising methyl methacrylate (MMA), poly (methyl methacrylate) (PMMA), and triethylene glycol dimethacrylate (TEGDMA) or a soft material comprising of long-chain difunctional acrylates. The disclosed technology also includes methods of biofilm disruption and removal from the surface of a substrate, and includes methods of inhibiting biofilm growth and cell attachment to a substrate.

Disclosed methods include formulating azobenzene-based polymer networks to induce a modulus change in a highly crosslinked polymer, in vivo, with no external heat requirement and using a benign light as the source of stimuli. A modulus change can be achieved via a coating on the substrate and within the bulk of the substrate via photoexposure. The azobenzene-based polymer network can be formed as a coating or in the bulk of a material from either a glassy composition comprising methyl methacrylate (MMA), poly (methyl methacrylate) (PMMA), and triethylene glycol dimethacrylate (TEGDMA) or a soft material comprising of long-chain difunctional acrylates. The disclosed technology also includes methods of biofilm disruption and removal from the surface of a substrate, and includes methods of inhibiting biofilm growth and cell attachment to a substrate.

A UV-cured cross-linked liquid resin reinforced with ceramic inorganic nano-particles and ceramic inorganic abrasion-resistant powder, comprised of 30%-45% by weight resin, wherein the resin is at least one of 2-propenoic acid, homopolymer, isophthalic acid, 1,4-Dimethoxybenzene, saturated polyester resin, and maleic anhydride; 10%-20% by weight industrial ceramic inorganic nano-materials; 30%-45% by weight industrial ceramic inorganic abrasion-resistant powder; and styrene, wherein the styrene is less than 25% by weight of the UV-cured cross-linked liquid resin reinforced with ceramic inorganic nano-particles and ceramic inorganic abrasion-resistant powder.

A UV-cured cross-linked liquid resin reinforced with ceramic inorganic nano-particles and ceramic inorganic abrasion-resistant powder, comprised of 30%-45% by weight resin, wherein the resin is at least one of 2-propenoic acid, homopolymer, isophthalic acid, 1,4-Dimethoxybenzene, saturated polyester resin, and maleic anhydride; 10%-20% by weight industrial ceramic inorganic nano-materials; 30%-45% by weight industrial ceramic inorganic abrasion-resistant powder; and styrene, wherein the styrene is less than 25% by weight of the UV-cured cross-linked liquid resin reinforced with ceramic inorganic nano-particles and ceramic inorganic abrasion-resistant powder.

A printing apparatus includes an ejection head including a first nozzle row configured to eject, toward a recording medium, a first liquid containing a photopolymerization initiator and a second nozzle row configured to eject, toward the recording medium, a second liquid containing the polymerizable compound and a color material and not containing the photopolymerization initiator, a driving unit configured to change relative positions of the ejection head and the recording medium, and an irradiation unit configured to irradiate, with the light, the recording medium onto which the first liquid and the second liquid are deposited. The first liquid and the second liquid are ejected from the ejection head so that the second liquid overlaps the first liquid on a surface of the recording medium. A distance between the irradiation unit and the first nozzle row is longer than a distance between the irradiation unit and the second nozzle row.

A printing apparatus includes an ejection head including a first nozzle row configured to eject, toward a recording medium, a first liquid containing a photopolymerization initiator and a second nozzle row configured to eject, toward the recording medium, a second liquid containing the polymerizable compound and a color material and not containing the photopolymerization initiator, a driving unit configured to change relative positions of the ejection head and the recording medium, and an irradiation unit configured to irradiate, with the light, the recording medium onto which the first liquid and the second liquid are deposited. The first liquid and the second liquid are ejected from the ejection head so that the second liquid overlaps the first liquid on a surface of the recording medium. A distance between the irradiation unit and the first nozzle row is longer than a distance between the irradiation unit and the second nozzle row.

A lithographic printing plate precursor including a support and a coating comprising a polymerisable compound, optionally a sensitizer, a photoinitiator and discrete particles is disclosed wherein the discrete particles comprise a crosslinked hydrophobic polymer backbone and a plurality of hydrophobic pendant grafts.

A lithographic printing plate precursor including a support and a coating comprising a polymerisable compound, optionally a sensitizer, a photoinitiator and discrete particles is disclosed wherein the discrete particles comprise a crosslinked hydrophobic polymer backbone and a plurality of hydrophobic pendant grafts.

The present invention relates to a printing substance for coating glass surfaces by way of an ink jet printing method, the printing substance comprising A) at least one monomer having at least one C—C double bond; B) at least one cationically curable monomer comprising epoxy groups; C) at least one cationically curable monomer comprising oxetane groups; D) at least one adhesion agent. In addition, the present invention describes a method for producing the printing substance and the use thereof.