An easy-cleaning coating, an easy cleaning coating having anti-fogging properties, and an easy-cleaning, anti-reflective coating.

Organic coating compositions, particularly antireflective coating compositions for use with an overcoated photoresist, are provided that in a first aspect comprise a crosslinker component that comprises a structure of the following Formula (I): ##STR00001##

A low-reflection coated glass sheet of the present invention includes a glass sheet and a low-reflection coating. The low-reflection coating is formed on at least a portion of one principal surface of the glass sheet and contains a binder containing silica as a main component, fine silica particles bound by the binder, and fine titania particles bound by the binder. The low-reflection coating satisfies the following relationships: 30 mass %<C.sub.SP<68 mass %; 12 mass %≤C.sub.TP<50 mass %; 20 mass %<C.sub.Binder<43.75 mass %; C.sub.TP/C.sub.Binder≥0.6; C.sub.Binder<25 mass % in the case of C.sub.SP≥55 mass %; and C.sub.TP>20 mass % in the case of C.sub.SP<55 mass %. The low-reflection coated glass sheet has a transmittance gain of 2.0% or more.

Provided are a polymer for an organic bottom anti-reflective coating and a bottom anti-reflective coating composition containing the same. More specifically, provided are a polymer for an organic bottom anti-reflective coating capable of relieving reflection of exposure light and irradiation light on a substrate of a photoresist layer applied on the substrate in a lithographic process of manufacturing a semiconductor device, and a bottom anti-reflective coating composition containing the same.

This invention is to provide a hard coating film, comprising a polymethyl methacrylate (PMMA) base film and an antiglare hard coating layer formed thereon, wherein the antiglare hard coating layer comprises a (meth)acrylate composition, an initiator, a plurality of silica nanoparticles, a plurality of organic microparticles and a leveling agent. The (meth)acrylate composition comprises a urethane (meth)acrylate oligomer with a functionality of 6 to 15 and a molecular weight ranging between 1,000 and 4,500, and at least one (meth)acrylate monomer with a functionality of 3 to 6, and at least one (meth)acrylate monomer with functionality of less than 3.

The invention relates to a method of making hybrid organic-inorganic core-shell nano-particles, comprising the steps of a) providing colloidal organic particles comprising a synthetic polyampholyte as a template; b) adding at least one inorganic oxide precursor; and c) forming a shell layer from the precursor on the template to result in core-shell nano-particles. With this method it is possible to make colloidal organic template particles having an average particle size in the range of 10 to 300 nm; which size can be controlled by the comonomer composition of the polyampholyte, and/or by selecting dispersion conditions. The invention also relates to organic-inorganic or hollow-inorganic core-shell nano-particles obtained with this method, to compositions comprising such nano-particles, to different uses of said nano-particles and compositions, and to products comprising or made from said nano-particles and compositions, including anti-reflective coatings and composite materials.

Embodiments of durable, anti-reflective articles are described. In one or more embodiments, the article includes a substrate and an anti-reflective coating disposed on the major surface. The article exhibits an average light transmittance of about 94% or greater over an optical wavelength regime and/or an average light reflectance of about 2% or less over the optical wavelength regime, as measured from an anti-reflective surface. In some embodiments, the article exhibits a maximum hardness of about 8 GPa or greater as measured by a Berkovich Indenter Hardness Test along an indentation depth of about 50 nm or greater and a b* value, in reflectance, in the range from about −5 to about 1 as measured on the anti-reflective surface only at all incidence illumination angles in the range from about 0 degrees to about 60 degrees under an International Commission on Illumination illuminant.

According to one or more embodiments described herein, a coated article may comprise a transparent substrate and an optical coating. The transparent substrate may have a major surface, and the optical coating may be disposed on the major surface of the transparent substrate and form an air-side surface. The optical coating may comprise one or more layers of deposited material and one or more light-altering features which may reduce oscillations in the reflectance spectrum of the coated article. The coated article may exhibit a maximum hardness of about 8 GPa or greater, have an average photopic transmittance of about 50% or greater, and exhibit an angular color shift of less than about 10 from a reference illumination angle in a range of 0-10 degrees to an incident illumination angle in a range of 30-60 degrees relative to the air-side surface.

Described herein is an article having a microsphere layer comprising a monolayer of microspheres, the monolayer of microspheres comprising a first area substantially free of microspheres and a second area comprising a plurality of randomly-distributed microspheres, wherein the monolayer of microspheres comprises a predetermined pattern, the predetermined pattern comprises at least one of (i) a plurality of the first areas, (ii) a plurality of the second areas, and (iii) combinations thereof; and (b) a bead bonding layer disposed on the microsphere layer, wherein the plurality of microspheres are partially embedded in a first major surface of the bead bonding layer, wherein the article has a retroreflectivity (R.sub.a) of less than 5.0 candelas/lux/square meter. Also disclosed herein are transfer carriers and methods of making the articles and transfer carriers.

An aqueous functional composition formulation is used to provide a functional composition in foamed, opacifying elements useful as a light-blocking articles. The aqueous functional composition formulation comprises: (i) glass particles such as hollow glass particles at a coverage of 0.1-2.2 g/cm.sup.2 and a (iv) water-soluble or water-dispersible organic polymeric binder that may be crosslinked. Thickeners, coating aids having an HLB of at least 5, (ii) lubricants, (iii) tinting materials, and (v) crosslinking agents can also be present in the aqueous functional composition formulation. Among other properties, the presence of the glass particles provides heat absorption capacity for the foamed, opacifying elements.