The present invention provides antifouling coating compositions having excellent long-term storage stability and provides an antifouling coating composition that can maintain the stable dissolution and antifouling performance of a coating film without causing coating film defects such as cracks in seawater for a long term, such that an antifouling coating film having increased environmental safety can be formed. The present invention provides an antifouling coating composition containing: (A) a triorganosilyl ester-containing copolymer obtained from a mixture of (a) a triorganosilyl (meth)acrylate monomer represented by general formula (1):

##STR00001##

(here, R.sup.1 is a hydrogen atom or a methyl group; and R.sup.2, R.sup.3, and R.sup.4 are the same or different from each other and each represents a C.sub.3-6 alkyl group branched at the α-position or a phenyl group) and (b) an ethylenically unsaturated monomer copolymerizable with the triorganosilyl (meth)acrylate monomer; and (B) calcium sulfate hydrate.

The present invention provides antifouling coating compositions having excellent long-term storage stability and provides an antifouling coating composition that can maintain the stable dissolution and antifouling performance of a coating film without causing coating film defects such as cracks in seawater for a long term, such that an antifouling coating film having increased environmental safety can be formed. The present invention provides an antifouling coating composition containing: (A) a triorganosilyl ester-containing copolymer obtained from a mixture of (a) a triorganosilyl (meth)acrylate monomer represented by general formula (1):

##STR00001##

(here, R.sup.1 is a hydrogen atom or a methyl group; and R.sup.2, R.sup.3, and R.sup.4 are the same or different from each other and each represents a C.sub.3-6 alkyl group branched at the α-position or a phenyl group) and (b) an ethylenically unsaturated monomer copolymerizable with the triorganosilyl (meth)acrylate monomer; and (B) calcium sulfate hydrate.

Biologically activated ion-exchange polymer salts are made by exchanging biologically active ionic agents onto ion-exchange polymers. The activated polymers are uniquely surface active and stable to thermal degradation and chemical and other forms of decomposition. The activated ion-exchange polymer salts may be processed and combined with polymer precursors using novel methods and materials to produce stable, biologically activated polymer composites, including antimicrobial and antifouling polymer composites.

Methods of protecting a surface include applying an inner polymer layer onto a surface. The inner polymer layer is impregnated with a biologically active chemical substance that protects the surface from biofouling-induced chemical, biological, and bio-proliferative damage. The inner polymer layer is an epoxy polymer. An outer polymer layer is applied onto the inner polymer layer. The outer polymer layer is impregnated with a biologically active chemical substance that protects the inner polymer layer from biofouling-induced chemical, biological, and bio-proliferative damage. The outer polymer layer is selected from the group consisting of polyurethanes and fluorourethanes.

A surface of a marine object is treated with an antifouling paint. The antifouling paint comprises a porous silicate and a wax. The porous silicate has a particle size of between 1 and 100 μm and is in a concentration of between 18 and 60 weight percent. The antifouling paint is applied to the surface. The wax is used to encapsulate the porous silicate and to prevent an immediate release of ions from the porous silicate.

A surface of a marine object is treated with an antifouling paint. The antifouling paint comprises a porous silicate and a wax. The porous silicate has a particle size of between 1 and 100 μm and is in a concentration of between 18 and 60 weight percent. The antifouling paint is applied to the surface. The wax is used to encapsulate the porous silicate and to prevent an immediate release of ions from the porous silicate.

A method of forming a metasurface includes forming a plurality of channels on a surface of a formed from a first material, like a metal, ceramic, or polymer. The method also includes filling the plurality of channels in the surface of the base substrate with a second material that is different from the first material to form a metasurface on the base substrate. The method further includes placing the metasurface into a heat exchange system such that the metasurface is proximate to a liquid used in the heat exchange system.

An anti-fouling (anti-pollution) coating material and a method of manufacturing a coating film are provided herein. The anti-fouling coating material has characteristics such as, but not limited to, an anti-fouling property, water repellency, oil repellency, and improved adhesion to a base material such as a lens. The anti-fouling coating material includes (a) a base material, (b) a low-reflectivity coating layer having a multilayer structure in which a silicon dioxide (SiO.sub.2)-containing layer and a titanium dioxide (TiO.sub.2)-containing layer are alternately stacked, (c) an anti-fouling coating layer that is formed on the low-reflectivity coating layer and includes an organic/inorganic composite material in which a silicon compound and a fluorine compound are linked to each other, and (d) an adhesion improving layer interposed between the base material and the low-reflectivity coating layer. The anti-fouling coating material is not readily detached to the surface of the base material such as a lens due to its superior adhesivity. Thus, the anti-fouling coating material can stably exert water repellency and oil repellency for a long time.

An object of the present invention is to provide an antifouling coating composition capable of forming an antifouling coating film that retains a high antifouling performance for a prolonged period of time and has an excellent damage resistance. Another object of the present invention is to provide an antifouling coating film formed with the antifouling coating composition, a substrate with an antifouling coating film and a method for producing the same, and an antifouling method using the antifouling coating film. The antifouling coating composition of the present invention contains a hydrolyzable polymer (A) containing a metal ester group, zinc oxide (B), and medetomidine (C), and has a content of the zinc oxide (B) in a solid content of the antifouling composition of 27 to 60% by mass.

A graft copolymer includes an oxazoline-based derivative grafted onto a polymer including a structural unit. A composition may include the copolymer, and an article may be manufactured from the composition.