The present invention relates to a photoinduced thermochromic or thermoluminescent composition, comprising: a) nanoparticles capable of absorbing near-infrared (NIR) radiation and converting the NIR radiation into heat, in particular metal gold nanoparticles; b) one or more phase change materials (PCM) selected from the group consisting of: b1) a PCM capable of acting as chromic or fluorochromic promoter; and b2) a PCM uncapable of acting as chromic or fluorochromic promoter; c) one or more dyes selected from the group consisting of: c1) a dye capable of modifying its colour- or emission-properties when the PCM changes between the solid state and the liquid state; and c2) a dye uncapable of modifying its colour- or emission-properties when the PCM between the solid state and the liquid state; and articles containing it. It also relates to processes for their preparation and their uses in therapy, cosmetics, diagnostics, optics and anti-fake technology.

A material composition may include one or more polymeric materials. The material composition may also include one or more inorganic particles comprising oxides, carbonates, sulfides, or any combination thereof. Further, the material composition may include one or more metal particles that produce a detectable change in an electrical property or an optical property based on a reaction with at least one of H2O, CO2, or H2S. The one or more inorganic particles and the one or more metal particles may be dispersed within the one or more polymeric materials.

A material composition may include one or more polymeric materials. The material composition may also include one or more inorganic particles comprising oxides, carbonates, sulfides, or any combination thereof. Further, the material composition may include one or more metal particles that produce a detectable change in an electrical property or an optical property based on a reaction with at least one of H2O, CO2, or H2S. The one or more inorganic particles and the one or more metal particles may be dispersed within the one or more polymeric materials.

A photoluminescent coating material which contains: a hydrocarbon-based solvent (A) that has an aniline point of 40° C. or higher; a resin (B1) that is incompatible with the hydrocarbon-based solvent (A); a solvent (C) that is compatible with the hydrocarbon-based solvent (A) and the resin (B1) while having a lower boiling point than the hydrocarbon-based solvent (A); and a scale-like aluminum (D).

A photoluminescent coating material which contains: a hydrocarbon-based solvent (A) that has an aniline point of 40° C. or higher; a resin (B1) that is incompatible with the hydrocarbon-based solvent (A); a solvent (C) that is compatible with the hydrocarbon-based solvent (A) and the resin (B1) while having a lower boiling point than the hydrocarbon-based solvent (A); and a scale-like aluminum (D).

The present invention provides a glitter pigment suitable for imparting high brightness to reflected light toward a regular reflection direction and reducing unnaturalness caused by an observation angle-dependent variation in reflected light. The glitter pigment according to the present invention includes: a flaky substrate; an optical interference film formed on a surface of the flaky substrate; and fine light scattering particles attached to the optical interference film, wherein reflected light is represented by an L*(15) value of more than 100, a ΔL*(h−s) value of less than 30, and a Δh(h−s) value of less than 40° in an L*C*h color system. The L*(15) value is an L* value of the reflected light toward a 15° direction based on an angular representation in which, when an illuminant is disposed so that an incident angle is 45°, an angle at which light is regularly reflected is defined as 0° and a light incident direction is defined as positive. The ΔL*(h−s) value is a difference in L* between a highlight and shade, and the Δh(h−s) value is a difference in h between a highlight and shade. The Δh value expressed in angle is an angular difference. The highlight is an average of values measured at 15° and 25°, and the shade is an average of values measured at 75° and 110°.

The present invention provides a glitter pigment suitable for imparting high brightness to reflected light toward a regular reflection direction and reducing unnaturalness caused by an observation angle-dependent variation in reflected light. The glitter pigment according to the present invention includes: a flaky substrate; an optical interference film formed on a surface of the flaky substrate; and fine light scattering particles attached to the optical interference film, wherein reflected light is represented by an L*(15) value of more than 100, a ΔL*(h−s) value of less than 30, and a Δh(h−s) value of less than 40° in an L*C*h color system. The L*(15) value is an L* value of the reflected light toward a 15° direction based on an angular representation in which, when an illuminant is disposed so that an incident angle is 45°, an angle at which light is regularly reflected is defined as 0° and a light incident direction is defined as positive. The ΔL*(h−s) value is a difference in L* between a highlight and shade, and the Δh(h−s) value is a difference in h between a highlight and shade. The Δh value expressed in angle is an angular difference. The highlight is an average of values measured at 15° and 25°, and the shade is an average of values measured at 75° and 110°.

Provided is a curable photochromic coating composition including (a) a polyol component, (b) a poly(anhydride) having at least three cyclic anhydride groups, (c) a secondary crosslinker, and (d) a photochromic material. The polyol component includes (i) a first polyol having two hydroxyl groups and a hydroxyl equivalent weight of at least 15,000 g/mol and (ii) a second polyol different from the first polyol having at least three hydroxyl groups and a hydroxyl equivalent weight of at least 300 g/mol. The secondary crosslinker is selected from a poly(carbodiimide), an oxazoline-functional material, or mixtures thereof. The present invention also provides an optical article prepared from the curable photochromic coating composition.

Provided is a curable photochromic coating composition including (a) a polyol component, (b) a poly(anhydride) having at least three cyclic anhydride groups, (c) a secondary crosslinker, and (d) a photochromic material. The polyol component includes (i) a first polyol having two hydroxyl groups and a hydroxyl equivalent weight of at least 15,000 g/mol and (ii) a second polyol different from the first polyol having at least three hydroxyl groups and a hydroxyl equivalent weight of at least 300 g/mol. The secondary crosslinker is selected from a poly(carbodiimide), an oxazoline-functional material, or mixtures thereof. The present invention also provides an optical article prepared from the curable photochromic coating composition.

Methods of producing colored and superhydrophobic surfaces, objects, and coatings using a colored paint that imparts a superhydrophobic surface on an object is a suspension of hydrophobic particles in a polymeric binder and a plasticizer in a solvent or mixed solvent, wherein at least a portion of the hydrophobic particles are colored particles. Colored particles can be ultramarine, iron oxide, chromium oxide, or any other colored metal oxide. The hydrophobic particles can be metal oxide particles that are surface functionalized with a fluorinated alkyl silane or an alkyl silane. The binder is a mixture of PDVF and PMMA in a ratio of 3:1 to 10:1. The plasticizer is a mixture of triethyl phosphate and perfluoro(butyltetrahydrofuran) or other perfluorinated hydrocarbon. Surfaces coated using this paint display contact angles in excess of 150° and resist abrasion.