A method for the formation of tantalum carbides on a graphite substrate includes the steps of: (a) adding an organic tantalum compound, a chelating agent, a pre-polymer to an organic solvent to form a tantalum polymeric solution; (b) subjecting a graphite substrate with the tantalum polymeric solution to a curing process to form a polymeric tantalum film on the graphite substrate; and (c) subjecting the polymeric tantalum film on the graphite substrate in an oven to a pyrolytic reaction in the presence of a protective gas to obtain a protective tantalum carbide on the graphite substrate.

There is disclosed a print construction comprising: (a) a printing substrate having an image-receiving surface; (b) a receptive layer, at least partially covering said image-receiving surface, and having a particle reception surface distally disposed to said image-receiving surface, said receptive layer optionally having a thickness of at least 1000 nanometer (nm); and (c) a plurality of individual particles adhered to said particle reception surface, and forming a monolayer thereon, the features of which are described herein.

There is disclosed a print construction comprising: (a) a printing substrate having an image-receiving surface; (b) a receptive layer, at least partially covering said image-receiving surface, and having a particle reception surface distally disposed to said image-receiving surface, said receptive layer optionally having a thickness of at least 1000 nanometer (nm); and (c) a plurality of individual particles adhered to said particle reception surface, and forming a monolayer thereon, the features of which are described herein.

A method for increasing a detection distance of a surface of an object illuminated by near-IR electromagnetic radiation, including: (a) directing near-IR electromagnetic radiation from a near-IR electromagnetic radiation source towards an object at least partially coated with a near-IR reflective coating that increases a near-IR electromagnetic radiation detection distance by at least 15% as measured at a wavelength in a near-IR range as compared to the same object coated with a color matched coating which absorbs more of the same near-IR radiation, where the color matched coating has a ΔE color matched value of 1.5 or less when compared to the near-IR reflective coating; and (b) detecting reflected near-IR electromagnetic radiation reflected from the near-IR reflective coating. A system for detecting proximity of vehicles is also disclosed.

A method for increasing a detection distance of a surface of an object illuminated by near-IR electromagnetic radiation, including: (a) directing near-IR electromagnetic radiation from a near-IR electromagnetic radiation source towards an object at least partially coated with a near-IR reflective coating that increases a near-IR electromagnetic radiation detection distance by at least 15% as measured at a wavelength in a near-IR range as compared to the same object coated with a color matched coating which absorbs more of the same near-IR radiation, where the color matched coating has a ΔE color matched value of 1.5 or less when compared to the near-IR reflective coating; and (b) detecting reflected near-IR electromagnetic radiation reflected from the near-IR reflective coating. A system for detecting proximity of vehicles is also disclosed.

There is disclosed a method of printing onto the surface of a substrate, which method comprises i) coating a donor surface (12) with a monolayer of particles, ii) treating the substrate surface (80) to render at least selected regions tacky, and iii) contacting the substrate surface with the donor surface to cause particles to transfer from the donor surface only to the tacky regions of the substrate surface. After printing on a substrate (20), the donor surface (12) returns to the coating station (14) where the continuity of the monolayer is restored by recovering with fresh particles the regions of the donor surface exposed by the transfer of particles to the substrate.

There is disclosed a method of printing onto the surface of a substrate, which method comprises i) coating a donor surface (12) with a monolayer of particles, ii) treating the substrate surface (80) to render at least selected regions tacky, and iii) contacting the substrate surface with the donor surface to cause particles to transfer from the donor surface only to the tacky regions of the substrate surface. After printing on a substrate (20), the donor surface (12) returns to the coating station (14) where the continuity of the monolayer is restored by recovering with fresh particles the regions of the donor surface exposed by the transfer of particles to the substrate.

An apparatus for coating a donor surface that is movable relative to the apparatus with a layer of thermoplastic particles, the particles adhering more strongly to the surface than to one another. The apparatus comprises an application device to apply to the donor surface a fluid stream within which the particles are suspended, a housing surrounds the application device forming an interior plenum for confining the fluid stream, the housing prevents egress of particles from a sealing gap defined between the rim of the housing and the surface to be coated, and a suction source connected to the housing to extract from the plenum excess fluid and particles. In operation, the suction source extracts substantially all particles that are not in direct contact with the donor surface, leaving substantially a single particle layer adhering to the donor surface upon exiting the apparatus.

An apparatus for coating a donor surface that is movable relative to the apparatus with a layer of thermoplastic particles, the particles adhering more strongly to the surface than to one another. The apparatus comprises an application device to apply to the donor surface a fluid stream within which the particles are suspended, a housing surrounds the application device forming an interior plenum for confining the fluid stream, the housing prevents egress of particles from a sealing gap defined between the rim of the housing and the surface to be coated, and a suction source connected to the housing to extract from the plenum excess fluid and particles. In operation, the suction source extracts substantially all particles that are not in direct contact with the donor surface, leaving substantially a single particle layer adhering to the donor surface upon exiting the apparatus.

A laminate containing a metallic base layer and a transparent colored layer formed on the metallic base layer, wherein, when

X=[(C*45).sup.2+(C*75).sup.2)].sup.1/2, and

Y=[(L*15).sup.2+(C*15).sup.2)].sup.1/2+[(L*25).sup.2+(C*25).sup.2)].sup.1/2,

X is 64 or more, and Y is 191 or more; and the measured value of graininess (HG value) is 45 or less,
with the proviso that C*15, C*25, C*45, and C*75 represent chroma calculated from spectral reflectances of light illuminated at an incident angle of 45 degrees with respect to the laminate and received at respective angles of 15 degrees, 25 degrees, 45 degrees, and 75 degrees deviated from the specular reflection light, and that L*15 and L*25 represent lightness calculated from spectral reflectances of light illuminated at an incident angle of 45 degrees with respect to the laminate and received at respective angles of 15 degrees and 25 degrees deviated from the specular reflection light.