The present invention relates to a method of preparing an oxidatively curable coating formulation made from an oxidatively curable alkyd-based resin, a complex comprising one or more manganese ions and one or more triazacyclononane-based ligands; and to the use of triazacyclononane-based ligands for accelerating the rate of curing of an alkyd-based resin formulation by such complexes. The formulations may be paints or other oxidatively curable coating compositions.

A water-based coating composition including: a polyol; a polyisocyanate; a hydrophobic curing catalyst which is made of an organometallic compound containing at least one metal atom selected from the group consisting of Sn, Bi, Zr, Ti, and Al and of which solubility in water under conditions of atmospheric pressure at 20° C. is 1 g/100 ml or less; and a nonionic surfactant of which an HLB value determined by a Griffin method is 10 to 15.

A water-based coating composition including: a polyol; a polyisocyanate; a hydrophobic curing catalyst which is made of an organometallic compound containing at least one metal atom selected from the group consisting of Sn, Bi, Zr, Ti, and Al and of which solubility in water under conditions of atmospheric pressure at 20° C. is 1 g/100 ml or less; and a nonionic surfactant of which an HLB value determined by a Griffin method is 10 to 15.

Described herein is method of functionalizing fluorinated polymers, wherein a reaction compound is grafted onto a fluorinated polymer, wherein the fluorinated polymer comprises at least one Br, I, and Cl group and is free of —CH.sub.2CH.sub.2— linkages. In one embodiment, the functionalized fluorinated polymer comprises a perfluorinated polymer backbone with pendent groups therefrom is disclosed, wherein at least one pendent group is according to formula I: where Rf is a bond, or a divalent perfluorinated group, optionally comprising at least one in-chain ether linkage; Z is I, Br, or Cl; and X comprises a functional group selected from the group consisting of an alcohol; phosphorous acid and salts thereof; phosphoric acid and salts thereof; a silane; an amine; an amide; a hydrocarbon, optionally comprising an in-chain oxygen, nitrogen, or sulfur linkage; a carboxylic acid and salts thereof; an ester; a sulfonyl fluoride, a sulfonic acid and salts thereof; and combinations thereof. Such functionalized fluorinated polymers may be used in coating compositions.

##STR00001##

Described herein is method of functionalizing fluorinated polymers, wherein a reaction compound is grafted onto a fluorinated polymer, wherein the fluorinated polymer comprises at least one Br, I, and Cl group and is free of —CH.sub.2CH.sub.2— linkages. In one embodiment, the functionalized fluorinated polymer comprises a perfluorinated polymer backbone with pendent groups therefrom is disclosed, wherein at least one pendent group is according to formula I: where Rf is a bond, or a divalent perfluorinated group, optionally comprising at least one in-chain ether linkage; Z is I, Br, or Cl; and X comprises a functional group selected from the group consisting of an alcohol; phosphorous acid and salts thereof; phosphoric acid and salts thereof; a silane; an amine; an amide; a hydrocarbon, optionally comprising an in-chain oxygen, nitrogen, or sulfur linkage; a carboxylic acid and salts thereof; an ester; a sulfonyl fluoride, a sulfonic acid and salts thereof; and combinations thereof. Such functionalized fluorinated polymers may be used in coating compositions.

##STR00001##

Provided is a water-soluble sheet-like coloring material in which sheets are less likely to stick to each other, have appropriate self-standing property and flexibility, and can be quickly brought into a uniform state when dissolved in water.

A water-soluble sheet-like coloring material including a film-forming water-soluble polymer; a dissolution accelerator; a colorant; and a moisture-retaining agent.

Provided is a water-soluble sheet-like coloring material in which sheets are less likely to stick to each other, have appropriate self-standing property and flexibility, and can be quickly brought into a uniform state when dissolved in water.

A water-soluble sheet-like coloring material including a film-forming water-soluble polymer; a dissolution accelerator; a colorant; and a moisture-retaining agent.

The present invention provides a coalescing agent for aqueous coatings, a coalescing agent composition, and an aqueous coating. The coalescing agent for aqueous coatings is obtained by esterification reaction of fatty acids and glycol ethers. The coalescing agent prepared by the present invention has a boiling point as high as 330° C., has no irritant odor, and is environmental friendly and safe. It overcomes shortcomings of conventional coalescing agents, which is suitable for various polymer emulsion systems, and can significantly reduce the film-forming temperature of aqueous emulsion coatings and optimize the film-forming performance.

The present invention provides a coalescing agent for aqueous coatings, a coalescing agent composition, and an aqueous coating. The coalescing agent for aqueous coatings is obtained by esterification reaction of fatty acids and glycol ethers. The coalescing agent prepared by the present invention has a boiling point as high as 330° C., has no irritant odor, and is environmental friendly and safe. It overcomes shortcomings of conventional coalescing agents, which is suitable for various polymer emulsion systems, and can significantly reduce the film-forming temperature of aqueous emulsion coatings and optimize the film-forming performance.

A heat exchanger includes a metal base defining a heat exchange channel for flowing at least one of a refrigerant and a coolant therein, and a coating layer coated at least a part of an outer surface of the metal base. The coating layer includes sol particles and an antibacterial material, where the sol particles include silica. The antibacterial material includes a rare earth element oxide. By combining the antibacterial agent containing the rare earth element oxide with sol, the advantages of each component can be fully utilized. On the one hand, it is easier to attach the antibacterial material via the sol, and on the other hand a surface of the metal base of the heat exchanger can have a good antibacterial and mold-inhibiting effects, which is beneficial to cost reduction.