Embodiments of the invention relate to an apparatus, method and article of manufacturing for producing an edible multi-color ink image. In some embodiments, first and second fluids are provided where: i. the first fluid is an acidic edible and aqueous ink whose color is pH sensitive, the first fluid comprising anthocyanin-containing extract of anthocyanin-containing plant matter (ACE-ACPM), or solids of the ACE-ACPM; ii. the second fluid is an edible pH-adjusting liquid which is clear, or whose primary colorant is riboflavin or riboflavin-phosphate.

Embodiments of the invention relate to an apparatus, method and article of manufacturing for producing an edible multi-color ink image. In some embodiments, first and second fluids are provided where: i. the first fluid is an acidic edible and aqueous ink whose color is pH sensitive, the first fluid comprising anthocyanin-containing extract of anthocyanin-containing plant matter (ACE-ACPM), or solids of the ACE-ACPM; ii. the second fluid is an edible pH-adjusting liquid which is clear, or whose primary colorant is riboflavin or riboflavin-phosphate.

A method of printing a stealth white image includes applying a stealth ink containing a red coloring material that emits visible light at exposure to ultraviolet radiation and a green coloring material that emits visible light at exposure to ultraviolet radiation to a substrate which contains a fluorescent brightener to form the stealth white image thereon, wherein the stealth white image demonstrates an a* value of from −2.0 to 2.0 and a b* value of from −10.0 to 0 at exposure to ultraviolet radiation having a wavelength of 370 nm according to CIE 1976 L*a*b* colorimetric system.

A method of printing a stealth white image includes applying a stealth ink containing a red coloring material that emits visible light at exposure to ultraviolet radiation and a green coloring material that emits visible light at exposure to ultraviolet radiation to a substrate which contains a fluorescent brightener to form the stealth white image thereon, wherein the stealth white image demonstrates an a* value of from −2.0 to 2.0 and a b* value of from −10.0 to 0 at exposure to ultraviolet radiation having a wavelength of 370 nm according to CIE 1976 L*a*b* colorimetric system.

A method of fabricating a three-dimensional (3D) object includes atomizing a pre-polymer composition into an aerosol jet stream. The pre-polymer composition includes an epoxy precursor and a photoacid generator. The method further includes depositing the aerosol jet stream onto a substrate to form a first layer of dielectric ink and curing the first layer of dielectric ink using ultraviolet (UV) light. The method further includes depositing the aerosol jet stream onto the first layer of dielectric ink to form a second layer of dielectric ink. The first layer of dielectric ink and the second layer of dielectric ink overlap by at least 50%.

A method of fabricating a three-dimensional (3D) object includes atomizing a pre-polymer composition into an aerosol jet stream. The pre-polymer composition includes an epoxy precursor and a photoacid generator. The method further includes depositing the aerosol jet stream onto a substrate to form a first layer of dielectric ink and curing the first layer of dielectric ink using ultraviolet (UV) light. The method further includes depositing the aerosol jet stream onto the first layer of dielectric ink to form a second layer of dielectric ink. The first layer of dielectric ink and the second layer of dielectric ink overlap by at least 50%.

The present invention provides a reversibly thermochromic aqueous inkjet printer ink composition which can form print images of high resolution and rich color development. The composition comprises: a reversibly thermochromic microcapsule pigment, water, and a polyalcohol organic solvent. Microcapsules which are comprised in the composition have a volume-based mean particle size (X) of 0.1 to 2 μm and a mean cross-sectional membrane thickness (Y) of 0.02 to 0.4 which is average of cross-sectional membrane thickness defined by the formula:

cross-sectional membrane thickness=(outer section diameter−inner section diameter)/2.

The present invention provides a reversibly thermochromic aqueous inkjet printer ink composition which can form print images of high resolution and rich color development. The composition comprises: a reversibly thermochromic microcapsule pigment, water, and a polyalcohol organic solvent. Microcapsules which are comprised in the composition have a volume-based mean particle size (X) of 0.1 to 2 μm and a mean cross-sectional membrane thickness (Y) of 0.02 to 0.4 which is average of cross-sectional membrane thickness defined by the formula:

cross-sectional membrane thickness=(outer section diameter−inner section diameter)/2.

A method for preparing three-dimensional perovskite nanopixels of a digital display is provided. The method includes steps of preparing precursor ink by mixing methylammonium halide and lead halide and adding them into another mixture, adding the precursor ink into a nanopipette, placing the nanopipette with the precursor ink above a silicon substrate and apart from the silicon substrate by a certain distance, configuring the nanopipette to come into contact with the Si substrate such that a portion of the precursor ink having an interface surface of a shape of a meniscus is formed between the nanopipette and the silicon substrate, performing rapid evaporation of the portion of the precursor ink to facilitate crystallization of perovskite, moving the nanopipette upwardly at a constant speed such that the crystallization of perovskite proceeds upwardly, and terminating the crystallization of perovskite to generate a freestanding nanopixel for emitting light.

A method for preparing three-dimensional perovskite nanopixels of a digital display is provided. The method includes steps of preparing precursor ink by mixing methylammonium halide and lead halide and adding them into another mixture, adding the precursor ink into a nanopipette, placing the nanopipette with the precursor ink above a silicon substrate and apart from the silicon substrate by a certain distance, configuring the nanopipette to come into contact with the Si substrate such that a portion of the precursor ink having an interface surface of a shape of a meniscus is formed between the nanopipette and the silicon substrate, performing rapid evaporation of the portion of the precursor ink to facilitate crystallization of perovskite, moving the nanopipette upwardly at a constant speed such that the crystallization of perovskite proceeds upwardly, and terminating the crystallization of perovskite to generate a freestanding nanopixel for emitting light.