The aqueous ink for ink jet contains a resin particle dyed with a fluorescent dye, and a water-soluble resin. The fluorescent dye contains a fluorescence-emitting dye selected from the group consisting of basic dye, disperse dye and oil-soluble dye, the resin particle has a core portion that contains an aromatic group-containing unit and cyano group-containing unit, and a shell portion that contains an aromatic group-containing unit, an anionic group-containing unit and a crosslinking agent-derived unit, but free of cyano group-containing unit, percentage (% by mass) of the crosslinking agent-derived unit in the shell portion is 30% by mass or more to 80% by mass or less, the water-soluble resin having an aromatic group-containing unit and an anionic group-containing unit, and the water-soluble resin having an acid value of 100 mgKOH/g or more to 180 mgKOH/g or less.

The aqueous ink for ink jet contains a resin particle dyed with a fluorescent dye, and a water-soluble resin. The fluorescent dye contains a fluorescence-emitting dye selected from the group consisting of basic dye, disperse dye and oil-soluble dye, the resin particle has a core portion that contains an aromatic group-containing unit and cyano group-containing unit, and a shell portion that contains an aromatic group-containing unit, an anionic group-containing unit and a crosslinking agent-derived unit, but free of cyano group-containing unit, percentage (% by mass) of the crosslinking agent-derived unit in the shell portion is 30% by mass or more to 80% by mass or less, the water-soluble resin having an aromatic group-containing unit and an anionic group-containing unit, and the water-soluble resin having an acid value of 100 mgKOH/g or more to 180 mgKOH/g or less.

A printed object includes a substrate and a first information code disposed on the substrate, wherein: the first information code is constituted of an infrared ray-absorptive ink layer that has been printed with an infrared ray absorptive ink; and the infrared ray absorptive ink layer is configured such that, when a laminated body constituted of a test substrate made of the same material as that of the substrate, and a test infrared absorptive ink layer made of the same material as that of the infrared ray absorptive ink layer and disposed on the test substrate is subjected to a relative spectral reflectivity measurement on the test infrared ray absorptive ink layer side, with the test substrate as the reference (100% reflectivity), the minimum relative reflectivity in the visible region is 50% or higher, and the minimum relative reflectivity in the infrared region is 75% or lower.

The present invention relates to semiconducting nanoparticle.

The present invention relates to semiconducting nanoparticle.

Novel reaction media for electron donating and electron accepting components in colour-change compositions are described. The compound is of formula (VI); R.sub.1, and R.sub.2 are independently selected from an optionally substituted linear or branched alkyl group, alkenyl group, alkoxy group, aryl group and an alkylene aryl group having from 5 to 22 carbon atoms; X.sub.1 and X.sub.2 are independently selected from —OC(O)—, —CO.sub.2— and O; Y.sub.1, and Y.sub.2 are independently selected from hydrogen, halogen, R.sub.1, —OR.sub.1; y is independently 0 or 1; and suitably the groups R.sub.1X.sub.1— and —X.sub.2R.sub.2 are independently in the ortho or meta position. The compounds are useful in ink compositions, writing implements containing the compound and medical and industrial applications in which temperature sensitive colour change may be required. ##STR00001##

Novel reaction media for electron donating and electron accepting components in colour-change compositions are described. The compound is of formula (VI); R.sub.1, and R.sub.2 are independently selected from an optionally substituted linear or branched alkyl group, alkenyl group, alkoxy group, aryl group and an alkylene aryl group having from 5 to 22 carbon atoms; X.sub.1 and X.sub.2 are independently selected from —OC(O)—, —CO.sub.2— and O; Y.sub.1, and Y.sub.2 are independently selected from hydrogen, halogen, R.sub.1, —OR.sub.1; y is independently 0 or 1; and suitably the groups R.sub.1X.sub.1— and —X.sub.2R.sub.2 are independently in the ortho or meta position. The compounds are useful in ink compositions, writing implements containing the compound and medical and industrial applications in which temperature sensitive colour change may be required. ##STR00001##

The method is an ink jet recording method, which uses an ink set being composed of a plurality of aqueous inks and including a combination of a first ink containing a coloring material and a second ink containing no coloring material and by which an image is recorded by applying the first ink and the second ink onto a recording medium so that an area to which the first ink is applied and an area to which the second ink is applied overlap at least in part with each other. The coloring material of the first ink contains fluorescent dye, the second ink contains a first water-soluble organic solvent, and an SP value S.sub.S of the first water-soluble organic solvent and an SP value S.sub.D of the fluorescent dye satisfy a relationship of the following formula (1):
|S.sub.S−S.sub.D|≤4.0  (1).

The present invention relates to a new crystal form of the compound of formula and a process for its preparation. The compound may be used in compositions for inks, paints and plastics, especially in a wide variety of printing systems and is particularly well-suited for security applications.

##STR00001##

The present invention relates to a new crystal form of the compound of formula and a process for its preparation. The compound may be used in compositions for inks, paints and plastics, especially in a wide variety of printing systems and is particularly well-suited for security applications.

##STR00001##