The pretreatment liquid of the present invention is applicable for a fabric to be used for inkjet textile printing, and the pretreatment liquid contains a block copolymer including a hydrophobic block derived from a hydrophobic resin having an SP value of less than 11 and a hydrophilic block derived from a hydrophilic resin having an SP value of 11 or more, with the difference between the SP values of the hydrophobic resin and the hydrophilic resin of 1.0 or more; and water.

An example of a multi-fluid kit includes a pretreatment fluid, a fixer fluid, and a white inkjet ink. The pretreatment fluid includes anionically modified cellulose nanocrystals and a first aqueous vehicle. In some examples, the fixer fluid includes an azetidinium-containing polyamine and a second aqueous vehicle. The multi-fluid kit is suitable for use in inkjet textile printing.

An example of a multi-fluid kit includes a pretreatment fluid, a fixer fluid, and a white inkjet ink. The pretreatment fluid includes anionically modified cellulose nanocrystals and a first aqueous vehicle. In some examples, the fixer fluid includes an azetidinium-containing polyamine and a second aqueous vehicle. The multi-fluid kit is suitable for use in inkjet textile printing.

An ink set includes a reaction liquid containing coagulant; a first ink containing a color material; and a second ink containing a color material. The ink set is used for recording on a non-absorptive recording medium or a low-absorptive recording medium and for imparting the reaction liquid, the first ink, and the second ink to the recording medium in a superimposed manner in this order.

An ink set includes a reaction liquid containing coagulant; a first ink containing a color material; and a second ink containing a color material. The ink set is used for recording on a non-absorptive recording medium or a low-absorptive recording medium and for imparting the reaction liquid, the first ink, and the second ink to the recording medium in a superimposed manner in this order.

A radiation curable polyurethane resin includes an ionic group, a polyalkylene oxide in a side chain thereof, and a (meth)acrylate or (meth)acrylamide having a hydroxyl functional group. The polyurethane resin is obtainable by reacting a polyester polyol, a polyether diol, a polyol containing an ionic group, a (meth)acrylate or (meth)acrylamide having a hydroxyl functional group, and a polyisocyanate. The polyester polyol is obtained by reacting a polycarboxylic acid and a polyol. The radiation curable polyurethane resin can be used as binder in an aqueous ink jet ink.

A radiation curable polyurethane resin includes an ionic group, a polyalkylene oxide in a side chain thereof, and a (meth)acrylate or (meth)acrylamide having a hydroxyl functional group. The polyurethane resin is obtainable by reacting a polyester polyol, a polyether diol, a polyol containing an ionic group, a (meth)acrylate or (meth)acrylamide having a hydroxyl functional group, and a polyisocyanate. The polyester polyol is obtained by reacting a polycarboxylic acid and a polyol. The radiation curable polyurethane resin can be used as binder in an aqueous ink jet ink.

An ink set contains a white ink composition containing a white coloring material and a resin, and a non-white ink composition containing a non-white coloring material and a resin. The white ink composition and the non-white ink composition are used with a treatment liquid containing a coagulant for coagulating a component of the non-white ink composition. When a 5% by mass calcium acetate monohydrate aqueous solution and each of the ink compositions are mixed, a ratio of the viscosity increase after the mixing to the viscosity increase before the mixing is lower in the white ink composition than in the non-white ink composition.

An ink set contains a white ink composition containing a white coloring material and a resin, and a non-white ink composition containing a non-white coloring material and a resin. The white ink composition and the non-white ink composition are used with a treatment liquid containing a coagulant for coagulating a component of the non-white ink composition. When a 5% by mass calcium acetate monohydrate aqueous solution and each of the ink compositions are mixed, a ratio of the viscosity increase after the mixing to the viscosity increase before the mixing is lower in the white ink composition than in the non-white ink composition.

An ink set including an inkjet ink, and a treatment liquid used in combination with the inkjet ink, wherein the inkjet ink includes a pigment, a water-soluble organic solvent, a surfactant and water, the treatment liquid includes a coagulant, an organic solvent and water, the coagulant includes calcium nitrate in an amount of 21.5 to 41.7% by mass relative to the total mass of the treatment liquid, an amount of organic solvent having a boiling point at one atmosphere of 240° C. or higher in the treatment liquid is not more than 8% by mass, a pH of the treatment liquid is within a range from 3.5 to 10.5, and a viscosity of the treatment liquid at 25° C. is within a range from 5.5 to 18.5 mPa.Math.s.