The present disclosure relates to the technical field of microbial electrochemical technology, in particular to a graphene-magnetite conductive skeleton electrode, a preparation method and application thereof, and a method for treating petrochemical wastewater. In the present disclosure, the surface roughness of the graphite rod electrode can be increased by the conductive skeleton modified on the surface of the graphite rod electrode, which is beneficial to the enrichment of microorganisms. The increase in the load of microorganisms will mean the amount of electroactive microorganisms will also increase, which will further improve the electron transfer ability, and because the material of the modified layer is a conductive material, it is also more conducive to the transfer of electrons; at the same time, the conductive skeleton modified on the surface of graphite rod electrode can also further enhance the transmission distance of electrons because of the skeleton constructed.

A fluoropolymer coating composition is described comprising an aqueous liquid medium, fluoropolymer particles dispersed in the aqueous liquid medium, and at least one aziridine compound. The aziridine compound comprises at least two aziridine groups (i.e. polyaziridine) or at least one aziridine group and at least one alkoxy silane group.

In another embodiment, an article is described comprising a substrate wherein a surface of the substrate comprises a coating comprising fluoropolymer particles; and a reaction product of at least one aziridine compound comprising at least two aziridine groups or at least one aziridine group and at least one alkoxy silane group. The coating can be utilized as a primer for bonding a non-fluorinated substrate to a fluoropolymer film and/or the coating can be used as an (e.g. outer exposed) surface layer. In some embodiments, the article may be the (e.g. backside) film of a photovoltaic module.

A fluoropolymer coating composition is described comprising an aqueous liquid medium, fluoropolymer particles dispersed in the aqueous liquid medium, and at least one aziridine compound. The aziridine compound comprises at least two aziridine groups (i.e. polyaziridine) or at least one aziridine group and at least one alkoxy silane group.

In another embodiment, an article is described comprising a substrate wherein a surface of the substrate comprises a coating comprising fluoropolymer particles; and a reaction product of at least one aziridine compound comprising at least two aziridine groups or at least one aziridine group and at least one alkoxy silane group. The coating can be utilized as a primer for bonding a non-fluorinated substrate to a fluoropolymer film and/or the coating can be used as an (e.g. outer exposed) surface layer. In some embodiments, the article may be the (e.g. backside) film of a photovoltaic module.

The present invention relates to a surface treatment composition for forming a self-assembled coating layer which is easily coated and removed and a surface treatment method, where the self-assembled coating layer can be easily formed because of use of a compound having the hydroxyl groups as a diol are attached to an ortho position of a benzene ring and be removed by treatment of Al.sup.3+ or Fe.sup.3+. Thus, the surface can be reused by forming a new self-assembled coating layer, thereby making the surface treatment composition be applied to various researches and industrial fields of the self-assembly coating layer which are used for reduction in metal abrasion resistance, introduction of a chemical functional group for detecting a biomolecule, the surface hydrophilicity, introduction of an antifouling property to the surface, and the like.

The present invention relates to a surface treatment composition for forming a self-assembled coating layer which is easily coated and removed and a surface treatment method, where the self-assembled coating layer can be easily formed because of use of a compound having the hydroxyl groups as a diol are attached to an ortho position of a benzene ring and be removed by treatment of Al.sup.3+ or Fe.sup.3+. Thus, the surface can be reused by forming a new self-assembled coating layer, thereby making the surface treatment composition be applied to various researches and industrial fields of the self-assembly coating layer which are used for reduction in metal abrasion resistance, introduction of a chemical functional group for detecting a biomolecule, the surface hydrophilicity, introduction of an antifouling property to the surface, and the like.

A method of coating a surface of a metal structure in situ comprises the steps of applying an liquidous under coating of a modified polyvinylidene fluoride (PVDF) or polyvinylidene difluoride (PVDF) material in an air dryable solution, and then applying a liquidous over coating of a modified polyvinylidene fluoride (PVDF) or polyvinylidene difluoride (PVDF) material in an air dryable solution. The under coating has: a PVDF or a PVDF co-polymer or a combination thereof of less than about 75% blended with at least about 25% compatible acrylic and/or other compatible polymer; and the PVDF or PVDF co-polymer or blend thereof has a particular PVDF molecular structure and a polymer crystallinity. The over coating has: a PVDF or a PVDF co-polymer or a blend thereof that is fluorinated to at least about 70% and at least about 70% PVDF molecular structure.

A method of coating a surface of a metal structure in situ comprises the steps of applying an liquidous under coating of a modified polyvinylidene fluoride (PVDF) or polyvinylidene difluoride (PVDF) material in an air dryable solution, and then applying a liquidous over coating of a modified polyvinylidene fluoride (PVDF) or polyvinylidene difluoride (PVDF) material in an air dryable solution. The under coating has: a PVDF or a PVDF co-polymer or a combination thereof of less than about 75% blended with at least about 25% compatible acrylic and/or other compatible polymer; and the PVDF or PVDF co-polymer or blend thereof has a particular PVDF molecular structure and a polymer crystallinity. The over coating has: a PVDF or a PVDF co-polymer or a blend thereof that is fluorinated to at least about 70% and at least about 70% PVDF molecular structure.

A fluoropolymer coating composition is described comprising an aqueous liquid medium, fluoropolymer particles dispersed in the aqueous liquid medium, and at least one aziridine compound. The aziridine compound comprises at least two aziridine groups (i.e. polyaziridine) or at least one aziridine group and at least one alkoxy silane group. In another embodiment, an article is described comprising a substrate wherein a surface of the substrate comprises a coating comprising fluoropolymer particles; and a reaction product of at least one aziridine compound comprising at least two aziridine groups or at least one aziridine group and at least one alkoxy silane group. The coating can be utilized as a primer for bonding a non-fluorinated substrate to a fluoropolymer film and/or the coating can be used as an (e.g. outer exposed) surface layer. In some embodiments, the article may be the (e.g. backside) film of a photovoltaic module.

A fluoropolymer coating composition is described comprising an aqueous liquid medium, fluoropolymer particles dispersed in the aqueous liquid medium, and at least one aziridine compound. The aziridine compound comprises at least two aziridine groups (i.e. polyaziridine) or at least one aziridine group and at least one alkoxy silane group. In another embodiment, an article is described comprising a substrate wherein a surface of the substrate comprises a coating comprising fluoropolymer particles; and a reaction product of at least one aziridine compound comprising at least two aziridine groups or at least one aziridine group and at least one alkoxy silane group. The coating can be utilized as a primer for bonding a non-fluorinated substrate to a fluoropolymer film and/or the coating can be used as an (e.g. outer exposed) surface layer. In some embodiments, the article may be the (e.g. backside) film of a photovoltaic module.

A process for treating a surface coating of a bulk metal part, comprises the steps of placing, in a cavity, at least one what is called metal part including what is called a surface coating that is able to absorb microwaves at the frequency ?.sub.0, the cavity being surrounded by one or a plurality of first susceptors the dimensions, material and arrangement of which are configured to screen the microwaves at the frequency ?.sub.0, in the vicinity of each the metal part, and in emitting the microwaves at the frequency ?.sub.0 into the cavity.