Provided is a low-temperature-curable cross-section repair material which can be cured in a short period of time, even in extremely low temperature environments of −25° C., and which exhibits excellent workability and strength development. Also provided is a cross-section repairing method using the same. The low-temperature-curable cross-section repair material is characterized by: comprising 100 parts by of a radical polymerizable resin composition (A), 0.1-10 parts by of a hydroxyl group-containing aromatic tertiary amine (C-1), 0.1-10 parts by of an organic peroxide (D), and 1.0-500 parts by of an inorganic filler (E); and the radical polymerizable resin composition (A) comprising at least one type of radical polymerizable resin (A-1) selected from the group consisting of vinyl ester resins, urethane (meth)acrylate resins and polyester (meth)acrylate resins, and a radical polymerizable unsaturated monomer (A-2) having at least two or more (meth)acryloyl groups per molecule thereof.

Copolymers and latex paint compositions using such copolymers that are heat-age stable and provide good adhesion, block resistance, and hiding all while using lower amounts of pigment are described herein. In one aspect, the heat-age stable compositions include an acrylic, styrene acrylic, vinyl acrylic copolymer or blends thereof including, as additional polymerizable units, at least one polymerizable phosphate surfactant and at least one linear or branched hydrophobic monomer that are both polymerized into the acrylic, styrene acrylic, vinyl acrylic copolymer backbone.

Copolymers and latex paint compositions using such copolymers that are heat-age stable and provide good adhesion, block resistance, and hiding all while using lower amounts of pigment are described herein. In one aspect, the heat-age stable compositions include an acrylic, styrene acrylic, vinyl acrylic copolymer or blends thereof including, as additional polymerizable units, at least one polymerizable phosphate surfactant and at least one linear or branched hydrophobic monomer that are both polymerized into the acrylic, styrene acrylic, vinyl acrylic copolymer backbone.

A method of forming a three-dimensional object, wherein said three-dimensional object is an insert for use between a helmet and a human body, is described. The method may use a polymerizable liquid, or resin, useful for the production by additive manufacturing of a three-dimensional object, comprising a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from said first component.

A method of forming a three-dimensional object, wherein said three-dimensional object is an insert for use between a helmet and a human body, is described. The method may use a polymerizable liquid, or resin, useful for the production by additive manufacturing of a three-dimensional object, comprising a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from said first component.

A method of forming a three-dimensional object is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid including a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from the first component; (c) irradiating the build region with light through the optically transparent member to form a solid polymer scaffold from the first component and also advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, and containing the second solidifiable component carried in the scaffold in unsolidified and/or uncured form; and (d) concurrently with or subsequent to the irradiating step, solidifying and/or curing the second solidifiable component in the three-dimensional intermediate to form the three-dimensional object.

One aspect of the present invention provides a photocurable resin composition for a surgical guide, which comprises 20 to 50 parts by weight of (meth)acrylate-based urethane copolymer; 40 to 70 parts by weight of a first (meth)acrylate-based monomer; 4 to 9 parts by weight of a second (meth)acrylate-based monomer; 1 to 4 parts by weight of a photoinitiator; and 0.005 to 1 parts by weight of a UV absorber, a surgical guide manufactured therefrom, and a method for manufacturing the same.

One aspect of the present invention provides a photocurable resin composition for a surgical guide, which comprises 20 to 50 parts by weight of (meth)acrylate-based urethane copolymer; 40 to 70 parts by weight of a first (meth)acrylate-based monomer; 4 to 9 parts by weight of a second (meth)acrylate-based monomer; 1 to 4 parts by weight of a photoinitiator; and 0.005 to 1 parts by weight of a UV absorber, a surgical guide manufactured therefrom, and a method for manufacturing the same.

Provided in the invention is an adhesion promoter (AP) that is the reaction product of: (i-1) at least one hydroxyl functional (meth)acrylated compound bearing at least two (meth)acryloyl groups, (i-2) optionally, at least one hydroxyl functional (meth)acrylated compound bearing one (meth)acryloyl group (ii), at least one titanium orthoester (ii-a) and/or at least one zirconium orthoester (ii-b), and, (iii) optionally, at least one other compound (iii) that is capable to react with hydroxyl groups. Materials of the invention are suitable for use in coating compositions, inks, paints, varnishes (including overprint varnishes), adhesives (including laminating adhesives), for the making of composites, molding compositions or 3D articles. Materials of the invention are suitable for use in inks and coating compositions (clear or pigmented).

Provided in the invention is an adhesion promoter (AP) that is the reaction product of: (i-1) at least one hydroxyl functional (meth)acrylated compound bearing at least two (meth)acryloyl groups, (i-2) optionally, at least one hydroxyl functional (meth)acrylated compound bearing one (meth)acryloyl group (ii), at least one titanium orthoester (ii-a) and/or at least one zirconium orthoester (ii-b), and, (iii) optionally, at least one other compound (iii) that is capable to react with hydroxyl groups. Materials of the invention are suitable for use in coating compositions, inks, paints, varnishes (including overprint varnishes), adhesives (including laminating adhesives), for the making of composites, molding compositions or 3D articles. Materials of the invention are suitable for use in inks and coating compositions (clear or pigmented).