A graft copolymer (C) having a main chain portion of a precursor polymer (A) and a graft portion from a polymer (B), wherein a core portion of the solid product comprises the main chain portion derived from (A), a shell portion comprises the graft portion derived from (B), and the solid product satisfies: Infrared absorption spectroscopic measurement of a section passing through a center (x) of the solid product, a point (z) on a surface where a distance between the center (x) and the surface is shortest, and a middle point (y) of a line connecting the center (x) and the point (z), absorbance (Abs) satisfies X<0.01, Y<0.01, and Z0.01, wherein X, Y, and Z represent values of Abs (key band of the polymer (B))/Abs (key band of the polymer (A)) at the center (x), the middle point (y) and the point (z).

The present invention provides a coating composition that has excellent storage stability and that is capable of forming a coating film having excellent water resistance, chemical resistance such as gasohol resistance and fuel resistance, and adhesion. The coating composition comprises an acid-modified polyolefin (A), a coumarone-indene resin (B), and a hydrocarbon-based solvent (C), wherein the coumarone-indene resin (B) is contained in an amount of 25 to 400 parts by mass, per 100 parts by mass of the acid-modified polyolefin (A). The coating composition further comprises at least one of an ester-based solvent or ketone-based solvent (D).

The present invention provides a coating composition that has excellent storage stability and that is capable of forming a coating film having excellent water resistance, chemical resistance such as gasohol resistance and fuel resistance, and adhesion. The coating composition comprises an acid-modified polyolefin (A), a coumarone-indene resin (B), and a hydrocarbon-based solvent (C), wherein the coumarone-indene resin (B) is contained in an amount of 25 to 400 parts by mass, per 100 parts by mass of the acid-modified polyolefin (A). The coating composition further comprises at least one of an ester-based solvent or ketone-based solvent (D).

The present invention relates to a composition comprising a stable aqueous dispersion of polymer particles comprising structural units of a polymerizable amino acid and structural units of an acid monomer or a salt thereof. The composition of the present invention is useful in improving lipstick stain resistance in coatings compositions.

A surface-treated metal sheet for adhesion to polyolefin includes a metal sheet, and a resin layer provided on at least one surface of the metal sheet. The resin layer contains an acid-modified polyolefin, the acid-modified polyolefin contains a first acid-modified polyolefin having an acid value of 5 mgKOH/g or less and a second acid-modified polyolefin having an acid value of 20 mgKOH/g or more and a melting point of higher than 90 C., and a difference between a melting point of the first acid-modified polyolefin and the melting point of the second acid-modified polyolefin is 0 C. or more and less than 40 C.

A surface-treated metal sheet for adhesion to polyolefin includes a metal sheet, and a resin layer provided on at least one surface of the metal sheet. The resin layer contains an acid-modified polyolefin, the acid-modified polyolefin contains a first acid-modified polyolefin having an acid value of 5 mgKOH/g or less and a second acid-modified polyolefin having an acid value of 20 mgKOH/g or more and a melting point of higher than 90 C., and a difference between a melting point of the first acid-modified polyolefin and the melting point of the second acid-modified polyolefin is 0 C. or more and less than 40 C.

The present invention provides a coating composition that has excellent storage stability and that is capable of forming a coating film having excellent water resistance, chemical resistance such as gasohol resistance and fuel resistance, and adhesion. The coating composition comprises an acid-modified polyolefin (A), a coumarone-indene resin (B), and a hydrocarbon-based solvent (C), wherein the coumarone-indene resin (B) is contained in an amount of 25 to 400 parts by mass, per 100 parts by mass of the acid-modified polyolefin (A). The coating composition further comprises at least one of an ester-based solvent or ketone-based solvent (D).

The present invention provides a coating composition that has excellent storage stability and that is capable of forming a coating film having excellent water resistance, chemical resistance such as gasohol resistance and fuel resistance, and adhesion. The coating composition comprises an acid-modified polyolefin (A), a coumarone-indene resin (B), and a hydrocarbon-based solvent (C), wherein the coumarone-indene resin (B) is contained in an amount of 25 to 400 parts by mass, per 100 parts by mass of the acid-modified polyolefin (A). The coating composition further comprises at least one of an ester-based solvent or ketone-based solvent (D).

The present invention is directed to film-forming compositions comprising: a) a non-chlorinated, linear polyolefin polymer comprising 0.5 to 10 percent by weight residues of an ethylenically unsaturated anhydride or acid; b) an aminoplast; and c) a component comprising: i) at least one non-chlorinated hydrocarbon having at least 18 carbon atoms and optionally aromatic groups and/or oxygen heteroatoms; and/or ii) an alkyd resin. The present invention is also drawn to methods of improving fuel resistance of a coated article, comprising: (1) applying the film-forming composition to a substrate to form a coated substrate; (2) optionally subjecting the coated substrate to a temperature for a time sufficient to cure the film-forming composition; (3) applying at least one curable film-forming composition to the coated substrate to form a multi-layer coated substrate; and (4) subjecting the multi-layer coated substrate to a temperature and for a time sufficient to cure all of the film-forming compositions.

The present invention is directed to film-forming compositions comprising: a) a non-chlorinated, linear polyolefin polymer comprising 0.5 to 10 percent by weight residues of an ethylenically unsaturated anhydride or acid; b) an aminoplast; and c) a component comprising: i) at least one non-chlorinated hydrocarbon having at least 18 carbon atoms and optionally aromatic groups and/or oxygen heteroatoms; and/or ii) an alkyd resin. The present invention is also drawn to methods of improving fuel resistance of a coated article, comprising: (1) applying the film-forming composition to a substrate to form a coated substrate; (2) optionally subjecting the coated substrate to a temperature for a time sufficient to cure the film-forming composition; (3) applying at least one curable film-forming composition to the coated substrate to form a multi-layer coated substrate; and (4) subjecting the multi-layer coated substrate to a temperature and for a time sufficient to cure all of the film-forming compositions.