Thermosetting powder coating compositions and processes for making the thermosetting powder coating compositions and processes for coating an article with the thermosetting powder coating compositions are disclosed. Cured thermosetting powder coating compositions are obtained by curing of the thermosetting powder coating compositions of the invention. Articles are provided having coated thereon the thermosetting powder coating compositions as well as to articles having coated and cured thereon the thermosetting powder coating compositions. The thermosetting powder coating compositions exhibit a substantially lower T.sub.chalk-free, that is a ΔT.sub.chalk-free which is in the range of from and including 5 up to and not including 10° C., wherein ΔT.sub.chalk-free=T.sub.chalk-free.sup.REF−T.sub.chalk-free.sup.A where T.sub.chalk-free.sup.A is the T.sub.chalk-free of a thermosetting powder coating composition according to the invention (TPCC-A) and T.sub.chalk-free.sup.REF is the T.sub.chalk-free of a thermosetting powder coating composition not according to the invention (TPCC-REF) that is comparable to TPCC-A.

The disclosure provides a cationic curing composition for a plastic substrate, a coating material including the composition and an application of the composition in the field of energy curing. The cationic curing composition includes a polyhydroxy resin, an epoxy compound, an oxetanyl-containing compound, and a cationic initiator, the polyhydroxy resin is a polyester resin, an acrylic resin and/or a phenolic resin, and the molar ratio of a hydroxyl, a three-membered epoxy group to a four-membered epoxy group in the cationic curing composition is 1:(3-20):(1-25). A plastic product includes the plastic substrate and a coating layer, and the coating layer is formed by curing the cationic curing composition.

The disclosure provides a cationic curing composition for a plastic substrate, a coating material including the composition and an application of the composition in the field of energy curing. The cationic curing composition includes a polyhydroxy resin, an epoxy compound, an oxetanyl-containing compound, and a cationic initiator, the polyhydroxy resin is a polyester resin, an acrylic resin and/or a phenolic resin, and the molar ratio of a hydroxyl, a three-membered epoxy group to a four-membered epoxy group in the cationic curing composition is 1:(3-20):(1-25). A plastic product includes the plastic substrate and a coating layer, and the coating layer is formed by curing the cationic curing composition.

The invention relates to compositions of α,α-branched alkane carboxylic acids glycidyl esters which derived from rosin and or hydrogenated rosin reacted with an epihalohydrin. The above glycidyl esters compositions can be used for example, as monomer in binder compositions for paints or adhesives, as reactive diluent or as acid scavenger. This invention is also about the uses of rosin and or hydrogenated rosin glycidyl ester in combinations with polyester polyols, or acrylic polyols, or polyether polyols.

The invention relates to compositions of α,α-branched alkane carboxylic acids glycidyl esters which derived from rosin and or hydrogenated rosin reacted with an epihalohydrin. The above glycidyl esters compositions can be used for example, as monomer in binder compositions for paints or adhesives, as reactive diluent or as acid scavenger. This invention is also about the uses of rosin and or hydrogenated rosin glycidyl ester in combinations with polyester polyols, or acrylic polyols, or polyether polyols.

The invention relates to an unsaturated polyester resin composition comprising: —a (meth)acrylate compound; and, —a polyester formed from at least: —reagent a) comprising itaconic acid and/or itaconic anhydride; —reagent b) comprising maleic acid, maleic anhydride, and/or fumaric acid; —reagent c) comprising dicyclopentadiene (DCPD); and, —reagent d) comprising at least one di- or poly-functional alcohol, preferably at least one diol; wherein the combined weight of reagent a) (i.e. the combined weight of itaconic acid and/or itaconic anhydride) is at least 10 wt. %, preferably at least 20 wt. %, of the total weight of di-acids and anhydrides used in the unsaturated polyester resin composition. The invention further relates to use of said unsaturated polyester resin for structural parts and for gel-coats. The invention also provides methods for preparing said unsaturated polyester resin composition.

The present disclosure relates to a method of coating a non-conductive substrate, said method comprising the steps of: a) applying a coating composition to the substrate, wherein the coating composition comprises: i) at least one unsaturated compound, ii) a thermal initiator comprising an organic peroxide, iii) a photoinitiator, and iv) at least one pigment, wherein the coating composition is free of accelerator, is capable of decreasing the activation energy of the thermal initiator, and is free of Co compounds, b) exposing the coating composition to UV light effective to start polymerization of the unsaturated compound, and c) exposing the coating composition to microwave heating effective to decompose the thermal initiator, wherein step c) is performed either simultaneously with step b) or sequentially after step b).

The present disclosure relates to a method of coating a non-conductive substrate, said method comprising the steps of: a) applying a coating composition to the substrate, wherein the coating composition comprises: i) at least one unsaturated compound, ii) a thermal initiator comprising an organic peroxide, iii) a photoinitiator, and iv) at least one pigment, wherein the coating composition is free of accelerator, is capable of decreasing the activation energy of the thermal initiator, and is free of Co compounds, b) exposing the coating composition to UV light effective to start polymerization of the unsaturated compound, and c) exposing the coating composition to microwave heating effective to decompose the thermal initiator, wherein step c) is performed either simultaneously with step b) or sequentially after step b).

A thermosetting powder coating composition C (PCC C) includes a physical mixture of a thermosetting powder coating composition A (PCC A) with a separate, distinct thermosetting powder coating composition B (PCC B). Also provided are processes for making the thermosetting powder coating composition C and for coating an article with the thermosetting powder coating composition C. A cured thermosetting powder coating composition C (c-PCC C) is also provided so as to obtain articles having coated and cured thereon the thermosetting powder coating composition C. Heat-curing can occur at low temperatures. The cured c-PCC C is a powder coating having at least one desirable property such as excellent resistance to swelling, good smoothness, good chemical resistance, low gloss, and/or low yellowness.

A thermosetting powder coating composition C (PCC C) includes a physical mixture of a thermosetting powder coating composition A (PCC A) with a separate, distinct thermosetting powder coating composition B (PCC B). Also provided are processes for making the thermosetting powder coating composition C and for coating an article with the thermosetting powder coating composition C. A cured thermosetting powder coating composition C (c-PCC C) is also provided so as to obtain articles having coated and cured thereon the thermosetting powder coating composition C. Heat-curing can occur at low temperatures. The cured c-PCC C is a powder coating having at least one desirable property such as excellent resistance to swelling, good smoothness, good chemical resistance, low gloss, and/or low yellowness.