Patent classifications
C09D167/08
RMA crosslinkable compositions and RMA crosslinkable resins for easy to clean coatings
The invention relates to RMA crosslinkable coating composition, a method for the preparation thereof and a resulting coating having easy to clean properties useful in applications like graffiti resistant, sanitisable coatings and in flooring, said composition comprising RMA crosslinkable component with at least 2 RMA donor groups and at least 2 RMA acceptor groups characterized by having fatty components selected from the group of fatty acids, fatty alcohols, fatty amines, fatty thiols and dimeric fatty acid in an amount represented by an Oil Content OC between 0, preferably 4 and 40 wt %, and crosslinking density XLD of at least 1.4 a glass transition Tg of at least 290 in combination providing a easy to clean value ΔE less than 20. The invention also relates to RMA crosslinkable fatty resins for use in RMA crosslinkable top coatings.
RMA crosslinkable compositions and RMA crosslinkable resins for easy to clean coatings
The invention relates to RMA crosslinkable coating composition, a method for the preparation thereof and a resulting coating having easy to clean properties useful in applications like graffiti resistant, sanitisable coatings and in flooring, said composition comprising RMA crosslinkable component with at least 2 RMA donor groups and at least 2 RMA acceptor groups characterized by having fatty components selected from the group of fatty acids, fatty alcohols, fatty amines, fatty thiols and dimeric fatty acid in an amount represented by an Oil Content OC between 0, preferably 4 and 40 wt %, and crosslinking density XLD of at least 1.4 a glass transition Tg of at least 290 in combination providing a easy to clean value ΔE less than 20. The invention also relates to RMA crosslinkable fatty resins for use in RMA crosslinkable top coatings.
AQUEOUS COATING COMPOSITION AND MULTILAYERED COATING FILM FORMATION METHOD
The present invention provides an aqueous coating composition that exhibits a small change in viscosity and can form a coating film having a superior coating film appearance even when the amount of a solvent contained in the aqueous coating composition decreases due to the change of the coating environment. An aqueous coating composition containing a polyester resin dispersion (A) and a melamine resin (B), wherein the polyester resin constituting the polyester resin dispersion (A) contains an alkyd resin having an acrylic vinyl-based polymer segment; the melamine resin (B) contains a hydrophobic melamine resin; as to a viscosity of a dry coating film of the coating composition, a coating film viscosity η1 of a dry coating film whose solid content is 60% by mass and a coating film viscosity η2 of a dry coating film whose solid content is 80% by mass satisfy the following condition:
1≤η2/η1≤10, where the coating film viscosities η1 and η2 are viscosities measured at a temperature of 25° C. and a shear rate of 0.1 sec.sup.−1.
AQUEOUS COATING COMPOSITION AND MULTILAYERED COATING FILM FORMATION METHOD
The present invention provides an aqueous coating composition that exhibits a small change in viscosity and can form a coating film having a superior coating film appearance even when the amount of a solvent contained in the aqueous coating composition decreases due to the change of the coating environment. An aqueous coating composition containing a polyester resin dispersion (A) and a melamine resin (B), wherein the polyester resin constituting the polyester resin dispersion (A) contains an alkyd resin having an acrylic vinyl-based polymer segment; the melamine resin (B) contains a hydrophobic melamine resin; as to a viscosity of a dry coating film of the coating composition, a coating film viscosity η1 of a dry coating film whose solid content is 60% by mass and a coating film viscosity η2 of a dry coating film whose solid content is 80% by mass satisfy the following condition:
1≤η2/η1≤10, where the coating film viscosities η1 and η2 are viscosities measured at a temperature of 25° C. and a shear rate of 0.1 sec.sup.−1.
AQUEOUS COATING COMPOSITION AND MULTILAYERED COATING FILM FORMATION METHOD
The present invention provides an aqueous coating composition that exhibits a small change in viscosity and can form a coating film having a superior coating film appearance even when the amount of a solvent contained in the aqueous coating composition decreases due to the change of the coating environment. An aqueous coating composition containing a polyester resin dispersion (A) and a melamine resin (B), wherein the polyester resin constituting the polyester resin dispersion (A) contains an alkyd resin having an acrylic vinyl-based polymer segment; the melamine resin (B) contains a hydrophobic melamine resin; as to a viscosity of a dry coating film of the coating composition, a coating film viscosity η1 of a dry coating film whose solid content is 60% by mass and a coating film viscosity η2 of a dry coating film whose solid content is 80% by mass satisfy the following condition:
1≤η2/η1≤10, where the coating film viscosities η1 and η2 are viscosities measured at a temperature of 25° C. and a shear rate of 0.1 sec.sup.−1.
ALKYD RESIN COMPOSITIONS
The present invention relates to an alkyd resin composition comprising a. 1-60 wt % of an imide compound according to anyone of formulas Ia, Ib, Ic, Id or Ie wherein R1 is H or a C1-C20 optionally substituted hydrocarbon group; R2 and R5 are independently H, or a C1-C20 hydrocarbon group; R3 and R4 are independently H, or a C1-C20 hydrocarbon group; R6 is H or a methyl group; R7 and R8 are independently H, methyl or ethyl; b. 10-40 wt % of an alcohol having a number average hydroxy functionality ≧2.0; c. 30-70 wt % of fatty acids or vegetable oils; d. 0-50 wt % of a mono and/or polyfunctional compound capable of esterification, which compound is different from the compounds used in a, b and c; wherein the wt % is determined relative to the total of weight of compounds a, b, c and d.
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ALKYD RESIN COMPOSITIONS
The present invention relates to an alkyd resin composition comprising a. 1-60 wt % of an imide compound according to anyone of formulas Ia, Ib, Ic, Id or Ie wherein R1 is H or a C1-C20 optionally substituted hydrocarbon group; R2 and R5 are independently H, or a C1-C20 hydrocarbon group; R3 and R4 are independently H, or a C1-C20 hydrocarbon group; R6 is H or a methyl group; R7 and R8 are independently H, methyl or ethyl; b. 10-40 wt % of an alcohol having a number average hydroxy functionality ≧2.0; c. 30-70 wt % of fatty acids or vegetable oils; d. 0-50 wt % of a mono and/or polyfunctional compound capable of esterification, which compound is different from the compounds used in a, b and c; wherein the wt % is determined relative to the total of weight of compounds a, b, c and d.
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LATEX COMPRISING WATER-SOLUBLE ACRYLIC MODIFIED ALKYD DISPERSION AND METHOD OF PRODUCTION THEREOF
A latex particle comprises an interior core and an outer shell. The core comprises an acrylic or vinyl polymer, and the shell comprises a water soluble alkyd polymer and at least one surfactant. Substantially all or all of the alkyd polymer is present in the shell of the latex particle and substantially none or none or the alkyd polymer is present in the core of the latex particle. Also described is a process for making the latex particle wherein the water soluble alkyd polymer is present as a co-surfactant during polymerization.
LATEX COMPRISING WATER-SOLUBLE ACRYLIC MODIFIED ALKYD DISPERSION AND METHOD OF PRODUCTION THEREOF
A latex particle comprises an interior core and an outer shell. The core comprises an acrylic or vinyl polymer, and the shell comprises a water soluble alkyd polymer and at least one surfactant. Substantially all or all of the alkyd polymer is present in the shell of the latex particle and substantially none or none or the alkyd polymer is present in the core of the latex particle. Also described is a process for making the latex particle wherein the water soluble alkyd polymer is present as a co-surfactant during polymerization.
Carbon black for waterborne coatings
An aqueous carbon black millbase, an aqueous carbon black liquid coating, and a method of making the millbase and liquid coating are provided. The carbon blacks are modified carbon blacks that are engineered to be able to be stirred into an aqueous vehicle without high energy milling of the carbon black. The modified carbon blacks include low organic treatment levels and the millbase and liquid coating do not require large quantities of dispersant. The resulting coatings exhibit excellent viscosity, color, hiding power and stability.