The present disclosure is drawn to multi-fluid kits for three-dimensional to printing, three-dimensional printing kits, and methods of making three-dimensional printed articles. In one example, a multi-fluid kit for three-dimensional printing can include a fusing agent, a first reactive agent, and a second reactive agent. The fusing agent can include water and a radiation absorber. The first reactive agent can include a first liquid vehicle and an epoxy compound having multiple epoxide groups. The second reactive agent can include a second liquid vehicle and an amine compound having multiple amino groups.

The present disclosure is drawn to multi-fluid kits for three-dimensional to printing, three-dimensional printing kits, and methods of making three-dimensional printed articles. In one example, a multi-fluid kit for three-dimensional printing can include a fusing agent, a first reactive agent, and a second reactive agent. The fusing agent can include water and a radiation absorber. The first reactive agent can include a first liquid vehicle and an epoxy compound having multiple epoxide groups. The second reactive agent can include a second liquid vehicle and an amine compound having multiple amino groups.

The present invention relates to a polymer film comprising a base film comprising polyamide-based resin; and two or more kinds of copolymers comprising polyamide-based segments and polyether-based segments, and a method for preparing the polymer film.

An example of a build material composition for three-dimensional (3D) printing includes a polyamide material and an antioxidant. The antioxidant consists of an aromatic multihydrazide; or an aromatic sulfonomonohydrazide; or a hydrazide having formula (I) disclosed herein, wherein: R is null, a C1 to C12 unbranched alkyl, a C3 to C8 branched alkyl, a C2 to C8 unbranched alkylene, a C4 to C8 branched alkylene, an alicyclic compound, a polyethylene glycol, or a combination thereof; A is C═O, O═S═O, P═O, or C═S; and n is an integer ranging from 1 to 4; or formula (II) disclosed herein wherein A is C═O, O═S═O, P═O, or C═S.

An example of a build material composition for three-dimensional (3D) printing includes a polyamide material and an antioxidant. The antioxidant consists of an aromatic multihydrazide; or an aromatic sulfonomonohydrazide; or a hydrazide having formula (I) disclosed herein, wherein: R is null, a C1 to C12 unbranched alkyl, a C3 to C8 branched alkyl, a C2 to C8 unbranched alkylene, a C4 to C8 branched alkylene, an alicyclic compound, a polyethylene glycol, or a combination thereof; A is C═O, O═S═O, P═O, or C═S; and n is an integer ranging from 1 to 4; or formula (II) disclosed herein wherein A is C═O, O═S═O, P═O, or C═S.

An example of a build material composition for three-dimensional (3D) printing includes a polyamide material and an antioxidant. The antioxidant includes an aromatic multihydrazide; or an aromatic sulfonomonohydrazide; or a hydrazide having formula (I) disclosed herein, wherein: R is null, a C1 to C12 unbranched alkyl, a C3 to C8 branched alkyl, a C2 to C8 unbranched alkylene, a C4 to C8 branched alkylene, an alicyclic compound, a polyethylene glycol, or a combination thereof; A is C═O, O=S═O, P═O, or C═S; and n is an integer ranging from 1 to 4; or formula (II) disclosed herein wherein A is C═O, O═S=O, P═O, or C═S.

##STR00001##

An example of a build material composition for three-dimensional (3D) printing includes a polyamide material and an antioxidant. The antioxidant includes an aromatic multihydrazide; or an aromatic sulfonomonohydrazide; or a hydrazide having formula (I) disclosed herein, wherein: R is null, a C1 to C12 unbranched alkyl, a C3 to C8 branched alkyl, a C2 to C8 unbranched alkylene, a C4 to C8 branched alkylene, an alicyclic compound, a polyethylene glycol, or a combination thereof; A is C═O, O=S═O, P═O, or C═S; and n is an integer ranging from 1 to 4; or formula (II) disclosed herein wherein A is C═O, O═S=O, P═O, or C═S.

##STR00001##

Disclosed are coating material compositions including (i) at least one polyol component (A), (ii) at least one crosslinking agent component (B) having groups reactive toward hydroxyl groups of component (A), (iii) at least one polyamide component (P1) in which the acid amide groups are connected by a saturated, aliphatic hydrocarbyl radical having 6 to 10 carbon atoms. Component (P1) is used in particulate form in which a size distribution (D.sub.50) is 20 to 100 μm. The coating material compositions further include (iv) at least one polycarboxamide component (P2) possessing the following structural formula ##STR00001##
in which s is 1, 2 or 3, t is 0 or 1, s+t is 2 or 3, R is a specific (s+t)-valent organic radical, and at least one of the radicals R.sup.1 and R.sup.2 carries at least one hydroxyl group. Also disclosed are methods of producing the coating material compositions.

Disclosed are coating material compositions including (i) at least one polyol component (A), (ii) at least one crosslinking agent component (B) having groups reactive toward hydroxyl groups of component (A), (iii) at least one polyamide component (P1) in which the acid amide groups are connected by a saturated, aliphatic hydrocarbyl radical having 6 to 10 carbon atoms. Component (P1) is used in particulate form in which a size distribution (D.sub.50) is 20 to 100 μm. The coating material compositions further include (iv) at least one polycarboxamide component (P2) possessing the following structural formula ##STR00001##
in which s is 1, 2 or 3, t is 0 or 1, s+t is 2 or 3, R is a specific (s+t)-valent organic radical, and at least one of the radicals R.sup.1 and R.sup.2 carries at least one hydroxyl group. Also disclosed are methods of producing the coating material compositions.

The present invention relates to the field of polymers used to form coatings at the surface of supports.

More particularly, the invention relates to a polymer having adhesion properties, in particular with regard to an organic or inorganic support, characterized in that it comprises at least one and preferably several consecutive or non-consecutive structural units of formula (I):

##STR00001##

in which: B represents a carbonyl or —NR′— unit with R′ representing a hydrogen atom, a C.sub.1 to C.sub.6 alkyl radical, or a C.sub.5 to C.sub.6 aryl, carbamate or acyl radical; and R represents: a hydrogen atom, a linear or branched, saturated or unsaturated C.sub.1 to C.sub.6 hydrocarbon-based radical which, where appropriate, is substituted with one or more halogen atoms, a C.sub.5 to C.sub.6 aryl radical, or an acyl, acyloxy, alkoxycarbonyl or cyano radical.