Compositions and methods useful for the singulation of fragile devices from substrates by the process of plasma singulation are described. Thermal resistant coatings comprising ingredients that exhibit both thermal resistance and water solubility are demonstrated. These ingredients which have high ultraviolet interaction allow laser interaction to create masks for thin and small devices, for example, substrates that are thin to 150 microns or less or have devices present that are measured 1 mm on a side or smaller. Methods are presented which apply the composition to the inorganic substrate whereby an ultraviolet sourced laser interacts with the surface and creates a mask which subsequently is processed in a plasma chamber to separate (singulate) the devices within the substrate and subsequently rinse with water to remove/dissolve the laser interactive and plasma protective layer. Once rinsed and clean, the devices proceed by pick and place tooling to final integration to electronic circuitry. The invention coating is a water rinsable creation that achieves high selectivity for both laser and plasma operations.

A high-solid-content coating composition including: (A) an acrylic resin containing a hydroxyl group and an alkoxysilyl group; (B) a polyester resin containing a hydroxyl group; and (C) a polyisocyanate compound, in which the acrylic resin (A) containing a hydroxyl group and an alkoxysilyl group is contained in an amount of 20 to 50 parts by mass per 100 parts by mass of resinous solid components of the high-solid-content coating composition, the polyester resin (B) containing a hydroxyl group has an acid value of 10 mg-KOH/g or less, a hydroxyl value of 180 to 300 mg-KOH/g, and a number-average molecular weight of 400 to 1,500, and the coating composition, when being applied, has a solid content of 50 mass % or more.

A high-solid-content coating composition including: (A) an acrylic resin containing a hydroxyl group and an alkoxysilyl group; (B) a polyester resin containing a hydroxyl group; and (C) a polyisocyanate compound, in which the acrylic resin (A) containing a hydroxyl group and an alkoxysilyl group is contained in an amount of 20 to 50 parts by mass per 100 parts by mass of resinous solid components of the high-solid-content coating composition, the polyester resin (B) containing a hydroxyl group has an acid value of 10 mg-KOH/g or less, a hydroxyl value of 180 to 300 mg-KOH/g, and a number-average molecular weight of 400 to 1,500, and the coating composition, when being applied, has a solid content of 50 mass % or more.

Described herein are static dissipating coatings and thermally-stable static-controlled (TSSC) electronic circuits, comprising such coatings. Also described herein are methods of forming such coatings and circuits. In some examples, a static dissipating coating comprises a conductive polymer and a thermally-stable base polymer. The conductive polymer comprises polyaniline and, in some examples, a conductive agent, such as dinonylnaphthalene sulfonic acid (DNNSA), dodecyl benzene sulfonic acid (DBSA), and/or camphor sulfonic acid (CSA). The thermally-stable base polymer comprises one or more copolymers of butyl-methacrylate, such as poly-butylmethacrylate-co-methyl methacrylate (PBM). The amount of the conductive polymer is specifically controlled to ensure the coating's overall conductivity and thermal stability. In some examples, the conductive polymer concentration is at or less than 25% by weight. The conductivity of the coating is between 10.sup.−9 S/cm and 10.sup.−6 S/cm even after being exposed to 150° C. for up to 24 hours.

Described herein are static dissipating coatings and thermally-stable static-controlled (TSSC) electronic circuits, comprising such coatings. Also described herein are methods of forming such coatings and circuits. In some examples, a static dissipating coating comprises a conductive polymer and a thermally-stable base polymer. The conductive polymer comprises polyaniline and, in some examples, a conductive agent, such as dinonylnaphthalene sulfonic acid (DNNSA), dodecyl benzene sulfonic acid (DBSA), and/or camphor sulfonic acid (CSA). The thermally-stable base polymer comprises one or more copolymers of butyl-methacrylate, such as poly-butylmethacrylate-co-methyl methacrylate (PBM). The amount of the conductive polymer is specifically controlled to ensure the coating's overall conductivity and thermal stability. In some examples, the conductive polymer concentration is at or less than 25% by weight. The conductivity of the coating is between 10.sup.−9 S/cm and 10.sup.−6 S/cm even after being exposed to 150° C. for up to 24 hours.

Disclosed herein are aqueous coating compositions containing an anionically stabilized polymer, one or more derivatized polyamines, and a volatile base. Coating compositions can further include one or more additional copolymers, which may or may not be anionically stabilized, and/or additional additives, including pigments, defoamers, pigment dispersing agents, thickeners, surfactants, and combinations thereof. By incorporating a derivatized polyamine, such as an alkoxylated polyamine, the setting time of the coating compositions can be decreased. Also provided are coatings formed from the coating compositions described herein, as well as methods of forming these coatings.

Disclosed herein are aqueous coating compositions containing an anionically stabilized polymer, one or more derivatized polyamines, and a volatile base. Coating compositions can further include one or more additional copolymers, which may or may not be anionically stabilized, and/or additional additives, including pigments, defoamers, pigment dispersing agents, thickeners, surfactants, and combinations thereof. By incorporating a derivatized polyamine, such as an alkoxylated polyamine, the setting time of the coating compositions can be decreased. Also provided are coatings formed from the coating compositions described herein, as well as methods of forming these coatings.

Disclosed herein are aqueous coating compositions containing an anionically stabilized polymer, one or more derivatized polyamines, and a volatile base. Coating compositions can further include one or more additional copolymers, which may or may not be anionically stabilized, and/or additional additives, including pigments, defoamers, pigment dispersing agents, thickeners, surfactants, and combinations thereof. By incorporating a derivatized polyamine, such as an alkoxylated polyamine, the setting time of the coating compositions can be decreased. Also provided are coatings formed from the coating compositions described herein, as well as methods of forming these coatings.

A composition comprising: (a) a conductive polymer, (b) a resin having a solubility parameter of 9.0 to 12.0 (cal/cm.sup.3).sup.1/2, (c) a solvent, and (d) a phenolic compound.

A composition comprising: (a) a conductive polymer, (b) a resin having a solubility parameter of 9.0 to 12.0 (cal/cm.sup.3).sup.1/2, (c) a solvent, and (d) a phenolic compound.