An aqueous dispersion along with methods for producing and uses for the same. Where the aqueous dispersion includes crosslinkable reactive silicone organic copolymers of ethylenically unsaturated monomers and of ethylenically functionalized silicone polymers and is obtainable by means of radically initiated miniemulsion polymerization in an aqueous medium.

An aqueous dispersion along with methods for producing and uses for the same. Where the aqueous dispersion includes crosslinkable reactive silicone organic copolymers of ethylenically unsaturated monomers and of ethylenically functionalized silicone polymers and is obtainable by means of radically initiated miniemulsion polymerization in an aqueous medium.

Provided are adhesive articles that include a silicone adhesive and a substrate, with a primer layer interposed between the silicone adhesive and the substrate. The primer layer includes a polymer having a polyorganosiloxane pendant group P represented by the formula (I) where each R.sup.1 is independently an alkyl, haloalkyl, arylalkyl, alkenyl, aryl, or aryl substituted with an alkyl, alkoxy, or halo; R2 is an alkyl or an alkenyl group; R3 is an alkylene or an arylalkylene group; and n is an integer in the range of 1 to 20. The primer layer typically improves the adhesion between the silicone adhesive and a wide variety of substrates.

##STR00001##

There are provided self-healing elastomeric materials and compositions and skin-like materials for use in a wide range of applications, particularly medical training simulators and mannequins. The self-healing elastomeric material comprises polysiloxane or poly ether soft segments connected via carbonate, urethane and/or urea bonds. The self-healing elastomeric material is intrinsically and/or thermally self- healing. Reusable devices, apparatuses and articles comprising the elastomeric materials as skin-like materials are disclosed.

A (meth)acrylic copolymer of the present invention includes a constituent unit (B) derived from a polysiloxane block-containing polymerizable monomer (b) represented by Formula (b1). In Formula (b1), R.sup.30 represents a hydrogen atom or a methyl group, a represents an integer of 2 to 5, b represents a number of 0 to 50, c represents an integer of 0 to 18, d represents a number of 1 to 1000, e represents a number of 1 to 80, R.sup.31 to R.sup.39 each represents an alkyl group, an alkoxy group, a phenyl group, a substituted phenyl group, a phenoxy group, or a substituted phenoxy group.

A (meth)acrylic copolymer of the present invention includes a constituent unit (B) derived from a polysiloxane block-containing polymerizable monomer (b) represented by Formula (b1). In Formula (b1), R.sup.30 represents a hydrogen atom or a methyl group, a represents an integer of 2 to 5, b represents a number of 0 to 50, c represents an integer of 0 to 18, d represents a number of 1 to 1000, e represents a number of 1 to 80, R.sup.31 to R.sup.39 each represents an alkyl group, an alkoxy group, a phenyl group, a substituted phenyl group, a phenoxy group, or a substituted phenoxy group.

A hydrosilylation curable textile coating composition comprises: (a) a linear organopolysiloxane polymer having at least two alkenyl and/or alkynyl groups per molecule; (b) a reinforcing filler comprising at least one of fumed silica, precipitated silica, or calcium carbonate; (c) a linear trimethyl terminated polydimethyl methylhydrogen siloxane containing at least two silicon-bonded hydrogen groups per molecule; Ld) a hydrosilylation cure catalyst; (e) an organosilicon resin; and (f) an adhesion promoter comprising a mixture and/or reaction product of: (i) one or more alkoxysilanes having an epoxy group in the molecule; (ii) a linear organopolysiloxane oligomer containing at least one alkenyl group and at least one hydroxy or alkoxy group per molecule; and (iii) an organometallic condensation reaction catalyst comprising organoaluminum or organozirconium compounds. Air bags and air bag fabrics can be coated with the hydrosilylation curable textile coating composition, and the resulting air bags and fabrics generally have enhanced scrub resistance.

A hydrosilylation curable textile coating composition comprises: (a) a linear organopolysiloxane polymer having at least two alkenyl and/or alkynyl groups per molecule; (b) a reinforcing filler comprising at least one of fumed silica, precipitated silica, or calcium carbonate; (c) a linear trimethyl terminated polydimethyl methylhydrogen siloxane containing at least two silicon-bonded hydrogen groups per molecule; Ld) a hydrosilylation cure catalyst; (e) an organosilicon resin; and (f) an adhesion promoter comprising a mixture and/or reaction product of: (i) one or more alkoxysilanes having an epoxy group in the molecule; (ii) a linear organopolysiloxane oligomer containing at least one alkenyl group and at least one hydroxy or alkoxy group per molecule; and (iii) an organometallic condensation reaction catalyst comprising organoaluminum or organozirconium compounds. Air bags and air bag fabrics can be coated with the hydrosilylation curable textile coating composition, and the resulting air bags and fabrics generally have enhanced scrub resistance.

A resin composition, wherein a resin component in the resin composition has a group represented by the following General Formula (11), (21) or (31) and a urethane bond:

##STR00001##

(in the formulae, Z.sup.1 is an alkyl group, and one or more hydrogen atoms in the alkyl group may be substituted with a cyano group, a carboxy group or a methoxycarbonyl group, and two or more of the substituents may be the same as or different from each other; Z.sup.2 is an alkyl group; Z.sup.3 is an aryl group; R.sup.4 is a hydrogen atom or a halogen atom; and the bond with the symbol * is formed with the bonding destination of the group represented by General Formula (11), (21) or (31)).

A resin composition, wherein a resin component in the resin composition has a group represented by the following General Formula (11), (21) or (31) and a urethane bond:

##STR00001##

(in the formulae, Z.sup.1 is an alkyl group, and one or more hydrogen atoms in the alkyl group may be substituted with a cyano group, a carboxy group or a methoxycarbonyl group, and two or more of the substituents may be the same as or different from each other; Z.sup.2 is an alkyl group; Z.sup.3 is an aryl group; R.sup.4 is a hydrogen atom or a halogen atom; and the bond with the symbol * is formed with the bonding destination of the group represented by General Formula (11), (21) or (31)).