According to an aspect of the present disclosure, A method of manufacturing a composite member including an aluminum member and a resin member that are bonded to each other, the method including: blasting on a surface of the aluminum member to form asperities on the surface of the aluminum member; performing hydrothermal treatment on the surface of the aluminum member having the asperities to modify a surface of the asperities into aluminum hydroxide and form a surface nano structure on the surface of the asperities; applying a binder containing a triazine thiol derivative to the surface of the asperities of the aluminum member modified into aluminum hydroxide and having the surface nano structure to form a coating to be bonded to the aluminum member; and bonding the coating and the resin member.

The present disclosure provides methods and systems for composite-to-metal hybrid bonded structures compromising the laser surface treatment on titanium alloys to promote adhesive bond performance. For example, a computer may be programmed to set a laser path corresponding to a predetermined geometric pattern. A laser may be coupled to the computer and apply a pulsed laser beam to a contact surface of the titanium alloy along the predefined geometric pattern. The laser may generate an open pore oxide layer on the contact surface of the substrate with a thickness of 100 and 500 nm. The open pore oxide layer may have a topography corresponding to the predefined geometric pattern. The topography may contain high degree of open pore structure and promote adhesive bond performance. Adhesive, primer or composite resin matrix may fully infiltrate into the open pore structures. Adhesive and composite laminate may co-cure to form composite-to-titanium hybrid bonded structures.

A method of and system for adhesive bonding by a) providing a polymerizable adhesive composition on a surface of an element to be bonded to form an assembly; b) irradiating the assembly with radiation at a first wavelength capable of vulcanization of bonds in the polymerizable adhesive composition by activation of sulfur-containing compound with at least one selected from x-ray, e-beam, visible, or infrared light to thereby generate ultraviolet light in the polymerizable adhesive composition; and c) adhesively joining two or more components together by way of the polymerizable adhesive composition, and a curable polymer for use therein.

The invention relates to the use of a separating medium, containing at least one essential oil or consisting of at least one essential oil, selected from the group consisting of phenols, phenylpropanoids and furanocoumarins, for separating at least two joining parts which are joined by means of an adhesive bond.

The instant invention concerns the use of polymers obtained by radical copolymerization of a mixture of (1) acrylic acid; (2) methacrylic acid; and (3) at least one allylcatechol selected from 4-allylbenzene-1,2-diol, 3-allylbenzene-1,2-diol; methylated forms thereof (eugenols); and mixtures thereof, for treating a metallic surface intended to be adhesive-bonded to another surface, in order to impart a resistance to the adhesive failure to the resulting bonding.

The instant invention concerns the use of polymers obtained by radical copolymerization of a mixture of (1) acrylic acid; (2) methacrylic acid; and (3) at least one allylcatechol selected from 4-allylbenzene-1,2-diol, 3-allylbenzene-1,2-diol; methylated forms thereof (eugenols); and mixtures thereof, for treating a metallic surface intended to be adhesive-bonded to another surface, in order to impart a resistance to the adhesive failure to the resulting bonding.

The present application provides compositions and methods for allowing surfaces such as HDPE, LDPE, polyethylene, polypropylene, Teflon (polytetrafluoroethylene), SBS, SEBS, SIS elastomers, and silicone rubber, which are notoriously difficult to apply adhesives, glues, or coatings to, to he treated with a Primer System that increases the ability of a glue, adhesive, or coating to adhere to that surface and subsequently allows other materials to be used as coatings on the surface or to be applied using a glue or adhesive.

The present application provides compositions and methods for allowing surfaces such as HDPE, LDPE, polyethylene, polypropylene, Teflon (polytetrafluoroethylene), SBS, SEBS, SIS elastomers, and silicone rubber, which are notoriously difficult to apply adhesives, glues, or coatings to, to he treated with a Primer System that increases the ability of a glue, adhesive, or coating to adhere to that surface and subsequently allows other materials to be used as coatings on the surface or to be applied using a glue or adhesive.

A method of and system for adhesive bonding by a) providing a polymerizable adhesive composition on a surface of an element to be bonded to form an assembly; b) irradiating the assembly with radiation at a first wavelength capable of vulcanization of bonds in the polymerizable adhesive composition by activation of sulfur-containing compound with at least one selected from x-ray, e-beam, visible, or infrared light to thereby generate ultraviolet light in the polymerizable adhesive composition; and c) adhesively joining two or more components together by way of the polymerizable adhesive composition, and a curable polymer for use therein.

Solid, non-melting polyurethanes having a glass transition temperature of at least 40° C. and free isocyanate groups are self-bonding materials that are useful in a variety of adhesive and molding operations. Under conditions of heat and moisture, these polyurethanes will self-bond. The polyurethanes can be used as adhesive coatings, which are solid and non-tacky and thus can be transported and stored easily under ambient conditions. These polyurethane adhesives are especially useful in applications in which, due to the location and/or orientation of the substrates, liquid or melting materials cannot be applied easily or will run off the substrates.