C09J133/04

Polyester/primer/metal composite film that is cohesive and impermeable to gas, method for the production thereof and the primer utilized in said method

The aim of the invention is to provide polyester/primer/metallic coating composite films having good adherence of the metallic coating in dry and humid conditions. Said films also form a good gas barrier: oxygen permeability less than or equal to 0.8 cc/m2/d; water vapour permeability less than or equal to 0.3 g/m2/d. To this end, the invention concerns a composite film comprising a polyester substrate, at least one coating adhering on at least one of the faces of the substrate and at least one layer of primer for cross-linked adhesion between the substrate and the coating. Said primer comprises at least one acrylic and/or methacrylic polymer P1, at least one acrylic and/or methacrylic polymer P2 different from P1, at least one cross-linking agent, and, preferably, at least one polyester that is soluble or dispersible in water: —P1 having a gel content TG1>70% by dry weight with respect to P1; —P2 having a gel content TG2≤TG1 and ≤20% by dry weight, with respect to P2; —P1 having a surface-grafted free weak acid content≥0.8 in meq/g of polymer; —[P2]≤60% by weight on dry by weight in respect to P1+P2. The method for producing said film, the adhering primer, and the articles obtained using said film, also form part of the present invention.

Polyester/primer/metal composite film that is cohesive and impermeable to gas, method for the production thereof and the primer utilized in said method

The aim of the invention is to provide polyester/primer/metallic coating composite films having good adherence of the metallic coating in dry and humid conditions. Said films also form a good gas barrier: oxygen permeability less than or equal to 0.8 cc/m2/d; water vapour permeability less than or equal to 0.3 g/m2/d. To this end, the invention concerns a composite film comprising a polyester substrate, at least one coating adhering on at least one of the faces of the substrate and at least one layer of primer for cross-linked adhesion between the substrate and the coating. Said primer comprises at least one acrylic and/or methacrylic polymer P1, at least one acrylic and/or methacrylic polymer P2 different from P1, at least one cross-linking agent, and, preferably, at least one polyester that is soluble or dispersible in water: —P1 having a gel content TG1>70% by dry weight with respect to P1; —P2 having a gel content TG2≤TG1 and ≤20% by dry weight, with respect to P2; —P1 having a surface-grafted free weak acid content≥0.8 in meq/g of polymer; —[P2]≤60% by weight on dry by weight in respect to P1+P2. The method for producing said film, the adhering primer, and the articles obtained using said film, also form part of the present invention.

ADHESIVE SHEET, CONSTRUCT, AND METHOD FOR PRODUCING CONSTRUCT
20230272247 · 2023-08-31 · ·

An adhesive sheet (1) comprising an adhesive layer (11) composed of an adhesive having active energy ray curability and ultraviolet ray absorbability, wherein when one surface of the adhesive layer (11) is irradiated with ultraviolet rays having a light amount of 2000 mJ/cm.sup.2 to cure the adhesive layer (11) and an infrared absorption spectrum is then measured by a total reflection measurement method for each of an irradiated surface and a non-irradiated surface, the maximum value of the absolute value of absorbance is 0.0001 to 0.012 within a wavenumber range of 700 to 1000 cm.sup.−1 in a difference spectrum obtained by subtracting the infrared absorption spectrum of the non-irradiated surface from the infrared absorption spectrum of the irradiated surface, and when the adhesive layer (11) is irradiated with ultraviolet rays having a light amount of 2000 mJ/cm.sup.2 to cure the adhesive layer (11), the difference in a gel fraction of the adhesive constituting the adhesive layer (11) before and after the irradiation is 5 points or more and 50 points or less. According to such an adhesive sheet (1), both the light resistance and the blister resistance can be achieved satisfactorily.

FREEZE PROTECTED WATER-BASED DISPERSION ADHESIVE AND USE THEREOF

A two-component composition including a first component A including an aqueous dispersion of at least one polymer P, at least one metal salt M, and at least one liquid organic freeze point depressant D, and a second component B having a mineral binder composition C having at least one hydraulic binder H. The two-component composition is used as an adhesive, sealant or coating and to a method for bonding a first substrate to a second substrate.

FREEZE PROTECTED WATER-BASED DISPERSION ADHESIVE AND USE THEREOF

A two-component composition including a first component A including an aqueous dispersion of at least one polymer P, at least one metal salt M, and at least one liquid organic freeze point depressant D, and a second component B having a mineral binder composition C having at least one hydraulic binder H. The two-component composition is used as an adhesive, sealant or coating and to a method for bonding a first substrate to a second substrate.

ADHESIVE FILM AND OPTICAL DEVICE INCLUDING THE SAME
20220135724 · 2022-05-05 · ·

An adhesive film includes an upper protective layer, a lower protective layer, and an adhesive layer between the upper protective layer and the lower protective layer. The adhesive layer includes a first adhesive layer and a second adhesive layer on the first adhesive layer. The first adhesive layer includes an acrylic resin, a photoinitiator, and a monofunctional monomer. The second adhesive layer includes an acrylic resin, a photoinitiator, and a multifunctional monomer.

ADHESIVE FILM AND OPTICAL DEVICE INCLUDING THE SAME
20220135724 · 2022-05-05 · ·

An adhesive film includes an upper protective layer, a lower protective layer, and an adhesive layer between the upper protective layer and the lower protective layer. The adhesive layer includes a first adhesive layer and a second adhesive layer on the first adhesive layer. The first adhesive layer includes an acrylic resin, a photoinitiator, and a monofunctional monomer. The second adhesive layer includes an acrylic resin, a photoinitiator, and a multifunctional monomer.

Object adhesion/peeling method, and object adhesion/peeling device

An object adhesion/peeling method according to an embodiment includes adhering a adhesion target object to a second surface side of an adhesive sheet, wherein the adhesive sheet includes adhesive surfaces on a first surface side and the second surface side, and a first electrode and a second electrode provided to be adjacent to the first electrode are provided on the first surface side; adhering the first surface side of the adhesive sheet to a fixation target surface; inputting a predetermined voltage to the first electrode and the second electrode to generate a potential difference based on the predetermined voltage in a direction orthogonal to a layer thickness direction of the adhesive sheet; and causing an electrochemical reaction on the first surface side of the adhesive sheet to peel off the adhesive sheet from the fixation target surface.

ECO-FRIENDLY ACRYLIC EMULSION OPP TAPE AND METHOD FOR MANUFACTURING SAME
20230242792 · 2023-08-03 ·

An eco-friendly aqueous acrylic emulsion OPP tape and a method for manufacturing the same and, more particularly, to a method for manufacturing an OPP tape using an aqueous acrylic emulsion adhesive that adopts an optimized drying process to significantly enhance the production efficiency, and an OPP tape using an aqueous acrylic emulsion adhesive that is produced by the manufacturing method and has non-toxicity, durability secured by stability, and excellent adhesiveness and retention.

PRESSURE-SENSITIVE ADHESIVE SHEET

Provided is a PSA sheet that can be separated well from the adherend after a curing treatment and that can prevent adhesive transfer during separation even when exposed to a high temperature. Provided is a PSA sheet having a PSA layer. The PSA layer of the PSA sheet comprises a polymer having a glass transition temperature of −63° C. or higher. The PSA sheet has an adhesive strength reduction rate 17% or higher after a heating/curing treatment.