Methods, compositions, and kits for adhering polymers and other materials to another material, and in particular to bone or bone-like structures or surfaces. A composition of matter includes a urethane dimethacrylate-methyl methacrylate copolymer with a plurality of first polymer regions based on urethane dimethacrylate and a plurality of second polymer regions based on methyl methacrylate. The method includes placing an orthopedic joint implant having an attachment surface in a joint space, applying a first non-urethane-containing precursor, a second urethane-containing precursor, and a initiator to the attachment surface; contacting the first and second precursors and the initiator with the joint surface; and copolymerizing the first and second precursors and forming an adhesive copolymer and attaching the implant to the joint.

Methods, compositions, and kits for adhering polymers and other materials to another material, and in particular to bone or bone-like structures or surfaces. A composition of matter includes a urethane dimethacrylate-methyl methacrylate copolymer with a plurality of first polymer regions based on urethane dimethacrylate and a plurality of second polymer regions based on methyl methacrylate. The method includes placing an orthopedic joint implant having an attachment surface in a joint space, applying a first non-urethane-containing precursor, a second urethane-containing precursor, and a initiator to the attachment surface; contacting the first and second precursors and the initiator with the joint surface; and copolymerizing the first and second precursors and forming an adhesive copolymer and attaching the implant to the joint.

A resin composition includes (a) at least one 2-methylene-1,3-dicarbonyl compound, (b) an initiator comprising at least one basic substance, and (c) an anionic polymerization inhibitor including at least one borate ester compound.

A resin composition includes (a) at least one 2-methylene-1,3-dicarbonyl compound, (b) an initiator comprising at least one basic substance, and (c) an anionic polymerization inhibitor including at least one borate ester compound.

The present teachings contemplate a method comprising providing a first and second substrate, locating an initiator onto a surface of the first or second substrate, the initiator including a substance for initiating polymerization of a polymerizable adhesive, locating the polymerizable adhesive onto a surface of the first and second substrate, the adhesive including a monofunctional, difunctional, or multifunctional methylene malonate, or cyanoacrylate, and contacting first and second substrate.

The present teachings contemplate a method comprising providing a first and second substrate, locating an initiator onto a surface of the first or second substrate, the initiator including a substance for initiating polymerization of a polymerizable adhesive, locating the polymerizable adhesive onto a surface of the first and second substrate, the adhesive including a monofunctional, difunctional, or multifunctional methylene malonate, or cyanoacrylate, and contacting first and second substrate.

Provided is a curable-type composition, including a methylene malonate compound, a Lewis acidic compound, and a photo base generator.

Provided is a curable-type composition, including a methylene malonate compound, a Lewis acidic compound, and a photo base generator.

The present invention relates to a bio-based acrylate monomer having a structure

##STR00001##

wherein R.sub.1 is H or —CH.sub.3, and wherein R.sub.2 is linear C1-C10 alkyl or branched C3-C10 alkyl.

A process prepares a cross-linked polymer containing urethane groups and silicon atoms. Starting materials of the process include a compound A) with a five-membered cyclic monothiocarbonate group, a compound B) with an amino group, selected from primary or secondary amino groups or blocked amino groups, and optionally, a compound C) with at least one functional group that reacts with a group —SH. One of the compounds contains a silicon-functional group. In one example of the process, compounds A) and B), and optionally C), are then reacted under exclusion of water to obtain a polymer with curable silicon-functional groups. The polymer is applied to a surface, gap, or a three-dimensional template. The silicon-functional groups are cured with ambient water. The polymer contains 0.001 to 0.3 mol of silicon per 100 g of the polymer.